An Efficient Method for the Preparation of Sulfonamides from Sodium Sulfinates and Amines

Sulfonamides have a special role on medicine due to their broad biological activities, as bacterial infections, diabetes mellitus, oedema, hypertension prevention and treatment. In addition, sulfonamides are also useful in herbicides and pesticides. Herein, we communicate an efficient strategy for the preparation of sulfonamides via NH₄I‐mediated amination of sodium sulfinates. This new method provides a general and environmentally friendly access to sulfonamide compounds and tolerates a wide range of functional groups.     

0.22 THz高效率行波管的互作用计算

利用CST Microwave Studio 计算双排矩形梳状慢波结构的色散并据此确定了0.22 THz左右频段（D波段）行波管用慢波结构的尺寸参数。将相速再同步技术应用于基于双排矩形梳状慢波结构的D波段行波管中,用CST PIC模拟计算了4例具有不同周期构型的D波段行波管。结果证实：对于无集中衰减器的D波段行波管,在218~232 GHz范围内,相速再同步技术使得输出功率从10~13 W提高到19~28 W,电子效率从1.4%~2.2%提高到2.6%~3.9%;对于具有集中衰减器D波段行波管,在218~232 GHz范围内,相速再同步技术使得输出功率从8~16.8 W提高到32~41 W,电子效率从1.5%~2.8%提高到4.4%~5.7%。此外,无论行波管有无集中衰减器,相速再同步技术都明显改善了行波管的增益平坦度。     

脉冲功率晶闸管反向恢复特性

为建立有效的晶闸管模型来仿真晶闸管关断时过电压,减小晶闸管过压损坏的概率,以最大通流150 kA、耐压5.2 kV的脉冲晶闸管为研究对象,将其前置于脉冲形成单元回路中作为大功率开关使用,记录放电过程中晶闸管两端电压及电流。实验数据表明：恢复过程中的电流下降率、反向恢复电荷、反向恢复电流峰值随通态电流峰值的增大而增大,晶闸管关断时间随通态电流峰值的增大而减小。此外,在关断过程中,当电流下降率在-50~1000 A/s时,电流下降率与电流峰值为线性关系。因此,在大脉冲电流条件下,推导反向恢复过程参数与通态电流参数的关系时电流下降率可用与电流峰值的线性关系代替。基于Matlab仿真平台,建立了具有反向恢复过程的脉冲晶闸管模型。该模型仿真得到的晶闸管反向恢复电流峰值与实测结果较为吻合,反向恢复电压尚待进一步修正。     

Nutritional Attributes and Phenolic Composition of Flower and Bud of Sophora japonica L. and Robinia pseudoacacia L.

Sophora japonica L. (SJL) and Robinia pseudoacacia L. (RPL) are widely cultivated in China. However, the utilization of their main by-products are limited due to a lack of comprehensive nutritional attributes. Herein, the proximate composition, mineral elements, fatty acids, amino acids, monosaccharides, and phenolics were analyzed to investigate the nutritional attributes of SJL and RPL. Dietary fiber was the main ingredient in SJL and RPL, followed by protein and lipids. The content of Fe in SJL and RPL was highest, especially in flowers of SJL, reaching about 1179.51 mg/kg. The total unsaturated fatty acids accounted for 89.67% of the bud of SJL. Meanwhile, the essential amino acids contents of the flower and bud of SJL and RPL accounted for 35.95–40.59% of total amino acids. The flower of SJL (373.75 mg/g) exhibited the most abundant monosaccharides. Meanwhile, the total phenolics and flavonoid contents in the buds of SJL and RPL were significantly higher than that of the flower, implying the buds possessed better biological activity. Moreover, the bud of SJL possessed the most abundant phenolics. The results provided a reference for the development of functional food derived from SJL and RPL.     

Thermal,Mechanical and Dielectric Properties of Polyimide Composite Films by In-Situ Reduction of Fluorinated Graphene

Materials with outstanding mechanical properties and excellent dielectric properties are increasingly favored in the microelectronics industry. The application of polyimide (PI) in the field of microelectronics is limited because of the fact that PI with excellent mechanical properties does not have special features in the dielectric properties. In this work, PI composite films with high dielectric properties and excellent mechanical properties are fabricated by in-situ reduction of fluorinated graphene (FG) in polyamide acid (PAA) composites. The dielectric permittivity of pure PI is 3.47 and the maximum energy storage density is 0.664 J/cm³ at 100 Hz, while the dielectric permittivity of the PI composite films reaches 235.74 under the same conditions, a 68-times increase compared to the pure PI, and the maximum energy storage density is 5.651, a 9-times increase compared to the pure PI films. This method not only solves the problem of the aggregation of the filler particles in the PI matrix and maintains the intrinsic excellent mechanical properties of the PI, but also significantly improves the dielectric properties of the PI.     

聚龙一号装置上首次铝套筒Z箍缩X射线背光照相实验

在聚龙一号脉冲功率装置上首次完成了对带正弦扰动铝套筒Z箍缩的X射线背光照相实验。实验采用千焦耳激光器（1053 nm, 1 kJ, 1 ns）驱动固体靶材产生X射线, 然后利用基于球面晶体的单色背光照相技术以及直接点投影背光照相技术, 成功观测到约7.5 MA电流驱动条件下, Z箍缩铝套筒的外边界不稳定性发展情况。该实验验证了在聚龙一号装置上联合千焦耳激光器开展X射线背光照相实验的能力, 为后续精密Z箍缩物理研究奠定了基础。     

聚焦光在亚表面损伤介质中的散射特性

针对光学元件的亚表面缺陷,结合基于激光共焦层析的亚表层检测方法,建立聚焦光束在亚表面损伤介质中的传输模型,并采用有限元分析方法,仿真研究K9玻璃光学元件亚表层缺陷对聚焦光束的散射调制特性,特别对颗粒状和微裂纹两类特殊缺陷的光学调制特性进行研究和分析,探索了波长、缺陷大小、缺陷折射率及缺陷方向对聚焦光束散射特性的影响规律,通过分析包含亚表面损伤缺陷信息的光场分布图和强度变化曲线,获得了亚表面损伤缺陷的信息,并对其进行评价。     

行波前置短磁聚焦飞秒条纹管设计

设计了一款长度为265 mm的飞秒条纹管。采用短磁聚焦透镜和行波偏转板,并将行波偏转板置于磁透镜之前以提高偏转灵敏度。采用蒙特卡罗方法对阴极表面理想点和阴极狭缝发射的光电子初始参量进行了模拟抽样,用CST软件的Particle Tracking模块模拟跟踪了光电子的运行轨迹,统计分析了光电子在最佳像面上的位置分布和渡越时间,给出了光电子在最佳像面上的点扩展函数和调制传递函数。计算结果显示,所设计的条纹管阴极有效尺寸达到6 mm,放大率为2.4~2.5,动态空间分辨力大于55 lp/mm。经保守估算,条纹管的时间分辨力有望达到245 fs。     

基于节点密度的自适应EFG法拓扑优化方法研究

针对无网格法拓扑优化中设计变量庞大、计算效率低的问题,提出了基于节点密度的自适应EFG拓扑优化方法.该方法以节点相对密度为设计变量,建立了以结构柔度最小为优化目标的自适应EFG拓扑优化模型,给出了拓扑优化中自适应节点加密准则、节点加密方法和新增节点设计变量更新规则.算例结果表明,采用论文提出的自适应EFG拓扑优化方法进行结构拓扑优化时,可以减少结构分析和优化的设计变量数目,提高优化效率.