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241.
Ashraf H. Bayoumi Adel H. Ghiaty Shimaa M. Abd El‐Gilil Ebtehal M. Husseiny Maha A. Ebrahim 《Journal of heterocyclic chemistry》2019,56(12):3215-3235
Novel 2 and 3‐substituted quinoxaline derivatives were synthesized through various synthetic pathways, among which cyanoacetamide and cyanoacetohydrazide quinoxaline derivatives 4a‐c and 11a‐c , respectively, were synthesized. Furthermore, methoxy quinoxaline derivatives 3c and quinoxaline derivatives bearing substituted pyridines 6a,b , 12a,b , and 13a,b were designed to be synthesized. However, we have synthesized acrylohydrazide 5a,b and 7 /acrylamide derivatives, Schiff base analogues 14a‐f , pyrazole derivatives 15a‐e, amide derivatives 16a‐f , guanidine derivatives 16 g,h as well as, quinoxalin‐2‐methylallyl propionate derivative 14g . All the synthesized compounds were confirmed via spectral data and elemental analyses. Moreover, the newly synthesized compounds were evaluated for their antimicrobial activity (Gm +ve, Gm ?ve in comparison to Gentamycin a standard) and fungi (in comparison to Ketoconazole as a standard). Thus, compound 16b showed promising antimicrobial activity against B. subtilis, P. vulgaris, and S. mutants with values ranging from 20 to 27‐mm zone of inhibition. While compounds 5a , 14e,f, and 16a,c,d,g,h showed potent antimicrobial activity. Moreover, the National Cancer Institute (NCI) selected 20 compounds that were submitted for anticancer screening against 60 types of cancer cell lines. The most active compounds are 5b and 12a where compound 5b containing 2,4‐dichlorophenyl moiety at cyanoacetamide linkage of hydrazine quinoxaline backbone exerted significant growth inhibition activity against Leukemia MOLT‐4, Renal cancer UO‐31, and Breast cancer MCF‐7. In addition, compound 12a having 4,6‐diaminopyridinone side chain at position‐3 of quinoxaline nucleus exhibited remarkable anticancer activity against renal cancer UO‐31. 相似文献
242.
Seyed Ebrahim Sajjadi Yalda Shokoohinia Saeed Hemmati 《Chemistry of Natural Compounds》2012,48(4):668-671
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This article deals with the study of the steady three-dimensional stagnation point flow of a nanofluid past a circular cylinder that has a sinusoidal radius variation. By means of similarity transformation, the governing partial differential equations are reduced into highly non-linear ordinary differential equations. The resulting non-linear system has been solved analytically using an efficient technique namely homotopy analysis method (HAM). Expressions for velocity and temperature fields are developed in series form. In this study, three different types of nanoparticles are considered, namely alumina (Al2O3), titania (TiO2), and copper (Cu) with water as the base fluid. For alumina–water nanofluid, graphical results are presented to describe the influence of the nanoparticle volume fraction φ and the ratio of the gradient of velocities c on the velocity and temperature fields. Moreover, the features of the flow and heat transfer characteristics are analyzed and discussed for foregoing nanofluids. It is found that the skin friction coefficient and the heat transfer rate at the surface are highest for copper–water nanofluid compared to the alumina–water and titania–water nanofluids. 相似文献
247.
A CF3-containing diamine, 2,2′-thiobis-[4-methyl(2-trifluoromethyl)4-aminophenoxy) phenyl ether] (DA), was successfully synthesized from 2-2′-sulfide-bis-(4-methyl phenol) and 2-chloro-5-nitrobenzotrifluoride. The sulfur containing diimide-diacid (DIDA) was prepared by condensation reaction of diamine DA and trimellitic anhydride. A series of novel organic-soluble polyamide-imides (PAIs) bearing flexible ether and sulfide links, electron-withdrawing trifluoromethyl groups and ortho-phenylene units were synthesized from DIDA, by direct polycondensation with various aromatic diamines in N-methyl-2-pyrrolidone using triphenyl phosphite and pyridine as a condensing agent in the presence of dehydrating agent (LiCl). The polyamide-imides were obtained in high yields and possessed inherent viscosities in the range of 0.42-0.95 dL g−1. All of the polymers were amorphous in nature, showed outstanding solubility and could be easily dissolved in amide-type polar aprotic solvents (e.g., N-methyl-2-pyrrolidone, N,N-dimethylacetamide, and N,N-dimethylformamide) and even dissolved in less polar solvents (e.g., pyridine and tetrahydrofuran). They showed good thermal stability with glass transition temperatures between 195-245 °C, 10% weight loss temperatures in excess of 485 °C, and char yields more than 50% at 700 °C in nitrogen atmosphere. Moreover, these PAIs possessed low refractive indexes (n = 1.57-1.59) and low birefringence (Δ ≈ 0.02) due to the trifluoromethyl pendent groups and thioether bridged ortho-catenated aromatic rings that interrupt chain packing and increase free volume. 相似文献
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In this letter, we submit our comments on recently published paper titled “Effects of temperature dependent fluid properties and variable Prandtl number on the transient convective flow due to a porous rotating disk by Alam et al. (Meccanica 49: 2439–2451, 2014)”. Authors of this paper have attempted to present similarity solutions in the paper. We comment in this letter is that the similarity transformations considered in Alam et al. (Meccanica 49: 2439–2451, 2014) are not correct and thus results are leading to invalid conclusions. 相似文献
250.
Non-linear vibration of a variable speed rotating beam is analyzed in this paper. The coupled longitudinal and bending vibration of a beam is studied and the governing equations of motion, using Hamilton’s principle, are derived. The solutions of the non-linear partial differential equations of motion are discretized to the time and position functions using the Galerkin method. The multiple scales method is then utilized to obtain the first-order approximate solution. The exact first-order solution is determined for both the stationary and non-stationary rotating speeds. A very close agreement is achieved between the simulation results obtained by the numerical integration method and the first-order exact solution one. The parameter sensitivity study is carried out and the effect of different parameters including the hub radius, structural damping, acceleration, and the deceleration rates on the vibration amplitude is investigated. 相似文献