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21.
V. P. Litvinov Yu. A. Sharanin M. P. Goncharenko V. D. Dyachenko A. M. Shestopalov 《Russian Chemical Bulletin》1991,40(8):1675-1681
The reaction of 3-cyano-1,4-dihydropyridine-2-thiolates and the corresponding selenolates with allyl bromide gave 2-allylthio- and 2-allylseleno-3-cyano-1,4-dihydropyridines, which, upon heating in various solvents or in the solid state, undergo [3,3]-sigmatropic rearrangement to give 3-cyano-3-allyl-1,2,3,4-tetrahydropyridine-2-thiones and the corresponding selenones. The resultant pyridinethiones are alkylated by alkyl halides at the sulfur atom and are oxidized by iodine to give disulfides.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1888–1895, August, 1991. 相似文献
22.
23.
The review summarizes and systematizes data published over the past decade on the use of aliphatic aldehydes in the synthesis of six- and seven-membered carbo- and heterocycles, bicyclic compounds, and macrocycles. Biological activity and synthetic potential of the resulting compounds were also considered. The data are classed according to the ring type formed. 相似文献
24.
4-Alkyl-6-amino-4-N 3,N 5-diaryl-2-thioxo-1,2,3,4-tetrahydropyridine-3,5-dicarboxamides were obtained via tandem synthesis involving the Knoevenagel reaction, Michael reaction and intramolecular condensation. Alkylation of the obtained dicarboxamides proceeds regioselectively at the S atom to form the corresponding thioethers. Structure of 6-allylsulfanyl-2-amino-4-isobutyl-N 3,N 5-di-m-tolyl-3,4-dihydropyridine-3,5-dicarboxamide was uniquely determined by XRD analysis. 相似文献
25.
V. D. Dyachenko E. N. Karpov I. A. Feskov 《Russian Journal of General Chemistry》2013,83(9):1716-1723
New 4-alkyl-6-amino-N 3,N 5-diaryl-2-thioxo-1,2,3,4-tetrahydropyridine-3,5-dicarboxamides have been prepared via enantioselective reaction of 3-amino-N-aryl-3-thioxopropanamides with N-aryl-2-cyanoacetamide and aliphatic aldehydes. The prepared products can be regioselectively alkylated at sulfur atom. 相似文献
26.
Dyachenko I. V. Dyachenko V. D. Dorovatovskii P. V. Khrustalev V. N. Nenajdenko V. G. 《Russian Chemical Bulletin》2021,70(11):2145-2155
Russian Chemical Bulletin - The tandem Knoevenagel—Michael—intramolecular ammonolysis—alkylation reaction was used to synthesize functionalized tetrahydropyridones. The molecular... 相似文献
27.
I. V. Dyachenko R. I. Vas’kevich M. V. Vovk 《Russian Journal of Organic Chemistry》2014,50(2):263-270
2-[Allyl(propargyl)sulfanyl]pyrido[3,4-d]pyrimidin-4-ones at heating in polyphosphoric acid undergo an intramolecular cyclization with the formation of pyrido[4,3-e]thiazolo-[3,2-a]pyrimidin-5-ones of angular structure. Under similar conditions the cyclization of 2-(cinnamylsulfanyl)pyrido[3,4-d]-pyrimidin-4-one results in a linear pyrido[3′,4′:4,5]pyrimido-[2,1-b][1,3]thiazin-6-one. The iodocyclization of the same substrates affords the corresponding 9-(iodomethyl)(iodomethylidene)pyrido[4,3-e][1,3]thiazolo-[3,2-a]pyrimidin-5-ones and 3-iodopyrido[3′,4′:4,5]pyrimido[2,1-b][1,3]thiazin-6-one of angular structure. 9-(Iodomethyl)-8,9-dihydro-5H-pyrido[4,3-e][1,3]thiazolo[3,2-a]pyrimidin-5-one treated with sodium azide gave 9-(azidomethyl) derivative whose cyclization with substituted alkynes in the presence of copper compounds provided pyrido [4,3-e][1,3]thiazolo[3,2-a]pyrimidinylmethyltriazoles. 相似文献
28.
The multicomponent condensation of malononitrile, hydrogen sulfide, aryl or
hetaryl aldehydes, 1,3-dicarbonyl compounds and alkylating reagents afforded
functionalized nitriles and esters of 6-alkylsulfanyl-1,4-dihydronicotinic
acids, their aromatic analogues and 1,4-dihydrothieno[2,3-b]pyridines. 相似文献
29.
Dyachenko V. D. Sukach S. M. Morkovnik A. S. 《Russian Journal of Organic Chemistry》2020,56(6):949-973
Russian Journal of Organic Chemistry - The review systematizes published data on the use of 2-acylcycloalkanones in organic synthesis. The data are arranged in accordance with the type of products... 相似文献
30.
A. V. Fokin V. I. Dyachenko V. D. Sviridov A. Yu. Sizov N. D. Chkanikov 《Russian Chemical Bulletin》1996,45(5):1178-1181
C-Hydroxy- andC-aminoalkylation of iminodibenzyl, iminostilbene, phenoxazine, and phenothiazine with hexafluoroacetone, methyl trifluoropyruvate, and their trifluoroacetylimines were investigated. The substitution occurred at one or severalpara- andortho-positions to the N atom of the heterocycles. In the case of methyl trifluoropyruvate and its derivative the substitution in theortho-position was accompanied by the formation of lactams.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1239–1242, May, 1996. 相似文献