Thermodynamic Complexation of Dopamine with Zinc(II) in Media with Different Dielectric Constants

The complexation of zinc(II) with dopamine has been investigated by spectrophotometric measurements in mixed solvent system at an ionic strength of 0.2 mol•dm－3 sodium chloride, employed at at (15±0.1), (25±0.1), (35±0.1) ℃ at inin a pH range of ca. 6 to ca. 7 with a high ratio of ligand to metal. The effect of solvent systems on protonation and complexation are was was discussed. Linear relationships are werewere observed by plotting lg K versus 1/D, where K and D show stability and dielectric constants, respectively.     

Lattice Boltzmann simulation of natural convection in nanofluid-filled 2D long enclosures at presence of magnetic field

In this paper, the effects of a magnetic field on natural convection flow in filled long enclosures with Cu/water nanofluid have been analyzed by lattice Boltzmann method. This study has been carried out for the pertinent parameters in the following ranges: the Rayleigh number of base fluid, Ra = 10³–10⁵, the volumetric fraction of nanoparticles between 0 and 6 %, the aspect ratio of the enclosure between A = 0.5 and 2. The Hartmann number has been varied from Ha = 0 to 90 with interval 30 while the magnetic field is considered at inclination angles of θ = 0°, 30°, 60° and 90°. Results show that the heat transfer decreases by the increment of Hartmann number for various Rayleigh numbers and the aspect ratios. Heat transfer decreases with the growth of the aspect ratio but this growth causes the effect of the nanoparticles to increase. The magnetic field augments the effect of the nanoparticles at high Rayleigh numbers (Ra = 10⁵). The effect of the nanoparticles rises for high Hartmann numbers when the aspect ratio increases. The rise in the magnetic field inclination improves heat transfer at aspect ratio of A = 0.5.     

Novel integrated optic intensity modulator based on mode coupling

The analysis, design, realization, and measurements of a novel intensity modulator are reported. The operating principle is based on mode coupling between a passive low-loss SiON waveguide and an electro-optic high-loss polymer waveguiding structure. Matching the waveguides is critical and results in severe demands for the technology. Extended simulations by the Coupled Mode Theory, the Leaky Wave Model, and Finite Difference Beam Propagation Method resulted in the design of several modulator structures. After realization, modulation could be demonstrated at 632 nm and at 1523 nm using lossy waveguiding modes and surface plasmon modes.     

Optimization Implementation and Characterization of the Equal Allocation of Nonseparable Costs Value

This paper devotes to the study of the equal allocation of nonseparable costs value for cooperative games. On the one hand, we show that the equal allocation of nonseparable costs value is the unique optimal solution that minimizes the total complaints for individual players over the pre-imputation set. On the other hand, analogously to the way of determining the Nucleolus, we obtain the equal allocation of nonseparable costs value by applying the lexicographic order over the individual complaints. Moreover, we offer alternative characterizations of the equal allocation of nonseparable costs value by proposing several new properties such as dual nullifying player property, dual dummifying player property and grand marginal contribution monotonicity.     

Diamond anvil cell for measurements in high magnetic fields

Abstract

We constructed a diamond anvil cell for pressures up to 100 GPa in magnetic fields up to 12 T. The cell can be operated at any temperature between 10 and 350 K. Loading by condensation of gases is possible.     

Palm Raceme as a Promising Biomass Precursor for Activated Carbon to Promote Lipase Activity with the Aid of Eutectic Solvents

This study concerns the role of activated carbon (AC) from palm raceme as a support material for the enhancement of lipase-catalyzed reactions in an aqueous solution, with deep eutectic solvent (DES) as a co-solvent. The effects of carbonization temperature, impregnation ratio, and carbonization time on lipase activity were studied. The activities of Amano lipase from Burkholderia cepacia (AML) and lipase from the porcine pancreas (PPL) were used to investigate the optimum conditions for AC preparation. The results showed that AC has more interaction with PPL and effectively provides greater enzymatic activity compared with AML. The optimum treatment conditions of AC samples that yield the highest enzymatic activity were 0.5 (NaOH (g)/palm raceme (g)), 150 min, and a carbonization temperature of 400 °C. DES was prepared from alanine/sodium hydroxide and used with AC for the further enhancement of enzymatic activity. Kinetic studies demonstrated that the activity of PPL was enhanced with the immobilization of AC in a DES medium.