全文获取类型
收费全文 | 363篇 |
免费 | 15篇 |
国内免费 | 9篇 |
专业分类
化学 | 171篇 |
晶体学 | 3篇 |
力学 | 12篇 |
数学 | 130篇 |
物理学 | 71篇 |
出版年
2023年 | 5篇 |
2022年 | 14篇 |
2021年 | 24篇 |
2020年 | 21篇 |
2019年 | 17篇 |
2018年 | 13篇 |
2017年 | 11篇 |
2016年 | 15篇 |
2015年 | 9篇 |
2014年 | 15篇 |
2013年 | 18篇 |
2012年 | 19篇 |
2011年 | 21篇 |
2010年 | 10篇 |
2009年 | 11篇 |
2008年 | 11篇 |
2007年 | 19篇 |
2006年 | 16篇 |
2005年 | 14篇 |
2004年 | 17篇 |
2003年 | 8篇 |
2002年 | 8篇 |
2001年 | 6篇 |
2000年 | 7篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 6篇 |
1993年 | 2篇 |
1992年 | 4篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1986年 | 2篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 3篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有387条查询结果,搜索用时 15 毫秒
71.
David M. Whalley Hung A. Duong Prof. Michael F. Greaney 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(8):1927-1930
A light-mediated Truce–Smiles arylative rearrangement is described that proceeds in the absence of any photocatalyst. The protocol creates two C−C bonds from simple starting materials, with the installation of an aryl ring and a difluoroacetate moiety across unactivated alkenes. The reaction proceeds via a radical mechanism, utilizing a light-mediated reduction of ethyl bromodifluoroacetate by N,N,N′,N′-tetramethylethylenediamine (TMEDA) to set up intermolecular addition to an unactivated alkene, followed by Truce–Smiles rearrangement. 相似文献
72.
73.
74.
One‐Step Pyro‐Synthesis of a Nanostructured Mn3O4/C Electrode with Long Cycle Stability for Rechargeable Lithium‐Ion Batteries
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Muhammad Hilmy Alfaruqi Dr. Jihyeon Gim Sungjin Kim Jinju Song Pham Tung Duong Jeonggeun Jo Dr. Joseph Paul Baboo Dr. Zhiliang Xiu Dr. Vinod Mathew Prof. Jaekook Kim 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(6):2039-2045
A nanostructured Mn3O4/C electrode was prepared by a one‐step polyol‐assisted pyro‐synthesis without any post‐heat treatments. The as‐prepared Mn3O4/C revealed nanostructured morphology comprised of secondary aggregates formed from carbon‐coated primary particles of average diameters ranging between 20 and 40 nm, as evidenced from the electron microscopy studies. The N2 adsorption studies reveal a hierarchical porous feature in the nanostructured electrode. The nanostructured morphology appears to be related to the present rapid combustion strategy. The nanostructured porous Mn3O4/C electrode demonstrated impressive electrode properties with reversible capacities of 666 mAh g?1 at a current density of 33 mA g?1, good capacity retentions (1141 mAh g?1 with 100 % Coulombic efficiencies at the 100th cycle), and rate capabilities (307 and 202 mAh g?1 at 528 and 1056 mA g?1, respectively) when tested as an anode for lithium‐ion battery applications. 相似文献
75.
An unprecedented synthesis of a range of high value homo- and heterobiindolyls is presented. The one-pot Miyaura borylation and subsequent Suzuki-Miyaura coupling sequence allows for the construction of the highly sterically congested C-C bond between two bromoindoles in modest to good overall yields. 相似文献
76.
Duong Quô c Vi d ê t 《Proceedings of the American Mathematical Society》2008,136(12):4185-4195
Let be a Noetherian local ring with the maximal ideal and an ideal of Denote by the fiber cone of This paper characterizes the multiplicity and the Cohen-Macaulayness of fiber cones in terms of minimal reductions of ideals.
77.
In this article we give necessary and sufficient conditions for the boundedness of the weighted Hardy-Cesà ro operators which is associated to the parameter curve γ(t, x) = γ(t)x defined by \({U_{\psi ,\gamma }}f\left( x \right) = \int {\left( {\gamma \left( t \right)x} \right)} \psi \left( t \right)dt\) on the weighted Morrey-Herz space over the p-adic field. Especially, the corresponding operator norms are established in each case. These results actually extend those of K. S. Rim and J. Lee [27] and of the authors [9]. Moreover, the sufficient conditions of boundedness of commutators of p-adic weighted Hardy-Cesàro operator with symbols in the Lipschitz space on the weighted Morrey-Herz space are also established. 相似文献
78.
Dry Reforming of Methane on a Highly‐Active Ni‐CeO2 Catalyst: Effects of Metal‐Support Interactions on C−H Bond Breaking
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
B. Sc. Zongyuan Liu Dr. David C. Grinter Dr. Pablo G. Lustemberg Dr. Thuy‐Duong Nguyen‐Phan Dr. Yinghui Zhou B. Sc. Si Luo Dr. Iradwikanari Waluyo Dr. Ethan J. Crumlin Dr. Dario J. Stacchiola Prof. Jing Zhou Dr. Javier Carrasco Prof. H. Fabio Busnengo Dr. M. Verónica Ganduglia‐Pirovano Dr. Sanjaya D. Senanayake Prof. José A. Rodriguez 《Angewandte Chemie (International ed. in English)》2016,55(26):7455-7459
Ni‐CeO2 is a highly efficient, stable and non‐expensive catalyst for methane dry reforming at relative low temperatures (700 K). The active phase of the catalyst consists of small nanoparticles of nickel dispersed on partially reduced ceria. Experiments of ambient pressure XPS indicate that methane dissociates on Ni/CeO2 at temperatures as low as 300 K, generating CHx and COx species on the surface of the catalyst. Strong metal–support interactions activate Ni for the dissociation of methane. The results of density‐functional calculations show a drop in the effective barrier for methane activation from 0.9 eV on Ni(111) to only 0.15 eV on Ni/CeO2?x(111). At 700 K, under methane dry reforming conditions, no signals for adsorbed CHx or C species are detected in the C 1s XPS region. The reforming of methane proceeds in a clean and efficient way. 相似文献
79.
Old and New Morrey Spaces with Heat Kernel Bounds 总被引:1,自引:0,他引:1
Given p ∈ [1,∞) and λ ∈ (0, n), we study Morrey space
of all locally integrable complex-valued functions f on
such that for every open Euclidean ball B ⊂
with radius rB there are numbers C = C(f ) (depending on f ) and c = c(f,B) (relying upon f and B) satisfying
and derive old and new, two essentially different cases arising from either choosing
or replacing c by
—where tB is scaled to rB and pt(·, ·) is the kernel of the infinitesimal generator L of an analytic semigroup
on
Consequently, we are led to simultaneously characterize the old and new Morrey spaces, but also to show that for a suitable
operator L, the new Morrey space is equivalent to the old one. 相似文献
80.
Normal mode calculations for two alternating sequence dodecamers in A, B, and Z conformations have been performed in dihedral angle space extended to endocyclic valence angles to account for sugar ring flexibility. Normal modes are analyzed in terms of helicoidal and backbone parameter variations with special attention being paid to global deformations of the double helix such as bending, twisting, or stretching. Results show that the allomorphic form of DNA has the largest influence on the flexibility of the sugar-phosphate backbone. Amplitudes of these vibrations follow the order: B > Z > A. In contrast, the amplitudes of helicoidal parameter variations are much more dependent on the base sequence. Global deformations of the double helix occur with characteristic times in the range of 1 to 10 ps and can be of mixed character, the strongest bending mode being at the same the time strongest stretching mode. © 1997 by John Wiley & Sons, Inc. J Comput Chem 18: 796–811, 1997 相似文献