全文获取类型
收费全文 | 4019篇 |
免费 | 687篇 |
国内免费 | 335篇 |
专业分类
化学 | 2620篇 |
晶体学 | 54篇 |
力学 | 295篇 |
综合类 | 17篇 |
数学 | 399篇 |
物理学 | 1656篇 |
出版年
2024年 | 16篇 |
2023年 | 108篇 |
2022年 | 144篇 |
2021年 | 174篇 |
2020年 | 162篇 |
2019年 | 157篇 |
2018年 | 158篇 |
2017年 | 123篇 |
2016年 | 217篇 |
2015年 | 200篇 |
2014年 | 229篇 |
2013年 | 309篇 |
2012年 | 382篇 |
2011年 | 368篇 |
2010年 | 248篇 |
2009年 | 215篇 |
2008年 | 239篇 |
2007年 | 224篇 |
2006年 | 214篇 |
2005年 | 177篇 |
2004年 | 129篇 |
2003年 | 104篇 |
2002年 | 82篇 |
2001年 | 73篇 |
2000年 | 82篇 |
1999年 | 69篇 |
1998年 | 65篇 |
1997年 | 52篇 |
1996年 | 55篇 |
1995年 | 52篇 |
1994年 | 28篇 |
1993年 | 40篇 |
1992年 | 39篇 |
1991年 | 23篇 |
1990年 | 21篇 |
1989年 | 15篇 |
1988年 | 11篇 |
1987年 | 7篇 |
1986年 | 6篇 |
1985年 | 10篇 |
1984年 | 1篇 |
1983年 | 6篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有5041条查询结果,搜索用时 0 毫秒
1.
本文研究并揭示了L_(2~a)(2~(2~a-1))型正交表行(列)间的递推规律,提出了一种泛函梯度数值计算的新方法——正交试验法,该方法在计算速度和精度上优于直接梯度法;在通用性及节省内存方面优于伴随算子法。 相似文献
2.
The theoretical proton-40Ca optical potential is constructed based on theα-particle model of the nucleus. With this potential, the differential cross section, analysing power and the spin rotation function for 200 MeV proton-40Ca elastic scattering are calculated. The results are in good agreement with the experimental data. 相似文献
3.
Envelop solitons in dusty plasmas for warm dust 总被引:1,自引:0,他引:1
A nonlinear Schrödinger equation is obtained for the warm dusty plasmas. The modulational instability of envelop soliton is investigated in this paper. Both the temperature of the dust grains and the charge variations of dust grains affect the instability regions of the dusty plasmas. It also affect the amplitude and the width of the envelop soliton. 相似文献
4.
5.
6.
连续一级反应的热动力学研究 总被引:1,自引:0,他引:1
本文把时间比法引入热动力学研究,建立了连续一级反应的热动力学研究法,并用来研究了一个连续反应体系的热动力学,验证了该方法的正确性. 相似文献
7.
A novel thermo-responsive 2,9(10),16(17),23(24)-tetrakis[(3-carboxyacrylamide) phthalocyaninato] zinc (ZnPc)-g-TiO2-g-poly(N-isopropylacrylamide) (PNIPAM) photocatalyst modified with phthalocyanines was prepared. The photocatalyst exhibited thermo-responsive properties due to the introduction of PNIPAM, which performed recovery for reuse above the lower critical solution temperature (LCST, about 26 °C). ZnPc-g-TiO2-g-PNIPAM effectively expanded the light response range to the visible light region and inhibited the recombination of electron–hole pairs, which enhanced the performance of the photocatalyst. As expected, ZnPc-g-TiO2-g-PNIPAM (0.3 g/L) exhibited excellent photocatalytic performance for the removal of Rhodamine B (RhB, 1.0 × 10−5 mol/L) and methylene blue (MB, 1.0 × 10−5 mol/L) under visible light, which reached 97.2% and 88.6% at 20 °C within 40 min, respectively. Furthermore, the influence of temperature upon photocatalytic performance was also investigated. When the temperature increased from 20 °C to 45 °C, the removal of RhB decreased by approximately 53.8%. The stability of the photocatalyst demonstrated that the photocatalytic activity was still above 80% for the removal of RhB after 3 cycles. Above all, this work provided an intelligent thermally responsive photocatalyst based on phthalocyanine for water purification under visible light. 相似文献
8.
Xiaohui Duan Mina Zhang Huan Du Xiu Gu Caihong Bai Liuqiang Zhang Kaixian Chen Kaifeng Hu Yiming Li 《Molecules (Basel, Switzerland)》2022,27(15)
Scrophulariae Radix (SR) is one of the oldest and most frequently used Chinese herbs for oriental medicine in China. Before clinical use, the SR should be processed using different methods after harvest, such as steaming, “sweating”, and traditional fire-drying. In order to investigate the difference in chemical constituents using different processing methods, the two-dimensional (2D) 1H-13C heteronuclear single quantum correlation (1H-13C HSQC)-based metabolomics approach was applied to extensively characterize the difference in the chemical components in the extracts of SR processed using different processing methods. In total, 20 compounds were identified as potential chemical markers that changed significantly with different steaming durations. Seven compounds can be used as potential chemical markers to differentiate processing by sweating, hot-air drying, and steaming for 4 h. These findings could elucidate the change of chemical constituents of the processed SR and provide a guide for the processing. In addition, our protocol may represent a general approach to characterizing chemical compounds of traditional Chinese medicine (TCM) and therefore might be considered as a promising approach to exploring the scientific basis of traditional processing of TCM. 相似文献
9.
Jianmei Liu Hong Wang Zhi Ma Qianheng Duan Yangyang Fei Xiangdong Meng 《Entropy (Basel, Switzerland)》2022,24(7)
In this paper, we consider the optimization of the quantum circuit for discrete logarithm of binary elliptic curves under a constrained connectivity, focusing on the resource expenditure and the optimal design for quantum operations such as the addition, binary shift, multiplication, squaring, inversion, and division included in the point addition on binary elliptic curves. Based on the space-efficient quantum Karatsuba multiplication, the number of CNOTs in the circuits of inversion and division has been reduced with the help of the Steiner tree problem reduction. The optimized size of the CNOTs is related to the minimum degree of the connected graph. 相似文献
10.
Counter-cations are essential components of polyoxometalates (POMs), which have a distinct influence on the solubility, stabilization, self-assembly, and functionality of POMs. To investigate the roles of cations in the packing of POMs, as a systematic investigation, herein, a series of triol-ligand covalently modified Cu-centered Anderson-Evans POMs with different counter ions were prepared in an aqueous solution and characterized by various techniques including single-crystal X-ray diffraction. Using the strategy of controlling Mo sources, in the presence of triol ligand, NH4+, Cu2+ and Na+ were introduced successfully into POMs. When (NH4)6Mo7O24 was selected, the counter cations of the produced POMs were ammonium ions, which resulted in the existence of clusters in the discrete state. Additionally, with the modulation of the pH of the solutions, the modified sites of triol ligands on the cluster can be controlled to form δ- or χ-isomers. By applying MoO3 in the same reaction, Cu2+ ions served as linkers to connect triol-ligand modified polyanions into chains. When Na4Mo8O26 was employed as the Mo source to react with triol ligands in the presence of CuCl2, two 2-D networks were obtained with {Na4(H2O)14} or {{Na2(H2O)4} sub-clusters as linkers, where the building blocks were δ/δ- and χ/χ-isomers, respectively. The present investigation reveals that the charges, sizes and coordination manners of the counter cations have an obvious influence on the assembled structure of polyanions. 相似文献