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31.
The temperature dependence of the ac susceptibility of amorphous Fe90—xMnxZr10 (x = 0, 4, 8) has been measured at different ac fields in the frequency range of 80 Hz to 1 kHz. All the compositions of the present study exhibit a double magnetic transition below room temperature. It is found that the Curie temperature (TC) decreases while the spin‐glass transition temperature (Tf) increases as Mn concentration increases from 0 to 8 at%. The values of TC) and critical exponent associated with the magnetic susceptibility were extracted from ac susceptibility measurements. The critical exponent is in close agreement with the value predicted by the three‐dimensional Heisenberg model. The results obtained here can be explained on the basis of competing exchange interactions below the magnetic ordering temperature. 相似文献
32.
In a large class of disordered organic solids, the observed field and temperature dependence of the mobility of photoinjected charge carriers arises from specific statistical features of the disordered potential energy landscape through which they move. In materials with polar constituents, energy fluctuations exhibit strong spatial correlations, with deep energetic valleys developing only over large length scales. We present a scaling analysis that shows how the hierarchical field‐induced flattening of fluctuations of different magnitudes gives rise to field dependent (e.g., Poole‐Frenkel type) mobilities characteristic of the spatial correlations from which they arise. 相似文献
33.
从烟草(品种革新一号)单倍体花粉植株的叶和茎产生的愈伤组织,结合悬浮培养,获得的细胞分离出原生质体。在液体培养基中静置培养,12小时后原生质体开始变为卵圆形,细胞壁明显可见,24小时后完成第一次细胞分裂。以后继续分裂形成浅黄色的愈伤组织,在培养四星期后可达1毫米大小,再放到转床上进行旋转培养18天左右,愈伤组织可达3—4毫米大小。当转移到分化培养基后,分别分化出苗及根,长成完整的植株。 原生质体再生细胞的分裂与分化,不仅受不同器官来源的愈伤组织及其年龄的影响;还受分化培养基的基本成份及所用细胞分裂素的类型等的影响。 相似文献
34.
用分子动力学方法和不同参数的指数 6势函数计算了T =30 4K的高密度氦的等温压缩线和能量分布 .给出了能精确描述高密度氦原子间相互作用的指数 6势函数优化参数 .并用优化的势函数计算了高密度氦T =30 0K和T =2 98K的等温压缩线 ,计算结果和实验值非常吻合 .进一步用优化的势函数模拟了高温高密度氦的状态方程及其结构 ,发现当把 ρ限定为 1 .6 0g /cm3 时 ,其径向分布函数的第 2个峰将在 2 0 0 0~ 30 40K区间消失 ,表明此时发生了固 液相变过程 . 相似文献
35.
有限生成的算子李代数 总被引:2,自引:0,他引:2
设A为结合代数,T1,…,Tn ∈A,ε(T)为T生成的李代数,这里记T= (T1,…,Tn)∈ An.本文证明:若ε(T)是幂零的,则其必为有限维的,并给出ε(T)为有限维幂零李代数的充要条件.然后考虑A为Banach空间X上有界线性算子组成的代数B(X),得到算子理论的一些结果;若拟幂零算子T1,T2生成的李代数是有限维幂零的,则T1T2,T1+T2均为拟幂零的.若非零紧算子T1与非标量算子T2生成的李代数是有限维的,则T2有非平凡超不变子空间,从而在形式上推广了有关不变子空间的 Lomonosov定理. 相似文献
36.
Summary The pore structures of zirconium oxide particles prepared by two different methods (PICA and Oil Emulsion processes) are compared. Nitrogen sorptometry and size exclusion chromatography are used to characterize the two different types of particles. Significant and unexpected differences were found in the accessible pore volumes and the bed packing densities of the two materials. The PICA material was found to have a higher totally included and totally excluded volume than would be normally expected. The chromatographic method provides results which are more useful for the application of these materials to separation sciences. 相似文献
37.
Molecular dipole moments of analytic density-functional theory are investigated. The effect of element-dependent exchange potentials on these moments are examined by comparison with conventional quantum-chemical methods and experiment for the subset of the extended G2 set of molecules that have nonzero dipole moment. Fitting the Kohn-Sham [Phys. Rev. 140, A1133 (1965)] potential itself makes a mean absolute error of less than 0.1 D. Variation of alpha (Slater's [Phys. Rev. 81, 385 (1951)] exchange parameter) values has far less effect on dipole moments than on energies. It is argued that in variable alpha methods one should choose the smaller of the two rather than the geometric mean of the two alpha values for the heteroatomic part of the linear-combination-atomic-orbital density. Calculations on the dipole moment of NH(2)(CH)(24)NO(2) are consistent with earlier calculations and show that varying the differences between alpha values for atoms with different atomic numbers has only short-ranged electrostatic effects. 相似文献
38.
Zachary Nuño Brandon Hessler Bryan Heiberg Ralph Damato Terry Dunlap Young-Seok Shon Yohannes Abate 《Journal of nanoparticle research》2012,14(3):766
Spectroscopic near-field imaging of single silica-shell/Au-core and pure silica nanoparticles deposited on a silicon substrate
is performed in the infrared wavelength range (λ = 9–11 μm) using scattering-type scanning near-field optical microscopy (s-SNOM).
By tuning the wavelength of the incident light, we have acquired information on the spectral phonon–polariton resonant near-field
interactions of the silica-shell/Au-core and pure silica nanoparticles with the probing tip. We made use of the enhanced near-field
coupling between the high index Au-core and the probing tip to achieve spectral near-field contrast of the thin silica coating
(thickness < 10 nm). Our results show that spectroscopic imaging of thin coating layers and complex core–shell nanoparticles
can be directly performed by s-SNOM. 相似文献
39.
Ten solvents containing heavy atoms were examined for suitability for use in the external heavy atom effect for routine phosphorimetry. In previous work only iodine-containing solvent systems have been used, and the incongruity of enhancement results for structurally similar compounds suggests that the ultraviolet transmission characteristics of the solvent systems may be responsible for fractional enhancements. In this study the effect of chlorine-, bromine-, and iodine-containing solvent systems on phosphorescence and fluorescence intensities was investigated. Generally, chlorine-, and bromine-containing solvent systems showed a significant improvement in phosphorimetric enhancements with slightly longer lifetimes than in solvent systems containing iodine. As expected from their smaller spin-orbit coupling, chlorine-containing solvent systems yield smaller enhancements than bromine-containing solvent systems. Solvent systems containing bromine seem to offer the best compromise between ultraviolet transmission characteristics and large spin-orbit coupling constants. 相似文献
40.
本文求出了Eliashberg方程在T=Tc时的解,得到了下面的临界温度级数表示式: 其中α0(μ*),α1(μ*)等系数是μ*的函数.此式表明,Tc不仅依赖于λ,〈ω2〉和μ*,而且依赖于有效声子谱α2F(ω)的各级矩〈ω2n〉.这是区别于前人的Tc公式最重要的一点。这说明像McMillan以及Allen和Dynes的Tc公式不仅是近似的,而主要是他们没有能正确地概括出α2F(ω)对Tc的影响. 相似文献