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991.
S. M. Arabei D. V. Novik T. A. Pavich K. N. Solov’ev 《Journal of Applied Spectroscopy》2006,73(4):511-521
We have studied the fluorescence and fluorescence excitation spectra at 300 K, 77 K, and 4.2 K for silicate gel matrices colored
with meso-tetrapropylporphin by impregnation of the matrix with a solution of the pigment. Comparison of the data obtained
with the absorption spectra in acidified solutions and analysis of the low-temperature fine-structure vibronic spectra, and
also taking into account data obtained earlier for octaethylporphin in a xerogel showed formation of two cationic forms of
meso-tetrapropylporphin in the gel matrix: the short-wavelength form has a dicationic structure, while the long-wavelength form
has a monocationic structure. We have traced out the correlations of the vibrational structure in the spectra of the dicationic
form with data for the porphin dication, and we have drawn a number of conclusions concerning the normal vibrational modes
that are active in the vibronic fluorescence and absorption spectra of the studied cationic forms. Using the AM1 semiempirical
quantum chemical method, we optimized the geometry of the mesotetrapropylporphin dication: the most stable of the possible
conformers is the dication structure with saddleshaped macrocycle nonplanarity.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 4, pp. 453–461, July–August, 2006. 相似文献
992.
Ion synthesis and laser annealing of Cu nanoparticles in Al2O3 总被引:1,自引:0,他引:1
A.L. Stepanov V.N. Popok D.E. Hole I.B. Khaibullin 《Applied Physics A: Materials Science & Processing》2002,74(3):441-446
Al2O3 samples with Cu nanoparticles, synthesised by ion implantation at 40 keV with a dose of 1×1017 ion/cm2 and a current density from 2.5 to 12.5 μA/cm2, were annealed using ten pulses from a KrF excimer laser with a single pulse fluence of 0.3 J/cm2. The copper depth distribution, formation and modification of metal nanoparticles under the ion implantation and laser treatment
were studied by Rutherford backscattering (RBS), energy dispersive X-ray (EDX) analysis, atomic force microscopy (AFM) and
optical spectroscopy. It was found that laser annealing leads to a reduction in the nanoparticle size without diffusion of
metal atoms into the bulk. The change in particle size and the possibility for oxidation of the copper particles are examined
in the framework of Mie theory. Calculations presented show that under excimer laser treatment, Cu nanoparticles are more
likely to be reduced in size than to undergo oxidation.
Received: 19 April 2001 / Accepted: 7 November 2001 / Published online: 23 January 2002 相似文献
993.
R. A. Wind P. D. Majors K. R. Minard E. J. Ackerman D. S. Daly G. R. Holtom B. D. Thrall T. J. Weber 《Applied magnetic resonance》2002,22(2):145-158
Confocal fluorescence optical microscopy and magnetic resonance microscopy are each used to study live cells in a minimally invasive way. Both techniques provide complementary information. Therefore, by examining cells simultaneously with both methodologies, more detailed information is obtained than is possible with each microscope individually. In this paper two configurations of a combined confocal and magnetic resonance microscope are described. The first configuration is capable of studying large single cells or three-dimensional cell agglomerates, whereas the second configuration is designed for the investigation of monolayers of mammalian cells. In both cases the sample compartment is part of a temperature regulated perfusion system. Images obtained with the combined system are shown forXenopus laevis oocytes, model JB6 tumor spheroids, and a single layer of Chinese hamster ovary cells. Finally, potential applications of the combined microscope are discussed. 相似文献
994.
Partially supported by NSF grant DMS-8701746 相似文献
995.
P G Stelmachowicz D E Lewis L L Larson W Jesteadt 《The Journal of the Acoustical Society of America》1987,81(6):1881-1887
Growth-of-masking functions were obtained from 19 normal and 5 hearing-impaired listeners using a simultaneous-masking paradigm. When masker and probe frequency are identical, the slope of masking approximates 1.0 for both normal-hearing and impaired listeners. For masker frequencies less than or greater than probe frequency, the slopes for impaired listeners are shallower than those of normals. These findings are consistent with previously reported physiological data (single-fiber rate versus level and AP masking functions) for animals with induced cochlear lesions. Results are discussed in terms of a potential masking technique to estimate the growth of response in normal and impaired ears. 相似文献
996.
L. G. Marcassa V. A. Nascimento L. L. Caliri A. Caires D. V. Magalhães V. S. Bagnato 《Laser Physics》2006,16(12):1722-1725
In this paper, we report observation of an enhancement of the ground state molecule Rb2 formation in a Rb magneto-optical trap due to a photoassociation laser. Such an enhancement effect is due to flux enhancement of atomic pairs at short internuclear distances. Our experimental observations consist in the measurement of the molecular formation rate constant due to a probe laser as a function of the trap laser intensity. The results are compared with a simple semi-classical model, showing good agreement. We conclude that the production of cold Rb2 may be enhanced using appropriate laser parameters; this may be useful for future experiments involving production and trapping of ultracold ground state molecules. 相似文献
997.
A model of a divacancy which explains a number of experimental facts for Ge exposed to a flow of accelerated electrons at temperature T=77 K is proposed. The model explains the absence of photoconduction associated with photoexcitation of infrared absorption bands at 0.44 and 0.52 eV corresponding to divacancies; the difference in the values of activation energy for divacancy energy levels determined by optical and electrical methods; and the existence of the limiting position of the Fermi level in the forbidden gap in the case of irradiation with large radiation fluxes. 相似文献
998.
This paper summarizes a set of novel techniques for obtaining optical transformations, which are useful tools for signal processing. Then the paper focuses on deriving several interesting discrete transformations. The discussed transforms include continuous fractional transformations, hybrid transforms and discrete transform kernels. 相似文献
999.
I. G. Alekseev P. E. Budkovsky V. P. Kanavets L. I. Koroleva B. V. Morozov V. M. Nesterov V. V. Ryltsov D. N. Svirida A. D. Sulimov V. V. Zhurkin Yu. A. Beloglazov A. I. Kovalev S. P. Kruglov D. V. Novinsky V. A. Shchedrov V. V. Sumachev V. Yu. Trautman N. A. Bazhanov E. I. Bunyatova 《Physics of Atomic Nuclei》2002,65(2):220-228
New experimental data on the spin-rotation parameters A and R measured for elastic π ± p scattering in the resonance region and on the asymmetry in pC scattering at primary momenta in the range 1.35–2.02 GeV/c, as well as in quasielastic proton scattering on nuclei in the same momentum range, are summarized. All these data were recently obtained by using the proton synchrotron installed at the Institute of Theoretical and Experimental Physics (ITEP, Moscow). The spectrum and features of seven isospin-3/2 baryon resonances that form a peak in the total cross section at a c.m. energy of 1.9 GeV are analyzed on the basis of new data on the parameters A and R, and the results of this analysis are presented. The experiments surveyed in this article were performed by a collaboration of researchers from ITEP and the Petersburg Nuclear Physics Institute (PNPI, Gatchina), the ITEP-PNPI collaboration. 相似文献
1000.
Maksimov R. D. Zicans J. Ivanova T. Negreeva S. N. Plume E. 《Mechanics of Composite Materials》2002,38(2):141-148
The results of experimental and theoretical investigations of elastic and thermophysical properties of poly(vinyl chloride) (PVC) and chlorinated polyethylene (CPE) blends are presented. Eight types of specimens with different ratios of weight contents of PVC and CPE (PVC/CPE = 100/0, 90/10, 80/20, 60/40, 40/60, 20/80, 10/90, and 0/100) were tested. The effect of blend composition on the elastic constants (tensile and shear modulus) is discussed. The data on the thermal conductivity, thermal diffusivity, and heat capacity of the blends investigated are also presented. 相似文献