Preparation and Evaluation of Calix[8]arene Bonded Silica Stationary Phase for High Performance Liquid Chromatography

In recent years, calix[n]arenes (n=4,5,6,7,8) as stationary phase have been introduced into the field of chromatography. In our previous works, we have synthesized, characterized and evaluated two different silica-bonded calix[n]arenes (n=4,6) stationary phase, on which the chromatographic behavior of PAHs, positional isomers,nucleosides and bases was investigated. In this paper we report the preparation of calix[8]arene bonded silica stationary phase, and characterization of its structure and chromatographic behavior.     

An analytical approach to reconstruction of axisymmetric defects in pipelines using T(0, 1) guided waves

Torsional guided waves have been widely utilized to inspect the surface corrosion in pipelines due to their simple displacement behaviors and the ability of longrange transmission. Especially, the torsional mode T (0, 1), which is the first order of torsional guided waves, plays the irreplaceable position and role, mainly because of its non-dispersion characteristic property. However, one of the most pressing challenges faced in modern quality inspection is to detect the surface defects in pipelines with a high level of accuracy. Taking into account this situation, a quantitative reconstruction method using the torsional guided wave T (0, 1) is proposed in this paper. The methodology for defect reconstruction consists of three steps. First, the reflection coefficients of the guided wave T (0, 1) scattered by different sizes of axisymmetric defects are calculated using the developed hybrid finite element method (HFEM). Then, applying the boundary integral equation (BIE) and Born approximation, the Fourier transform of the surface defect profile can be analytically derived as the correlative product of reflection coefficients of the torsional guided wave T (0, 1) and the fundamental solution of the intact pipeline in the frequency domain. Finally, reconstruction of defects is precisely performed by the inverse Fourier transform of the product in the frequency domain. Numerical experiments show that the proposed approach is suitable for the detection of surface defects with arbitrary shapes. Meanwhile, the effects of the depth and width of surface defects on the accuracy of defect reconstruction are investigated. It is noted that the reconstructive error is less than 10%, providing that the defect depth is no more than one half of the pipe thickness.     

基于球形压电陶瓷的耐压水听器

利用球形压电陶瓷自身所具有的耐压能力,采用径向极化空气背衬压电球壳换能器作为声学接收敏感元件,设计并制作了一种球形耐压水听器。首先对其低频开路接收灵敏度和谐振频率等声学特性进行了分析和有限元仿真,然后对其强度和稳定性等耐压性能进行了分析和有限元仿真,最后对其声学性能和耐压能力进行了测试。测试表明,该球形耐压水听器的直径为36 mm,工作频段为50 Hz～10 kHz,低频接收灵敏度为-198.4 dB (0 dB=1 V/μPa),等效自噪声谱级为46.5 dB@1 kHz,其耐压深度可达3000 m。该耐压水听器为大深度水听器设计提供了参考,在深水声学领域具有重要的应用价值。     

退色光度法测定痕量Cr(Ⅲ)的研究

基于在ＯＰ存在下,痕量Ｃｒ（Ⅲ）可使萘酚绿Ｂ退色的反应,本文提出了一种应用新的退色光度法测定痕量Ｃｒ（Ⅲ）的方法,该方法线性范围为０．２４－３．００μｇ．ｍＬ＾－１,检出限为２．０５μｇ．ｍＬ＾－１。该方法用于模拟样品的测定,回收率为１００％－１０８％。     

稠环芳烃在烷基膦酸改性锆镁复合氧化物固定相上的反相液相色谱保留行为

以稠环芳烃为探针 ,考察了烷基膦酸改性锆镁复合氧化物材料的反相色谱性能。研究了稠环芳烃类化合物的结构与其保留值的关系 ,比较了烷基膦酸改性锆镁复合氧化物固定相和十八烷基键合硅胶 Zorbax ODS对稠环芳烃异构体的选择性 ,并对可能的保留机理进行了讨论。以甲醇 -水 (体积比为 75∶ 2 5)为流动相 ,在烷基膦酸改性锆镁复合氧化物固定相上分离了 8种稠环芳烃类化合物     

Pseudo-invariant Eigen-operator for Deriving Energy-Level Gap for Jaynes-Cummings Model

We extend the concept of invariant eigen-operator to pseudo-invariant eigen-operator case through analyzing the standard Jaynes-Cummings model. We find the pseudo-invariant eigen-operator in terms of supersymmetric generators of this model, which diretly leads to the energy-level gap for Jaynes-Cummings Hamiltonian.     

聚合物湍流减阻流动的直接数值模拟研究

采用离散弹性元素.珠簧哑铃模型方程模拟了聚合物减阻流动.模拟出了高分子聚合物浓度的空间分布.得到了减阻率与粘弹性应力,雷诺应力等的定量关系.分析了聚合物湍流结构和离散弹性元素模型中弹性系数的关系.     

A new generalization of Hardy–Berndt sums

In this paper, we construct a new generalization of Hardy–Berndt sums which are explicit extensions of Hardy–Berndt sums. We express these sums in terms of Dedekind sums s _r (h, k : x, y|λ) with x?=?y?=?0 and obtain corresponding reciprocity formulas.     

动态加权的多频段距离特征量数据融合方法

距离特征量反映了目标距离变化规律,该观测量可由基于LOFAR谱图的距离特征量提取方法得到。为解决单一频段提取的距离特征量精度不高的问题,本文基于最优加权平均法,提出了多频段距离特征量值提取技术。针对该方法在实际应用中无法准确得到距离特征量解算值误差的标准差,提出了一种对方差进行实时估计的动态加权融合方法。试验数据处理结果表明,融合后精度明显提高。