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91.
The electronic spectrum of Dewar benzene [bicyclo (2.2.0) hexa-2,5-diene] consists of two transitions above 185 nm. The lower energy transition is structureless and broad with a maximum at 205 nm. The other system begins around 200 nm and shows initially well-defined vibronic structure on a background of increasing continuous absorption, but becomes structureless by 185 nm. Arguments are presented that the two excited states involved in the spectrum are 1A2 arising from a excitation, and 1B1 from a excitation involving the strained σ-bridge bond in Dewar benzene. The interrelationships both photochemical and photophysical of the (CH)6 potential surface are discussed. 相似文献
92.
Eguchi K Enomoto S Furuno K Ikeda H Ikeda K Inoue K Ishihara K Iwamoto T Kawashima T Kishimoto Y Koga M Koseki Y Maeda T Mitsui T Motoki M Nakajima K Ogawa H Owada K Piquemal F Shimizu I Shirai J Suekane F Suzuki A Tada K Tajima O Takayama T Tamae K Watanabe H Busenitz J Djurcic Z McKinny K Mei DM Piepke A Yakushev E Berger BE Chan YD Decowski MP Dwyer DA Freedman SJ Fu Y Fujikawa BK Goldman J Heeger KM Lesko KT Luk KB Murayama H Nygren DR Okada CE Poon AW Steiner HM Winslow LA Horton-Smith GA 《Physical review letters》2004,92(7):071301
Data corresponding to a KamLAND detector exposure of 0.28 kton yr has been used to search for nu;(e)'s in the energy range 8.3相似文献
93.
94.
Dr. Romain Tessier Prof. Dr. Raj Kumar Nandi Brendan G. Dwyer Dr. Daniel Abegg Charlotte Sornay Dr. Javier Ceballos Stéphane Erb Dr. Sarah Cianférani Dr. Alain Wagner Dr. Guilhem Chaubet Prof. Dr. Alexander Adibekian Prof. Dr. Jerome Waser 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(27)
95.
Denis A. Malyshev Danielle A. Pfaff Shannon I. Ippoliti Dr. Gil Tae Hwang Prof. Tammy J. Dwyer Prof. Floyd E. Romesberg 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(42):12650-12659
As part of an ongoing effort to expand the genetic alphabet for in vitro and eventual in vivo applications, we have synthesized a wide variety of predominantly hydrophobic unnatural base pairs and evaluated their replication in DNA. Collectively, the results have led us to propose that these base pairs, which lack stabilizing edge‐on interactions, are replicated by means of a unique intercalative mechanism. Here, we report the synthesis and characterization of three novel derivatives of the nucleotide analogue d MMO2 , which forms an unnatural base pair with the nucleotide analogue d 5SICS . Replacing the para‐methyl substituent of d MMO2 with an annulated furan ring (yielding d FMO ) has a dramatically negative effect on replication, while replacing it with a methoxy (d DMO ) or with a thiomethyl group (d TMO ) improves replication in both steady‐state assays and during PCR amplification. Thus, d TMO –d 5SICS , and especially d DMO –d 5SICS , represent significant progress toward the expansion of the genetic alphabet. To elucidate the structure–activity relationships governing unnatural base pair replication, we determined the solution structure of duplex DNA containing the parental d MMO2 –d 5SICS pair, and also used this structure to generate models of the derivative base pairs. The results strongly support the intercalative mechanism of replication, reveal a surprisingly high level of specificity that may be achieved by optimizing packing interactions, and should prove invaluable for the further optimization of the unnatural base pair. 相似文献
96.
In this work we investigate methods of statistical processing and background fitting of atomic resolution electron energy loss spectrum image (SI) data. Application of principal component analysis to SI data has been analyzed in terms of the spectral signal-to-noise ratio (SNR) and was found to improve both the spectral SNR and its standard deviation over the SI, though only the latter was found to improve significantly and consistently across all data sets analyzed. The influence of the number of principal components used in the reconstructed data set on the SNR and resultant elemental maps has been analyzed and the experimental results are compared to theoretical calculations. 相似文献
97.
Araki T Enomoto S Furuno K Gando Y Ichimura K Ikeda H Inoue K Kishimoto Y Koga M Koseki Y Maeda T Mitsui T Motoki M Nakajima K Nakamura K Ogawa H Ogawa M Owada K Ricol JS Shimizu I Shirai J Suekane F Suzuki A Tada K Takeuchi S Tamae K Tsuda Y Watanabe H Busenitz J Classen T Djurcic Z Keefer G Leonard DS Piepke A Yakushev E Berger BE Chan YD Decowski MP Dwyer DA Freedman SJ Fujikawa BK Goldman J Gray F Heeger KM Hsu L Lesko KT Luk KB Murayama H O'Donnell T Poon AW Steiner HM Winslow LA 《Physical review letters》2006,96(10):101802
The Kamioka Liquid scintillator Anti-Neutrino Detector is used in a search for single neutron or two-neutron intranuclear disappearance that would produce holes in the -shell energy level of (12)C nuclei. Such holes could be created as a result of nucleon decay into invisible modes (inv), e.g., n--> 3v or nn--> 2v. The deexcitation of the corresponding daughter nucleus results in a sequence of space and time-correlated events observable in the liquid scintillator detector. We report on new limits for one- and two-neutron disappearance: tau(n--> inv) > 5.8 x 10(29) years and tau (nn--> inv) > 1.4 x 10(30) years at 90% C.L. These results represent an improvement of factors of approximately 3 and >10(4) and over previous experiments. 相似文献
98.
Anisotropic specimens of MoS2 are obtained by pressing the microcrystalline powder into special die. This inelastic compression results in a rearrangement of the disulfide micro platelets observed by atomic force microscopy and reflected in the macroscopic anisotropy in electrical conductivity in these samples. The conductivity measured parallel and perpendicular to the direction of applied pressure exhibits an anisotropy factor of ∼10 at 1 GPa. This behaviour of the conductivity as a function of applied pressure is explained as the result of the simultaneous influence of a rearrangement of the micro platelets in the solid and the change of the inter-grain distances. 相似文献
99.
In situ xanthate deprotection to generate thiol chain transfer agents for conventional free radical linear and branched vinyl polymerization 下载免费PDF全文
100.
The objective of this study was to determine if topical anesthesia to the larynx and pharynx affects vocal fold motion during dynamic voice evaluation with transnasal flexible endoscopy. Transnasal dynamic laryngeal examinations of 10 patients with no voice complaints were evaluated by five blinded fellowship-trained laryngologists. Each patient was examined before and after application of topical anesthetic. Reviewers rated briskness of right and left vocal fold movement and longitudinal tension on a visual analogue scale. Statistical comparisons were made between individual subject scores before and after anesthetic application. Inter-rater reliability was also assessed. No statistical difference was observed between subject scores before and after anesthetic application. Average intraclass correlation coefficients were 0.643 and 0.591 for pre- and postanesthesia scores, respectively. Application of topical anesthesia to the larynx and pharynx does not affect vocal fold motion. 相似文献