Dynamic mechanical thermal analysis transitions of partially and fully substituted cellulose fatty esters

The main transitions of cellulose fatty esters with different degrees of substitution (DSs) were investigated with dynamic mechanical thermal analysis. Two distinct main relaxations were observed in partially substituted cellulose esters (PSCEs). They were attributed to the glass‐transition temperature and to the chain local motion of the aliphatic substituents. The temperatures of both transitions decreased when DS or the number of carbon atoms (n) of the acyl substituent increased. Conversely, all the transitions of fully substituted cellulose esters occurred within a narrow temperature range, and they did not vary significantly with n. This phenomenon was explained by the formation of a crystalline phase of the fatty substituents. The presence of few residual OH groups in PSCEs was responsible for a large increase in the storage bending modulus, and it eliminated the effect of n on damping. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 281–288, 2003     

Projective varieties with projectively equivalent singular 0-dimensional sections

Fix integers m, n such that 1 ≤ m ≤ n ? 3. Let X ? Pⁿ be an integral non-degenerate m-dimensional variety. Assume either char(K) = 0 or char(K) > deg(X). Here we prove that all general 0-dimensional sections of X containing a tangent vector to a smooth point of X are protectively equivalent if and only if n ? m + 1 ≤ deg(X) ≤ n ? m + 2.     

Decrease in the group velocity of a light pulse in the Bose-Einstein condensate of a dilute gas

A semiclassical theory of electromagnetically induced transparency in a Bose-Einstein condensate is considered. A nonlinear Schrödinger equation that describes the interaction of the Bose-Einstein condensate with an electromagnetic field is derived. An analysis of the obtained solutions to this equation demonstrates a decrease in the group velocity of the light pulse.     

Photoluminescence of liquid-crystal azo derivatives in nanopores

Optics and Spectroscopy - The fluorescence of the nematic liquid crystal n-butyl-n′-methoxyazoxybenzene (BMAOB) in the form of a layer and in porous glasses with pores of different diameter...     

Martensite Transformation in Nanoparticles and Nanomaterials

Journal of Nanoparticle Research - It was shown that the thermoelastic martensite transformation B2 ? B19 inside nanoparticles surrounded by amorphous matrix in Ni–Ti–Cu alloys as...     

On the Sum of Roots of a Closed Set

An invariant of a closed set that is equal to the sum of roots is introduced. For a closed subset in a root system, we describe symmetric and special parts and its stabilizer in the Weyl group by means of the sum of roots. We determine associated bases with respect to which the closed set has the simplest form. All possible values of the root sum are found. Bibliography: 9 titles.     

Generalized Darboux transform in the Ishimori magnet model on the background of spiral structures

The integration procedure based on the generalized Darboux transform is suggested for the Ishimori magnet model. Exact solutions are constructed for the model on the background of spiral structures. The possibility of phase transition in the system is hypothesized.     

Optical limiters and diffraction elements based on a COANP-fullerene system: Nonlinear optical properties and quantum-chemical simulation

The results of optical study and quantum-chemical simulation of a conjugated organic system, 2-cyclooctylamino-5-nitropyridine (COANP)-fullerene, performed to determine its potential for application as a limiter of visible and near-IR laser radiation and as a material for diffraction elements in systems for reversible recording of optical information, are presented. Complexation between a COANP molecule and fullerene is considered as one of the main mechanisms responsible for the corresponding properties of this system. For the first time, nonlinear optical characteristics of COANP-C₆₀ and COANP-C₇₀ systems are comparatively studied and the intermolecular interaction between a COANP molecule and fullerene is analyzed on the quantum-chemical level.