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The microwave heating of two-dimensional slabs in a long rectangularwaveguide propagating the TE10 mode is examined. The temperaturedependency of the electrical conductivity and the thermal absorptivityis assumed to be governed by the Arrhenius law, while both theelectrical permittivity and the magnetic permeability are assumedconstant. The governing equations are the forced heat equationand the steady-state version of Maxwell's equation while theboundary conditions take into account both convective and radiativeheat loss. Approximate analytical solutions, valid for smallthermal absorptivity, are found for the temperature and theelectric-field amplitude using the Galerkin method. As the Arrheniuslaw is not amenable analytically, it is approximated by a rational-cubicfunction. At the steady state the temperature versus power relationshipis found to be multivalued; at the critical power level thermalrunaway occurs when the temperature jumps from the lower (cool)temperature branch to the upper (hot) temperature branch ofthe solution. In the steady-state limit the approximate analyticalsolutions are compared with the numerical solutions of the governingequations for various special cases. These are the limits ofsmall and large heat loss and an intermediate case involvingradiative heat loss. Results are also presented for a case wheredifferential cooling occurs on the different sides on the slab.An alternative heating scenario, where one end of the waveguideis blocked by a short, is also considered. The approximate solutionsare found for this geometry and compared in the small Biot-numberlimit to Kriegsmann (1997). Also, a control process is presented,which allows thermal runaway to be avoided and the desired finalsteady state to be reached. Various special cases of the feedbackparameters associated with the control process are examined. 相似文献
34.
Thomas R. Dugan 《Journal of organometallic chemistry》2009,694(17):2825-6860
The oxidative addition and reductive elimination reactions of H2 on unsaturated transition-metal complexes are crucial in utilizing this important molecule. Both biological and man-made iron catalysts use iron to perform H2 transformations, and highly unsaturated iron complexes in unusual geometries (tetrahedral and trigonal planar) are anticipated to give unusual or novel reactions. In this paper, two new synthetic routes to the low-coordinate iron hydride complex [LtBuFe(μ-H)]2 are reported. Et3SiH was used as the hydride source in one route by taking advantage of the silaphilicity of the fluoride ligand in three-coordinate LtBuFeF. The other synthetic method proceeded through the binuclear oxidative addition of H2 or D2 to a putative Fe(I) intermediate. Deuteration was verified through reduction of an alkyne and release of the deuterated alkene product. Mössbauer spectra of [LtBuFe(μ-H)]2 indicate that the samples are pure, and that the iron(II) centers are high-spin. 相似文献
35.
Evidence that microbially produced alkaline materials are involved in coal biosolubilization 总被引:2,自引:0,他引:2
Quigley D. R. Ward B. Crawford D. L. Hatcher H. J. Dugan P. R. 《Applied biochemistry and biotechnology》1989,20(1):753-763
Applied Biochemistry and Biotechnology - The biosolubilities (susceptibility to being attacked and solubilized by microbes) of 17 coals by 9 microbes were evaluated, as were solubilities of these... 相似文献
36.
Shackman JG Reid KR Dugan CE Kennedy RT 《Analytical and bioanalytical chemistry》2012,402(9):2797-2803
A rapid microfluidic based capillary electrophoresis immunoassay (CEIA) was developed for on-line monitoring of glucagon secretion
from pancreatic islets of Langerhans. In the device, a cell chamber containing living islets was perfused with buffers containing
either high or low glucose concentration. Perfusate was continuously sampled by electroosmosis through a separate channel
on the chip. The perfusate was mixed on-line with fluorescein isothiocyanate-labeled glucagon (FITC-glucagon) and monoclonal
anti-glucagon antibody. To minimize sample dilution, the on-chip mixing ratio of sampled perfusate to reagents was maximized
by allowing reagents to only be added by diffusion. Every 6 s, the reaction mixture was injected onto a 1.5-cm separation
channel where free FITC-glucagon and the FITC-glucagon–antibody complex were separated under an electric field of 700 V cm−1. The immunoassay had a detection limit of 1 nM. Groups of islets were quantitatively monitored for changes in glucagon secretion
as the glucose concentration was decreased from 15 to 1 mM in the perfusate revealing a pulse of glucagon secretion during
a step change. The highly automated system should be enable studies of the regulation of glucagon and its potential role in
diabetes and obesity. The method also further demonstrates the potential of rapid CEIA on microfluidic systems for monitoring
cellular function. 相似文献
37.
The effective quadrupole moments Qeff of the nuclei of 165Ho, 175Lu, 176Lu, 179Hf and 181Ta were accurately measured by detecting the pionic atom 5g-4f X-rays of the elements. The spectroscopic quadropole moments, Qspec, were obtained by correcting Qeff for nuclear finite size effect, distortion of the pion wave function by the pion-nucleus strong interaction, and contribution to the energy level splittings by the strong interaction. The intrinsic quadrupole moments, Q0, were obtained by projecting Qspec into the frame of reference fixed on the nucleus. The shift, ε0, and broadening, Γ0, of the 4f energy level due to the strong interaction between the pion and the nucleons for all the elements were also measured. Theoretical values of ε0 and Γ0 were calculated and compared to the experimental values. The measured values of Q0 were compared with existing results in muonic and pionic atoms. The measured values of ε0 and Γ0 were also compared with existing values. 相似文献
38.
Reactions produced by stopped negative pions on targets of 165Ho, 175Lu, 176Lu, 179Hf, and 181Ta are investigated by measuring photons coincident with the stopped pions. These photons were detected with an 80 cm3 Ge(Li) detector and identified as pionic X-rays or rotational γ-rays from the residual nuclei. Pion capture is found to result in the excitation of high-spin states. Yields for the residual nuclei are inferred from the observed γ-transitions and compared to calculations based on the exciton model for pre-equilibrium emission followed by particle evaporation. Preliminary results of a pion stop, γn coincidence experiment are presented and compared to the calculations. 相似文献
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Andreas?Lüthi Martin?A?Wikstr?m Mary?J?Palmer Paul?Matthews Tim?A?Benke John?TR?Isaac Graham?L?CollingridgeEmail author 《BMC neuroscience》2004,5(1):44