β方石英的振动光谱和方石英的相变

利用价力场模型计算了β方石英振动光谱横模的全部基频和简正模式。基频的计算值与β方石英的喇曼和红外光谱的观测值符合得很好。由此提供了一组甚好的β方石英的力常数。讨论了方石英αβ相变，并提出α方石英的软模Ｂ２６ｃｍ－１在此相变中起着基本作用     

甲烷的拉曼光谱特征

测定ＣＨ４的拉曼光谱时出现２个特征２０１７ｃｍ＾－１和３０２０ｃｍ＾－１，这是由于ＣＨ４分子中４个Ｃ－Ｈ键不等价造成的，本文中还讨论了其归属。     

稀土与芦丁的配合物

芦丁(H_4R)是带4个苯羟基的黄酮类化合物,易与金属离子形成配合物,用于某些金属离子的分析。我们曾研究过稀土与槲皮素形成的配合物。本文报导芦丁与稀土的配合物。 稀土硝酸盐溶液由稀土氧化物(光谱纯,上海试剂厂)制得。芦丁系上海试剂二厂的生     

Selective debenzylation of aromatic benzyl ethers by silica-supported sodium hydrogen sulfate

A new debenzylation of aromatic benzyl ethers by silica-supported sodium hydrogen sulfate is described. The process proceeds selectively and efficiently in good to excellent yields without affecting sensitive functional groups such as nitro, COOMe, aldehyde, ketone, and tosyl.     

A comparison of the vectorial nonparaxial approach with Fresnel and Fraunhofer approximations

Based on the vectorial Rayleigh diffraction integrals, a nonparaxial propagation equation of vectorial plane waves diffracted at a circular aperture is derived. The nonparaxial far-field expression, Fresnel and Fraunhofer diffraction formulae are given and treated as special cases of our general expression. The theoretical formulation permits us to study and compare the transversal and axial intensity distributions of diffracted plane waves both analytically and numerically. Illustrative numerical examples are given. It is shown that the vectorial nonparaxial approach has to be used if the aperture size is comparable with or less than the wavelength, and the knowledge of both transversal and axial intensity distributions is required to provide a comprehensive comparison of the paraxial and nonparaxial results.     

Covalently Attached Monolayer of Phthalocyanine on Chemically Modified Silicon Oxide Surface

Highly stable monolayers of 2,9,16,23-tetracarboxyl phthalocyanine on 3-aminopropyl-triethoxysilane (ATS) modified silicon and quartz substrates were prepared by reaction of carboxyl and amine. The monolayers were characterized by UV-Vis spectra and AFM measurements. The results indicated that the ultra-thin films on silicon or quartz were smooth, and the ordered structures were observed in these films.     

透明陶瓷及应用

透明陶瓷具有电光转换特性。在护目镜、图象存储等方面有广泛应用。     

OSCILLATION FOR NEUTRAL DELAY DIFFERENTIAL EQUATION WITH POSITIVE AND NEGATIVE COEFFICIENTS

In this paper, a new oscillating result is established for the first order neutral delay differential equation with positive and negative coefficients, which improves and generalizes several results in the literatures.     

30cm大屏幕高分辨率X光电视光学系统研究

本研究发表了30cm大屏幕高分辨率电视光学系统所采用的参数、系统设计、结构特点和所能达到的性能指标。该系统已通过广研制并投入批量生产。     

两体衰变径迹

在19MeV/u ⁴⁰Ar+²⁰⁹Bi反应中,云母片固体径迹探测器记录了几例连续两次衰变径迹.分析表明,这些事件两次衰变的时间间隔约为10^－13s.根据位垒穿透的WKB理论,这样的裂变是可能的.