Metal bis[trifluoromethyl)sulfonyl]amide complexes: highly efficient Friedel-Crafts acylation catalysts

A range of metal bis[(trifluoromethyl)sulfonyl]amide complexes, including many unreported ones, have been synthesised, most of which have been found to be excellent Friedel-Crafts acylation catalysts in the absence of solvent; these reactions have also been carried out in ionic liquids, which allow the catalysts to be recycled and reused.     

Solubilities of the Silver Halides in Aqueous Mixtures of Methanol,Acetonitrile, and Dimethylsulfoxide

Summary.  The solubilities of the silver halides in three non-aqueous solvents: methanol, acetonitrile, and dimethylsulfoxide, and in their aqueous mixtures, are reviewed. Values for the solubility product, K _SO , the enthalpies of solution, Δ _sol H ^o , and the equilibrium products for AgX ⁽ⁱ⁻¹⁾⁻ _i silver halide complexes, β _i , are listed and, where possible, compared. The solvent systems provide examples for three types of mixed aqueous solvent system: aqueous alcohol mixtures and aqueous mixtures with dipolar aprotic solvents that are weakly or strongly basic. The experimental data are discussed in terms of the solvation of the silver and halide ions in the mixed solvents. E-mail: Earle.Waghorne@ucd.ie Received September 30, 2002; accepted October 29, 2002 Published online April 7, 2003 RID="a" ID="a" Dedicated to Prof. Heinz Gamsj?ger on the occasion of his seventieth birthday     

在硅胶表面制备牛血红蛋白分子印迹聚合物

采用表面印迹法, 以乙烯基三甲氧基硅烷修饰的硅胶为载体, 丙烯酰胺为功能单体, N,N-亚甲基双丙烯酰胺为交联剂, 并将改性聚乙烯醇(PVA)作为辅助识别聚合物链(ARPCs)引入聚合体系中, 制备了牛血红蛋白分子印迹聚合物(MIP). 实验使用红外光谱分析了改性PVA的结构特征, 用扫描电镜(SEM)观察MIP的表面形貌, 考察了ARPCs的含量对MIP吸附性能的影响. 吸附动力学实验研究表明, 聚合体系中ARPCs的引入使MIP对模板牛血红蛋白(BHb)的吸附量明显提高|十二烷基磺酸钠-聚丙烯酰胺凝胶电泳(SDS-PAGE)结果显示, MIP对BHb的特异性吸附能力明显提高.     

The physical origin of the land–ocean contrast in lightning activity

New tests and older ideas are explored to understand the origin of the pronounced contrast in lightning between land and sea. The behavior of islands as miniature continents with variable area supports the traditional thermal hypothesis over the aerosol hypothesis for lightning control. The substantial land–ocean contrast in updraft strength is supported globally by TRMM (Tropical Rainfall Measuring Mission) radar comparisons of mixed phase radar reflectivity. The land–ocean updraft contrast is grossly inconsistent with the land–ocean contrast in CAPE (Convective Available Potential Energy), from the standpoint of parcel theory. This inconsistency is resolved by the scaling of buoyant parcel size with cloud base height, as suggested by earlier investigators. Strongly electrified continental convection is then favored by a larger surface Bowen ratio, and by larger, more strongly buoyant boundary layer parcels which more efficiently transform CAPE to kinetic energy of the updraft in the moist stage of conditional instability. To cite this article: E. Williams, S. Stanfill, C. R. Physique 3 (2002) 1277–1292.     

Dependence of forward deuteron photodisintegration on the D state

The cross section for forward produced protons in deuteron photodisintegration is shown to be moderately sensitive to the % D state of the deuteron. A 4.58% D state model has about half the discrepancy from experiment of a 7.53% model.     

Proton capture by 176Yb in the giant dipole resonance region

The proton capture cross section for the reaction ¹⁷⁶Yb(p, γ)¹⁷⁷Lu has been measured for incident proton energies between 6 and 24 MeV. The excitation function for this deformed nucleus agrees remarkably well with the results of previous studies on spherical nuclei, e.g. ¹⁴²Ce(p, γ)¹⁴³Pr. The results indicate that the giant dipole resonance (GDR) is strongly excited as predicted by the direct-semidirect (DSD) model. It is found that the model describes reasonably well the excitation function. In the low-energy proton range, where the excitation function increases rapidly with proton energy, the observed cross section is significantly higher than the DSD predictions. The difference can only partly be explained by compound nucleus contributions. In the high-energy end, the predicted cross section tends to be too high primarily due to an increasing contribution of direct capture to orbitals with large angular momenta.     

Diet Planning in the Third World by Linear and Goal Programming

The use of linear programming to select diets to meet specific nutritional requirements frequently results in an over-supply of certain nutrients. Nutritional balance is difficult to achieve in diets selected by linear programming owing to the complex inter-relationships of the constraints. Goal programming is presented as a method of achieving nutritional balance in selected diets. An example demonstrating the goal programming approach is followed by a report of an application of the technique to the selection from 150 food raw materials to satisfy the daily nutritional requirements of Thais. The nutritional balance of the raw materials selected by goal programming showed a marked improvement over that selected by linear programming.     

Frequency dependent complex refractive indices of supercooled liquid water and ice determined from aerosol extinction spectra

Complex refractive indices of supercooled liquid water at 240, 253, 263, and 273 K, and ice at 200, 210, and 235 K in the mid infrared from 460 to 4000 cm(-1) are reported. The results were obtained from the extinction spectra of small (micron-size) aerosol particles, recorded using the cryogenic flow tube technique. An improved iterative procedure for retrieving complex refractive indices from extinction measurements is described. The refractive indices of ice determined in the present study are in good agreement with data reported earlier. The temperature region and range of states covered in the present work are relevant to the study of upper tropospheric and stratospheric aerosols and clouds.