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991.
Matveeva E. D. Podrugina T. A. Grishin Yu. K. Tkachev V. V. Zhdankin V. V. Aldoshin S. M. Zefirov N. S. 《Russian Journal of Organic Chemistry》2003,39(4):536-541
A mixed phosphonium-iodonium ylide, phenyliodoniumethoxycarbonylmethylenetriphenylphosphorane borofluoride, was synthesized. Its structure was established by means of X-ray diffraction analysis. Temperature dependence of 1H, 13C, and 31P spectra of the ylide synthesized was investigated. A dynamic equilibrium between Z and E-isomers was observed. 相似文献
992.
Curtis T. Mcmullen 《Acta Mathematica》2003,191(2):191-223
993.
A. Henderson 《Mathematische Zeitschrift》2003,243(1):127-143
We prove that the local intersection cohomology of nilpotent orbit closures of cyclic quivers is trivial when the two orbits
involved correspond to partitions with at most two rows. This gives a geometric proof of a result of Graham and Lehrer, which
states that standard modules of the affine Hecke algebra of GLd corresponding to nilpotents with at most two Jordan blocks are multiplicity-free.
Received: 7 February 2002 / Published online: 8 November 2002 相似文献
994.
It is proved that every finite group for which the degrees of its nonmonomial characters are primes is solvable. The proof uses the classification of the finite simple groups. 相似文献
995.
We obtain a lower bound on the number of prime divisors of integers whose g-ary expansion contains a fixed number of nonzero digits.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
996.
997.
998.
O. A. Alekseeva N. I. Sorokina I. A. Verin T. Yu. Losevskaya V. I. Voronkova V. K. Yanovskii V. I. Simonov 《Crystallography Reports》2003,48(2):205-211
This study is a continuation of research into the atomic structure and physical properties of niobium-doped potassium titanyl phosphate crystals, KTiOPO4 (KTP: Nb). Crystals containing 7 and 11 at. % of niobium were grown and studied. With an increase in niobium content, the number of vacancies and additional potassium positions in the structure also increase. This fact accounts for an increase in both the intensities of relaxation peaks and the conductivity of KTP: Nb crystals. 相似文献
999.
I. P. Kuranova K. M. Polyakov E. A. Smirnova W. E. Höhne V. S. Lamzin R. Meijer 《Crystallography Reports》2003,48(6):953-958
Crystals of Saccharomyces cerevisiae inorganic pyrophosphatase suitable for X-ray diffraction study were grown by cocrystallization of the enzyme with cobalt chloride and imidodiphosphate. Saccharomyces cerevisiae is a metal-dependent enzyme which catalyzes hydrolysis of inorganic pyrophosphate to orthophosphate. The three-dimensional structure of this enzyme was solved by the molecular-replacement method and refined at 1.8 Å resolution to an R factor of 19.5%. Cobalt and phosphate ions were revealed in the active centers of both identical subunits (A and B) of the pyrophosphatase molecule. In subunit B, a water molecule was found between two cobalt ions. It is believed that this water molecule acts as an attacking nucleophile in the enzymatic cleavage of the pyrophosphate bond. It was demonstrated that cobalt ions and a phosphate group occupy only part of the potential binding sites (two chemically identical and crystallographically independent subunits have different binding sites). The arrangement of ligands and the structure of the nucleophile-binding site are discussed in relation to the mechanism of action of the enzyme and the nature of the metal activator. 相似文献
1000.
V. I. Tsoy 《Optics and Spectroscopy》2003,94(4):607-612
In the framework of the matrix formulation of the coupled plane wave approach, a method is proposed for increasing the stability of the numerical analysis of vector electromagnetic fields in periodic structures, including dielectric and metallic anisotropic layers and relief boundaries. 相似文献