[N_2O_2]型镍基配合物在中性水溶液中产氢性能的研究

通过简单易行的曼尼希(Mannich)反应,合成了一种[N_2O_2]型配体,在少量三乙胺存在条件下,成功实现了与高氯酸镍配位,得到了镍金属配合物。通过核磁共振氢谱、高分辨质谱等手段对配体和配合物进行了表征。该化合物在水中具有一定的溶解度,并在中性磷酸缓冲溶液中显示出良好的电化学催化产氢活性。     

AgBr@TiO<Subscript>2</Subscript>/GO ternary composites with enhanced photocatalytic activity for oxidation of benzyl alcohol to benzaldehyde

AgBr@TiO₂/GO (graphene oxide) ternary composite photocatalyst was synthesized by fabricating core–shell-structured AgBr@TiO₂ and anchoring it onto the surface of GO. The obtained samples were characterized by transmission electron microscopy, X-ray diffraction analysis, X-ray photoelectron spectroscopy, ultraviolet–visible (UV–Vis) diffuse reflectance spectrum, and photoluminescence (PL) spectroscopy. It was found that the AgBr nanoparticles were prone to aggregation while the core–shell-structured AgBr@TiO₂ possessed excellent dispersity. PL analysis revealed that the ternary-structured AgBr@TiO₂/GO could effectively promote the separation rate of electron–hole pairs. Photocatalytic oxidation of benzyl alcohol to benzaldehyde under visible-light irradiation was selected as probe reaction to evaluate the photocatalytic activity of the different samples. It was found that the AgBr@TiO₂/GO ternary composite exhibited evidently improved photocatalytic activity compared with AgBr, AgBr@TiO₂, and AgBr/GO. On the basis of the experiment results, the photocatalytic oxidation mechanism of benzyl alcohol over AgBr@TiO₂/GO is tentatively discussed.     

Novel TEMPO-oxidized cellulose nanofiber/polyvinyl alcohol/polyethyleneimine nanoparticles for Cu2+ removal in water

Cellulose - In this study, environmentally friendly TEMPO-oxidized cellulose nanofiber (TO-CNF)/polyvinyl alcohol (PVA)/polyethyleneimine (PEI) nanoparticles were obtained by assembling PEI into...     

Comment on: “Topology identification and adaptive synchronization of uncertain complex networks with adaptive double scaling functions” [Commun Nonlinear Sci Numer Simul 2011;16:3337-43]

In this comment letter we point out that the main result of the recent paper [Xu Y, Zhou W, Fang J, Sun W. Topology identification and adaptive synchronization of uncertain complex networks with adaptive double scaling functions. Commun Nonlinear Sci Numer Simul 2011;16(18):3337-43] has certain errors. The mistakes are corrected and a correct version is presented in this letter. We further indicate that a sufficient condition has been neglected in a series of articles discussing the same topic of network topology identification; hence we hope this letter can help clarify some unclear concepts about this topic.     

无穷维自回归过程的中偏差原理

本文考虑无穷维自回归过程经验协方差函数的中偏差原理,仅对自回归过程的随机扰动项做了高斯可积性的假设,这个条件比[4]中的对数Sobolev不等式要弱很多.主要利用了m-相依随机变量的中偏差结果和Ellis-Grtner定理,推广了[6]的结果.     

马氏过程经验测度的大偏差上界

本文研究了ω拓扑下马氏过程经验测度的一致大偏差上界.利用非紧度量βω(P)的性质,证明了马氏过程经验测度在(M1(E),ω)满足一致好的大偏差上界,当且仅当rω(P)＝0,推广了吴黎明[10]中的定理6.1.     

资源有限网络计划启发式方法的评价（中）：启发式方法的综合比较和评价

通过设计评价启发式方法优劣效果的度量指标——工期比率、比率和及差值率,利用随机活动网络发生器产生的５０ 个网络计划,对最常用的３１ 种资源有限网络计划的启发式方法的总体效果进行了比较、分析、评价和排序,便于人们在使用启发式方法之前,就可以预知该方法的大致效果,估计可能引起的偏差,在满足实际需要的前提下,选择合适的启发式方法。     

Adaptive generalized function matrix projective lag synchronization of uncertain complex dynamical networks with different dimensions

Generalized function matrix projective lag synchronization of uncertain complex dynamical networks with different dimension of nodes via adaptive control method is investigated in this paper. Based on Lyapunov stability theory, adaptive controller is obtained and unknown parameters of both the drive network and the response network are estimated by adaptive laws. In addition, the three-dimension chaotic system and the four-dimension hyperchaotic system, respectively, as the nodes of the drive and response network are analyzed in detail, and numerical simulation results are presented to illustrate the effectiveness of the theoretical results.     

Jet formation in shock-heavy gas bubble interaction

The influences of the acoustic impedance and shock strength on the jet formation in shock-heavy gas bubble interaction are numerically studied in this work. The process of a shock interacting with a krypton or a SF 6 bubble is studied by the numerical method VAS2D. As a validation, the experiments of a SF 6 bubble accelerated by a planar shock were performed. The results indicate that, due to the mismatch of acoustic impedance, the way of jet formation in heavy gas bubble with different species is diversified under the same initial condition. With respect to the same bubble, the manner of jet formation is also distinctly different under different shock strengths. The disparities of the acoustic impedance result in different effects of shock focusing in the bubble, and different behaviors of shock wave inside and outside the bubble. The analyses of the wave pattern and the pressure variation indicate that the jet formation is closely associated with the pressure perturbation. Moreover, the analysis of the vorticity deposition, and comparisons of circulation and baroclinic torque show that the baroclinic vorticity also contributes to the jet formation. It is concluded that the pressure perturbation and baroclinic vorticity deposition are the two dominant factors for the jet formation in shock-heavy gas bubble interaction.