Alkohole

Ohne Zusammenfassung     

Statistical hadronization and hadronic microcanonical ensemble I

We present a full treatment of the microcanonical ensemble of the ideal hadron-resonance gas starting from a quantum-mechanical formulation which is appropriate for the statistical model of hadronization. By using a suitable transition operator for hadronization we are able to recover the results of the statistical theory, particularly the expressions of the rates of different channels. Explicit formulae are obtained for the phase space volume or density of states of the ideal relativistic gas in quantum statistics as a cluster decomposition, generalizing previous ones in the literature. The problem of the computation of averages in the hadron gas microcanonical ensemble and the comparison with canonical ones will be the main subject of a forthcoming second paper.Received: 8 July 2003, Revised: 17 October 2003, Published online: 5 May 2004     

Pyroelectric effect in lead-magnoniobate-based solid solutions

A coordinated study of the dielectric, electrostriction, and pyroelectric properties of the lead-magnoniobate-based ceramic solid solutions 0.9PbMg_1/3Nb_2/3O₃-0.1PbTiO₃ and 0.55PbMg_1/3Nb_2/3O₃-0.45PbSc_1/2Nb_1/2O₃ conducted at the relaxor transition temperatures is reported. Electromechanical coupling stimulated by the giant electrostriction effect is shown to play an essential part in the pyroelectric effect.     

Large deviations for random walks in a mixing random environment and other (non‐Markov) random walks

We extend a recent work by S. R. S. Varadhan [8] on large deviations for random walks in a product random environment to include more general random walks on the lattice. In particular, some reinforced random walks and several classes of random walks in Gibbs fields are included. © 2004 Wiley Periodicals, Inc.     

Base-Catalyzed Reaction of Cyanoalkylphosphonates with Methanol

The equilibrium conversion of nitriles in the reaction of cyanoalkylphosphonates with methanol in the presence of sodium methylate, as determined by potentiometric titration with perchloric acid in nitromethane, varies from 58 to 17.7%. The practical yields of imidates were evaluated by a preparative procedure of isolation of purified imidates from the reaction mixtures (56-14%). Because of the low conversions of nitriles, the reaction is expedient to use only for preparing alkyl (dialkoxyphosphoryl)acetimidates.     

Paradigms and Paradoxes: Energetics of Aqueous Oxyanions of Nonmetals and Metalloids

The enthalpies of formation of simple nonmetal or metalloid oxyanions in aqueous solution are discussed. Archival values are cited and estimates are made. Trends prove evasive.     

Effects of Moisture and Stresses on the Structure and Properties of Polyester Resin

The results of a complex study of structural changes in a cured Norpol 440 polyester resin under the action of damp environment and mechanical loading are presented. A considerable effect of absorbed moisture on the structure and some characteristics of the material is revealed by using thermophysical methods and X-ray diffractometry. The joint effect of moisture and mechanical stress is estimated by investigating the creep in stationary and nonstationary moisture conditions. The anisotropy of the material structure formed during creep is evaluated from the results of dilatometric measurements. It is found that the degree of anisotropy of the material after creep accompanied by moisture sorption is higher than that after creep in the conditions of moisture equilibrium with atmosphere. It is established that the aftercure and relaxation of the residual creep deformation come to an end at heating to 80-85°C. At a further rise in temperature and repeated heating, changes in the material structure are not observed.     

Algebra with Quadratic Commutation Relations for an Axially Perturbed Coulomb–Dirac Field

The motion of a particle in the field of an electromagnetic monopole (in the Coulomb–Dirac field) perturbed by an axially symmetric potential after quantum averaging is described by an integrable system. Its Hamiltonian can be written in terms of the generators of an algebra with quadratic commutation relations. We construct the irreducible representations of this algebra in terms of second-order differential operators; we also construct its hypergeometric coherent states. We use these states in the first-order approximation with respect to the perturbing field to obtain the integral representation of the eigenfunctions of the original problem in terms of solutions of the model Heun-type second-order ordinary differential equation and present the asymptotic approximation of the corresponding eigenvalues.     

Conic Formulation for l p -Norm Optimization

In this paper, we formulate the l _p -norm optimization problem as a conic optimization problem, derive its duality properties (weak duality, zero duality gap, and primal attainment) using standard conic duality and show how it can be solved in polynomial time applying the framework of interior-point algorithms based on self-concordant barriers.