纳米WO3的制备及其光解水析氧性能研究

用溶胶凝胶法,灼烧法合成了纳米级WO3,采用X-射线衍射、紫外可见漫反射光谱对WO3进行表征.在Fe3 为电子受体、溶液酸度pH为2.0情况下,研究了纳米级WO3在365nm紫外辐射下光解水析氧的光催化活性,并讨论了不同方法制备的催化剂活性差异的原因.结果表明,结晶程度越高、尺寸越小、比表面积越大的纳米级WO3具有更高的光分解水析氧活性,电子受体的浓度、溶液的酸度对析氧活性有明显的影响.     

Investigation on crosslinking behaviors of NBR/PVC filled with anhydrous copper sulfate particles by dynamic mechanical analysis

Crosslinking behaviors of acrylonitrile butadiene rubber (NBR)/poly (vinyl chloride) (PVC) alloy, filled with anhydrous copper sulfate (CuSO₄) particles, were investigated for the first time by dynamic mechanical analysis (DMA) under hetero and isothermal modes, respectively. In the heterothermal testing, (NBR/PVC)/CuSO₄ compound showed two marked increases in the storage modulus (E′), corresponding to coordination crosslinking of NBR-CuSO₄ and self-crosslinking of NBR and PVC respectively. During the isothermal testing, a dramatic increase in E′ was found at the initial stage while that of original NBR/PVC alloy was not detected. The marked increase in E′ of (NBR/PVC)/CuSO₄ compound was mainly due to the crosslinking induced by coordination between  CN and Cu²⁺. The increasing extent of E′ increased with the rise of CuSO₄ content, suggesting the formation of a greater number of crosslinks. Moreover, the activation energy (E_a) of crosslinking process was about 139 kJ/mol. In this work, fourier transform infrared spectrum (FT-IR) and equilibrium swelling method were also performed for the characterization of the compound. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 41–51, 2007     

OSCILLATION FOR NONAUTONOMOUS NEUTRAL DYNAMIC DELAY EQUATIONS ON TIME SCALES

The article is concerned with oscillation of nonautonomous neutral dynamic delay equations on time scales. Sufficient conditions are established for the existence of bounded positive solutions and for oscillation of all solutions of this equation. Some results extend known results for difference equations when the time scale is the set Z of positive integers and for differential equations when the time scale is the set R of real numbers.     

LD端抽运平直腔Nd:YVO4固态激光器的输出功率特性研究

对LD端抽运平直腔Nd:YVO₄固态激光器输出功率特性受激光器内在诸因素(热透镜效应、腔长、激活孔径等)的制约关系进行了研究.并用传播圆-变换圆图解分析方法给出了合理的解释，同时，对进一步提高其输出功率特性指出了方向. 关键词： 固体激光器 热透镜 变换圆 平直腔     

On existence of solutions for some hyperbolic-parabolic-type chemotaxis systems

In this paper, we discuss the local and global existence ofweak solutions for some hyperbolic–parabolic systems modellingchemotaxis.     

单晶和多晶纯铝蠕变过程中的内耗

研究了单晶和多晶纯铝蠕变过程中的低频内耗. 在单晶纯铝中观察到: 内耗在蠕变初期单调下降, 在蠕变第一阶段后期出现了一个显著的时间内耗峰, 在蠕变第二阶段内耗趋于稳定值. 多晶纯铝在类似实验条件下则不出现时间内耗峰. 文中分析了出现时间内耗峰的条件和原因, 认为它是由于蠕变第一阶段中运动位错的阻尼系数逐渐增大所引起的. 文中还从蠕变过程中位错运动的微观机制出发, 推导出了蠕变过程中内耗的表达式, 满意地解释了实验结果. 关键词：     

Numerical solution of differential equations using Sinc method based on the interpolation of the highest derivatives

In general, we will use the numerical differentiation when dealing with the differential equations. Thus the differential equations can be transformed into algebraic equations and then we can get the numerical solutions. But as we all have known, the numerical differentiation process is very sensitive to even a small level of errors. In contrast it is expected that on average the numerical integration process is much less sensitive to errors. In this paper, based on the Sinc method we provide a new method using Sinc method incorporated with the double exponential transformation based on the interpolation of the highest derivatives (SIHD) for the differential equations. The error in the approximation of the solution is shown to converge at an exponential rate. The numerical results show that compared with the exiting results, our method is of high accuracy, of good convergence with little computational efforts. It is easy to treat nonhomogeneous mixed boundary condition for our method, which is unlike the traditional Sinc method.     

Solvothermal synthesis of TiO2: anatase nanocrystals and rutile nanofibres from TiCl4 in acetone

This work reports a new synthetic approach for single‐phase TiO₂ nanomaterials by solvothermal treatment of titanium tetrachloride in acetone at 80–110 °C. Small, uniform, and yet size‐tunable (5–10 nm) anatase titania nanocrystallites were obtained using a low concentration of TiCl₄ in acetone (i.e., at molar ratios of TiCl₄/acetone ≤ 1:15) in the temperature range of 80–110 °C, while rutile nanofibers were synthesized using a high concentration of TiCl₄ (e.g., TiCl₄/acetone = 1:10) at 110 °C. Copyright © 2007 John Wiley & Sons, Ltd.