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31.
This paper is mainly concerned with the computational complexity of determining whether or not the vertices of a graph can be partitioned into equal sized subsets so that each subset induces a particular type of graph. Many of the NP-completeness results are for planar graphs. These are proved using a planar version of 3-dimensional matching.  相似文献   
32.
Conical structures formed in 157 nm laser-ablated polycarbonate exhibit a well-defined fringe structure with a period of a few 100 nm surrounding the cone base. Experiments and modelling studies of the interference produced by these micro-conical mirrors are shown to provide a means of measuring the spatial coherence of the highly multi-mode 157 nm laser.  相似文献   
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This paper gives examples of embeddings of root systems of Coxeter groups, including sporadic embeddings of standard real root systems in other standard real root systems, and, for a general Coxeter group, an embedding of its universal symmetric root system over commutative rings into the standard real root system of a simply laced Coxeter group.  相似文献   
35.
    
A fully quantitative theory of the relationship between protein conformation and optical spectroscopy would facilitate deeper insights into biophysical and simulation studies of protein dynamics and folding. In contrast to intense bands in the far-ultraviolet, near-UV bands are much weaker and have been challenging to compute theoretically. We report some advances in the accuracy of calculations in the near-UV, which were realised through the consideration of the vibrational structure of the electronic transitions of aromatic side chains.  相似文献   
36.
    
Early detection of pathogenic microorganisms is pivotal to diagnosis and prevention of health and safety crises. Standard methods for pathogen detection often rely on lengthy culturing procedures, confirmed by biochemical assays, leading to >24 h for a diagnosis. The main challenge for pathogen detection is their low concentration within complex matrices. Detection of blood-borne pathogens via techniques such as PCR requires an initial positive blood culture and removal of inhibitory blood components, reducing its potential as a diagnostic tool. Among different label-free microfluidic techniques, inertial focusing on microscale channels holds great promise for automation, parallelization, and passive continuous separation of particles and cells. This work presents inertial microfluidic manipulation of small particles and cells (1–10 μm) in curved serpentine glass channels etched at different depths (deep and shallow designs) that can be exploited for (1) bacteria preconcentration from biological samples and (2) bacteria-blood cell separation. In our shallow device, the ability to focus Escherichia coli into the channel side streams with high recovery (89% at 2.2× preconcentration factor) could be applied for bacteria preconcentration in urine for diagnosis of urinary tract infections. Relying on differential equilibrium positions of red blood cells and E. coli inside the deep device, 97% red blood cells were depleted from 1:50 diluted blood with 54% E. coli recovered at a throughput of 0.7 mL/min. Parallelization of such devices could process relevant volumes of 7 mL whole blood in 10 min, allowing faster sample preparation for downstream molecular diagnostics of bacteria present in bloodstream.  相似文献   
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38.
In this paper we demonstrate the use of picosecond time-resolved infrared spectroscopy (ps-TRIR) to monitor the early structural dynamics of DNA bases and polydeoxynucleotides following UV excitation in solution.  相似文献   
39.
We analyse thegeneralised assignment problem under the assumption that all coefficients are drawn uniformly and independently from [0, 1]. We show that such problems can be solved exactly with high probability, in a well-defined sense. The results are closely related to earlier work of Lueker, Goldberg and Marchetti-Spaccamela and ourselves.Supported by NATO grant RG0088/89.Supported by NSF grant CCR-8900112 and NATO grant RG0088/89.  相似文献   
40.
The results of a 13C NMR spectral investigation involving 5,6-dihydro-1,4-oxathiins, 1,4-tetrahydro[9,10]benzoxathiin, trans-tetrahydro-1,4-benzoxathiin, and the corresponding sulfoxides and sulfones are reported. An interpretation involving a dipolar structure with (2p→2p)π conjugation as opposed to (2p→3d)π interactions with the vinyloxy sulfides seems consistent with trends in the 13C NMR shifts. For the sulfoxides and sulfones, the substitutent-induced chemical shift (SCS) effects at the β vinylic carbons (βSO and βSO2 effects) are considerably less than those at sp3 carbons. The γSO and γSO2 values at the sp2γ carbons indicate deshielding, in contrast to the shielding at the sp3 carbons.  相似文献   
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