全文获取类型
收费全文 | 1045篇 |
免费 | 34篇 |
国内免费 | 17篇 |
专业分类
化学 | 472篇 |
晶体学 | 9篇 |
力学 | 32篇 |
数学 | 374篇 |
物理学 | 209篇 |
出版年
2023年 | 10篇 |
2022年 | 36篇 |
2021年 | 44篇 |
2020年 | 39篇 |
2019年 | 40篇 |
2018年 | 37篇 |
2017年 | 39篇 |
2016年 | 42篇 |
2015年 | 30篇 |
2014年 | 36篇 |
2013年 | 52篇 |
2012年 | 59篇 |
2011年 | 61篇 |
2010年 | 41篇 |
2009年 | 38篇 |
2008年 | 38篇 |
2007年 | 40篇 |
2006年 | 30篇 |
2005年 | 43篇 |
2004年 | 32篇 |
2003年 | 22篇 |
2002年 | 31篇 |
2001年 | 17篇 |
2000年 | 18篇 |
1999年 | 8篇 |
1998年 | 8篇 |
1997年 | 7篇 |
1996年 | 19篇 |
1995年 | 14篇 |
1994年 | 17篇 |
1993年 | 6篇 |
1992年 | 14篇 |
1991年 | 5篇 |
1990年 | 8篇 |
1989年 | 6篇 |
1988年 | 12篇 |
1987年 | 8篇 |
1986年 | 5篇 |
1985年 | 10篇 |
1984年 | 9篇 |
1983年 | 6篇 |
1982年 | 4篇 |
1981年 | 6篇 |
1980年 | 3篇 |
1977年 | 6篇 |
1976年 | 11篇 |
1975年 | 5篇 |
1974年 | 5篇 |
1973年 | 5篇 |
1972年 | 5篇 |
排序方式: 共有1096条查询结果,搜索用时 218 毫秒
71.
We describe the details of an experiment using an atomic beam of rubidium which allowed us to detect by field ionization techniques the np Rydberg states from n = 28 up to n = 78, to detect also ns and nd states using a Stark mixing, and for all of these detected states to check the classical law Ec = [16n*4]?1 concerning the critical ionizing electric field Ec. It turns out that for n as high as 65 this law is quite well verified. 相似文献
72.
A simple method of measuring the wavelength γ1 and the spectral line spacing Δγ of a multi-mode dye laser light by using the correlated speckle patterns produced at the far-field of a diffuser is proposed. Examples of the obtained values of γ1 and Δγ are 6.0 × 103 Å and 3.0 × 101 Å, respectively. 相似文献
73.
Bendikov M Duong HM Starkey K Houk KN Carter EA Wudl F 《Journal of the American Chemical Society》2004,126(24):7416-7417
A series of oligoacenes from benzene to decacene were studied computationally with DFT and CASSCF methods. In contrast to the common view that acenes are closed-shell systems or may have a triplet ground state, these results offer the first theoretical predictions for the singlet ground state and diradical character for oligoacenes. The nature of the ground states of these molecules arises from the disjoint nature of the NBMOs that are singly occupied in the diradical. 相似文献
74.
Photoexcitation of antiferromagnetic NiO leads to ultrafast reorientation of Ni2+ spins due to change of the magnetic anisotropy. Recovery of the magnetic ground state occurs as coherent oscillation of the antiferromagnetic order parameter between hard- and easy-axis states manifesting itself as quantum beating. The coherence time is approximately 1 ns with the beating frequency being determined by the anisotropy energy. 相似文献
75.
We report the spontaneous emergence of a doubly periodic train of sedimented knolls in a dense suspension. These solidified knolls rise out of, and coexist alongside, a sea of freely flowing liquid in a slowly rotating horizontal bottle. We apply a variable viscosity model that permits simultaneous analysis of fluidlike and solidlike behaviors that are ubiquitous in a variety of sedimenting flows. The model generates qualitative agreement with experiments, and produces new insights into mechanisms by which sedimented structures form. 相似文献
76.
N-heterocyclic carbenes as highly efficient catalysts for the cyclotrimerization of isocyanates 总被引:2,自引:0,他引:2
[reaction: see text] A series of N-heterocyclic carbenes (NHCs) were evaluated as potential catalysts for the cyclotrimerization of isocyanates to afford isocyanurates. 1,3-Bis-(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene (SIPr) was found to be a highly efficient catalyst for the cyclotrimerization of a variety of isocyanates. 相似文献
77.
Molality as a unit of measure for expressing 1H MRS brain metabolite concentrations in vivo 总被引:1,自引:0,他引:1
Knight-Scott J Haley AP Rossmiller SR Farace E Mai VM Christopher JM Manning CA Simnad VI Siragy HM 《Magnetic resonance imaging》2003,21(7):787-797
Absolute concentrations of cerebral metabolite in in vivo 1H magnetic resonance spectroscopy studies (1H-MRS) are widely reported in molar units as moles per liter of tissue, or in molal units as moles per kilogram of tissue. Such measurements require external referencing or assumptions as to local water content. To reduce the scan time, avoid assumptions that may be invalid under specific pathologies, and provide a universally accessible referencing procedure, we suggest that metabolite concentrations from 1H-MRS measurements in vivo be reported in molal units as moles per kilogram of tissue water. Using internal water referencing, a two-compartment water model, a simulated brain spectrum for peak identification, and a spectroscopic bi-exponential spin-spin relaxation segmentation technique, we measured the absolute concentrations for the four common 1H brain metabolites: choline (Cho), myo-inositol (mIno), phosphocreatine + creatine (Cr), and N-acetyl-aspartate (NAA), in the hippocampal region (n = 26) and along the Sylvian fissure (n = 61) of 35 healthy adults. A stimulated echo localization method (20 ms echo time, 10 ms mixing time, 4 s repetition time) yielded metabolite concentrations, uncorrected for metabolite relaxation or contributions from macromolecule resonances, that were expectantly higher than with molar literature values. Along the Sylvian fissure the average concentrations (coefficient of variation (CV)) in mmoles/kg of tissue water were 17.6 (12%) for NAA, 14.2 (9%) for Cr, 3.6 (13%) for Cho, and 13.2 (15%) for mIno. Respective values for the hippocampal region were 15.7 (20%), 14.7 (16%), 4.6 (19%), and 17.7 (26%). The concentrations of the two regions were significantly different (p = 0.001) for NAA, mIno, and Cho, a trend in agreement with previous studies. All gray matter Sylvian fissure CV values, except for NAA, were also in agreement with previous 1H-MRS gray matter studies. The reduced precision of the NAA concentration was attributed to overlapping signal contributions from glutamate and glutamine (Glx), suggesting that a detailed Glx model is critical for accurate quantitation of the NAA 2.02 ppm resonance. The reduced precision of the measurements in the hippocampal region was attributed to poor spectral resolution. 相似文献
78.
Changes in MRI signal intensity during hypercapnic challenge under conscious and anesthetized conditions 总被引:5,自引:0,他引:5
Most functional magnetic resonance imaging (fMRI) studies in animals are conducted under anesthesia to minimize motion artifacts. However, methods and techniques have been developed recently for imaging fully conscious rats. Functional MRI studies on conscious animals report enhanced BOLD signal changes as compared to the anesthetized condition. In this study, rats were exposed to different concentrations of carbon dioxide (CO(2)) while conscious and anesthetized to test whether cerebrovascular reactivity may be contributing to these enhanced BOLD signal changes. Hypercapnia produced significantly greater increases in MRI signal intensity in fully conscious animals (6.7-13.3% changes) as when anesthetized with 1% isoflurane (3.2-4.9% changes). In addition, the response to hypercapnia was more immediate in the conscious condition (< 30s) with signal risetimes twice as fast as in the anesthetized state (60s). Both cortical and subcortical brain regions showed a robust, dose- dependent increase in MRI signal intensity with hypercapnic challenge while the animals were conscious but little or no change when anesthetized. Baseline variations in MRI signal were higher while animals were conscious but this was off set by greater signal intensity changes leading to a greater contrast-to-noise ratio, 13.1 in conscious animals, as compared to 8.0 in the anesthetized condition. In summary, cerebral vasculature appears to be more sensitive to hypercapnic challenge in the conscious condition resulting in enhanced T2* MRI signal intensity and the potential for better BOLD signal changes during functional imaging. 相似文献
79.
Let be a space of homogeneous type, and be the generator of a semigroup with Gaussian kernel bounds on . We define the Hardy spaces of for a range of , by means of area integral function associated with the Poisson semigroup of , which is proved to coincide with the usual atomic Hardy spaces on spaces of homogeneous type.
80.
Many graphs arising in various information networks exhibit the "power law" behavior -the number of vertices of degree k is proportional to k-# for some positive #. We show that if # > 2.5, the largest eigenvalue of a random power law graph is almost surely(1+ o(1))?m (1+ o(1))\sqrt{m} where m is the maximum degree. Moreover, the klargest eigenvalues of a random power law graph with exponent # have power law distribution with exponent 2# if the maximum degree is sufficiently large, where k is a function depending on #, mand d, the average degree. When 2<#< 2.5, the largest eigenvalue is heavily concentrated at cm3-# for some constant c depending on # and the average degree. This result follows from a more general theorem which shows that the largest eigenvalue of a random graph with a given expected degree sequence is determined by m, the maximum degree, and [(d)\tilde] \tilde{d} , the weighted average of the squares of the expected degrees. We show that the k-th largest eigenvalue is almost surely (1+ o(1))?{mk} (1+ o(1))\sqrt{m_k} where mk is the k-th largest expected degree provided mk is large enough. These results have implications on the usage of spectral techniques in many areas related to pattern detection and information retrieval. 相似文献