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排序方式: 共有570条查询结果,搜索用时 62 毫秒
61.
A. Burr F. M. Berberich Sprinkmeyer Diedrichs E. Ackermann C. Valencien E. Müller-Hössly G. Cornalba Wuyt Courtoy F. Bordas F. Touplain R. Sanfelici G. Knappe H. Durand W. Gero R. Eichloff H. Bleçkmann L. Mathieu L. Ferré W. D. Kooper E. Oertel A. Kling P. Roy L. Ronnet L. Vandam R. Ledent E. Comanducci T. Jona Tillmans Schneehagen 《Analytical and bioanalytical chemistry》1920,59(5-6):266-273
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In the centrifugal horizontal casting of steel pipes, the normally used rotational speed results in an acceleration of 100 times gravity within the liquid metal layer. Due to such centrifugal forces liquid metal seems to have a body rotation. However metallurgical analysis of pipes show spatial variations in solidification structure which can only originate from recirculating flows. The present study is concerned with the analysis of such stirring motions. Both theoretical and experimental approaches are presented.
Résumé Dans le procédé d'élaboration par coulée centrifuge horizontale de tubes d'acier, la vitesse de rotation utilisée conduit à une accélération de 100 g dans le métal liquide. A cause des forces centrifuges qui en résultent, le métal semble animé d'une rotation en bloc. Cependant, des analyses métallurgiques effectuées sur des tubes ainsi élaborés montrent des variations spatiales de la structure de solidification dont l'origine est la présence d'écoulements de recirculation. La présente étude concerne l'analyse de ces écoulements. Les résultats de ces deux approaches, théorique et expérimentale, sont présentés.相似文献
64.
In order to better understand the metabolic fate of n-3 polyunsaturated fatty acids (PUFAs), an efficient access to symmetrical and unsymmetrical triacylglycerols (TGs), esterified with PUFAs, with known high purity, is required. In this context, we optimized the esterification of a mixture of glycerols protected as dioxane and dioxolane with PUFAs. The kinetics of this reaction depends on various factors, such as the fatty acid chain length and the stereochemistry of the dioxane. Then, one-pot acetal hydrolysis and esterification of hydroxyl groups led to the desired structured TGs without either double bond isomerization or acyl migration (except when symmetrical TGs are acylated with long-chain saturated fatty acids in external positions). PUFAs location on the glycerol backbone was assayed by NMR, HPLC and pancreatic lipase hydrolysis. 相似文献
65.
Fabien Durand Ai-Hua Fan Andrei Yu. Khrennikov Dongdai Lin Franco Vivaldi Yuefei Wang 《P-Adic Numbers, Ultrametric Analysis, and Applications》2011,3(4):359-362
On the occasion of the 60th birthday of Professor Vladimir Sergeevich Anashin, we present a review of his significant scientific
research and related activities. 相似文献
66.
William J. Durand Andrew A. Peterson Felix Studt Frank Abild-Pedersen Jens K. Nørskov 《Surface science》2011,605(15-16):1354-1359
Polycrystalline copper electrocatalysts have been experimentally shown to be capable of reducing CO2 into CH4 and C2H4 with relatively high selectivity, and a mechanism has recently been proposed for this reduction on the fcc(211) surface of copper, which was assumed to be the most active facet. In the current work, we use computational methods to explore the effects of the nanostructure of the copper surface and compare the effects of the fcc(111), fcc(100) and fcc(211) facets of copper on the energetics of the electroreduction of CO2. The calculations performed in this study generally show that the intermediates in CO2 reduction are most stabilized by the (211) facet, followed by the (100) facet, with the (111) surface binding the adsorbates most weakly. This leads to the prediction that the (211) facet is the most active surface among the three in producing CH4 from CO2, as well as the by-products H2 and CO. HCOOH production may be mildly enhanced on the more close-packed surfaces ((111) and (100)) as compared to the (211) facet, due to a change in mechanism from a carboxyl intermediate to a formate intermediate. The results are compared to published experimental data on these same surfaces; the predicted trends in voltage requirements are consistent between the experimental and computational data. 相似文献
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Hydrogenated amorphous-Si/SiO2 (a-Si:H/SiO2) superlattices with different a-Si : H thickness in the range of a few nanometers have been fabricated by ultra high vacuum evaporator (UHV evaporator). The photoluminescence (PL) of our superlattices is observed in the visible spectral region and the peak energy shifts to higher energy as the a-Si : H layer thickness decreases. The temperature dependence of the PL spectra reveals four sub-bands by fitting. Bands at 2.2, 1.9, 1.65 and 1.45 eV are detected and are attributed to E′δ centers, nonbridging-oxygen–hole centers (NBOHC), Si/SiO2 interface and a-Si : H layer, respectively. We explain the overall blueshift of the PL spectra by the modification of the contribution of these sub-bands. 相似文献
69.
C. P. Slichter S. E. Barrett J. A. Martindale D. J. Durand C. H. Pennington C. A. Klug K. E. O’Hara S. M. DeSoto T. Imai J. P. Rice T. A. Friedmann D. M. Ginsberg 《Applied magnetic resonance》1992,3(3-4):423-448
The authors review and up-date their work on Knight shifts, spin-lattice relaxation, and indirect nuclear spin-spin coupling for YBa2Cu3O7 in the superconducting state. The data are analyzed in particular to show what it may indicate about the orbital and spin pairing of the superconducting state. 相似文献
70.