Heuristische Verfahren zur Tourenplanung bei der Hausmüllentsorgung in ländlichen Regionen

Zusammenfassung Tourenprobleme bei der Hausmüllsammlung lassen sich in die Reihe der Lieferplanprobleme einordnen. Zur Lösung praktischer Größenordnungen werden hier einfache heuristische Verfahren (Prioritätsregeln) vorgestellt, weniger um der Vielzahl heuristischer Verfahren weitere hinzuzufügen als vielmehr dem Praktiker einen vielversprechenden Weg beim Lösen seiner Probleme aufzuzeigen.

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Summary The discussed solid waste collection problem shows the properties of the so called truck dispatching problem. To solve problems for typical problem structure heuristic rules are pointed out in order to show the planner an efficient way of problem solving.

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Zusammenfassung dreier Vorträge im 4. planungstechnischen Seminar Tourenplanung bei der Abfallbeseitigung am Institut für Siedlungswasserwirtschaft der Universität Karlsruhe am 1.10.1976.     

Kriterien in der Theorie der Gleichverteilung

It is the aim of this paper to introduce two new notions of discrepancy. They are defined by the formulas $$\begin{gathered} \Delta _N^r \left( {\omega ;f} \right) = \mathop {\sup }\limits_{\left| z \right| = r} \left| {\left( {{1 \mathord{\left/ {\vphantom {1 N}} \right. \kern-\nulldelimiterspace} N}} \right)\sum\limits_{n = 1}^N {f\left( {z e^2 \pi i\omega \left( n \right)} \right)} - f\left( 0 \right)} \right|, and \hfill \\ \delta _N^r \left( {\omega ;f} \right) = \mathop {\sup }\limits_{\left| z \right| = r} \left| {\left( {{1 \mathord{\left/ {\vphantom {1 N}} \right. \kern-\nulldelimiterspace} N}} \right)\sum\limits_{n = 1}^N {f\left( {z \omega \left( n \right)} \right)} \cdot z - \int\limits_0^z {f\left( \zeta \right)d\zeta } } \right|, \hfill \\ \end{gathered} $$ wheref is a holomorphic function defined in the unit disc withf ^(k) (0)≠0 for allk∈?,r<1 is a positive number, and ω is a sequence in [0, 1]. The first of these discrepancies can be generalized for multidimensional sequences. ω is uniform distributed if and only if lim _N→∞ Δ _N ^r (ω;f)=0 resp. lim _N→∞δ _N ^r (ω;f)=0. These results are proved in a quantitative way by estimating the classical discrepancyD _N (ω) by means ofΔ _N ^r (ω;f) and δ _N ^r (ω;f): $$\begin{gathered} \Delta _N^r \left( {\omega ;f} \right) \ll D_N \left( \omega \right) \ll \Phi \left( {\Delta _N^r \left( {\omega ;f} \right)} \right), \hfill \\ \delta _N^r \left( {\omega ;f} \right) \ll D_N \left( \omega \right) \ll \Psi \left( {\delta _N^r \left( {\omega ;f} \right)} \right). \hfill \\ \end{gathered} $$ The functions Φ and Ψ only depend onf andr. These estimations are based on the inequalities ofKoksma-Hlawka andErdös-Turán.     

Adsorption of NH3 onto activated carbon prepared from palm shells impregnated with H2SO4

Adsorption of ammonia (NH3) onto activated carbons prepared from palm shells impregnated with sulfuric acid (H2SO4) was investigated. The effects of activation temperature and acid concentration on pore surface area development were studied. The relatively large micropore surface areas of the palm-shell activated carbons prepared by H2SO4 activation suggest their potential applications in gas adsorption. Adsorption experiments at a fixed temperature showed that the amounts of NH3 adsorbed onto the chemically activated carbons, unlike those prepared by CO2 thermal activation, were not solely dependent on the specific pore surface areas of the adsorbents. Further adsorption tests for a wide range of temperatures suggested combined physisorption and chemisorption of NH3. Desorption tests at the same temperature as adsorption and at an elevated temperature were carried out to confirm the occurrence of chemisorption due to the interaction between NH3 and some oxygen functional groups via hydrogen bonding. The surface functional groups on the adsorbent surface were detected by Fourier transform infrared spectroscopy. The amounts of NH3 adsorbed by chemisorption were correlated with the contents of elemental oxygen present in the adsorbents. Mechanisms for chemical activation and adsorption processes are proposed based on the observed phenomena.     

Waterborne polyurethane assembly multifunctional coating for hydrophobic and antibacterial fabrics

Surface modification of fabrics is a powerful strategy that can endow fabrics with desired effects while keeping the intrinsic properties. Herein, an ordinary strategy, dipping-drying based layer-by-layer self-assembly (LbL) coating, is reported to functionalize fabrics’ surfaces. Firstly, the novel cation waterborne polyurethanes (QAHDPU) and anion waterborne polyurethanes (HDPU) are successfully designed and synthesized. By incorporating targeted molecule, hydantoin diol (HD) and quaternary ammonium salt with long alkyl chain (DOQA), the QAHDPU are antibacterial and hydrophobically functionalized. Taking advantage of strong adhesion, waterborne polyurethanes (WPUs) are physically bonded to surfaces of fabrics to generate durable antibacterial and hydrophobic fabrics. The QAHDPU with long alkyl chain combined with rough and porous fabric surface fabricates hydrophobic fabric surface, which can prevent bacteria from adhering to the fabrics. Furthermore, the coated fabrics present excellent antibacterial properties after chlorination, forming a second barrier against bacteria. The chlorinated coated fabrics, can inactivate 85.0–99.9% of Staphylococcus aureus and 85.0–97.7% of Escherichia coli with contact time of 60 min. The hydrophobic properties of coated fabrics are greatly improved with water contact angles of 122.0°–141.1°. In addition, the proposed method is applicable for a variety of fibers and expected to be used for industrial production.

Graphical abstract

     

Inspection of the reversal of enantiomer migration order in ligand exchange micellar electrokinetic capillary chromatography

Enantiometers of D,L-phenylalanine were separated by capillary electrophoresis based on the principle of ligand exchange. Copper (II) complex of 4-hydroxy-L-proline was used as chiral selector. The separation and the migration order of D- and L-phenylalanine were strongly affected by adding an anion surfactant sodium dodecylsulfate (SDS). Without SDS in the electrolyte, the separation was also carried out but the resolution was very small. With SDS added into the electrolyte, the resolution decreased with increasing concentration of SDS until 5.0 mM. When the concentration of SDS in the electrolyte was over 5.0 mM, inversion of the migration order of DL-phenylalanine was observed and the resolution was also increased with increasing concentration up to 20 mM. It was interesting to find that the inversion of the migration order took place not only in the enantioscparation but also in the positional isomers. A family of a fluorinated amino acid, o-, m- and p-fluoro-D,L-phenylalanine was separated and the inversion of the migration order is discussed.     

Strukturviskosität von verdünnten Lösungen von Biopolymeren

The importance of the rheological behaviour of solutions of macromolecules is briefly evaluated. The viscosity of the solutions depends on concentration, shear rate and time of shear, this relation being determined by the structure of the dissolved molecules. In dilute solutions shear dependence of viscosity is very frequently caused by the preferential orientation of anisotropic molecules. In such a case the particle dimensions can be calculated from the true limiting viscosity number, an anisotropy factor, the rotational diffusion constant and the effective particle density. These numbers can be derived from the flow curve, which has been extrapolated to zero concentration. It is necessary to measure the flow curve at shear gradients, which are sufficiently low to allow for an extrapolation to vanishing shear rate. By comparing the experimental flow curve with a choice of theoretical ones, the rotational diffusion constant and the anisotropy factor (axial ratio) can be found. From the limiting viscosity number and the axial ratio, the particle density can be calculated.     

Instrumental neutron activation analysis of large samples: A pilot experiment

A large sample INAA (LS-INAA) was conducted based on available experimental conditions. Four different materials, e.g., a quartz-sand and three wastes from an incineration plant were analyzed on sample size of 1 kg. The neutron flux spatial distribution was determined by irradiation of flux monitors in the sample. The gamma-ray apparent counting efficiency was evaluated based on the effective-solid angle concept, using linear attenuation coefficients calculated from an iteration process. The k ₀- and the modified monostandard methods were modified for the LS-INAA. To check the LS-INAA performance, a conventional small sample INAA was carried out for the quartz sand and a waste. All detected elements in the LS-INAA are presented and the discussion is conducted to explore the sources of errors in the LS-INAA. As a pilot experiment, the information from this work will be used in constructing irradiation and counting devices for the new FRM-II neutron source in Garching, Germany.     

Komplexe von 2,6-Dimethylpyridin-1-oxid mit Lanthanidjodiden

Complexes of 2,6-dimethylpyridine 1-oxide with lanthanide iodides of the formulaeLn(2,6-LTNO)₅I₃ whereLn=La, Tb and Yb,Ln(2,6-LTNO)₄I₃ whereLn=Pr and Nd and Er(2,6-LTNO)_4.5I₃ have been prepared and characterised by chemical analysis, infrared and conductance studies. Infrared and conductance data have been interpreted in terms of dimeric (or polymeric) structures involving bridging amine oxide groups.

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Mit 2 Abbildungen     

Über die Synthese von 5-(o-Trifluormethylphenyl)-1H-thieno[3,4—e]-1,4-diazepin-2(3H)-onen

The synthesis of 5-(o-trifluoromethylphenyl)-1H-thieno-[3,4-e]1,4-diazepin-2(3H)-one (7) and its nitration and chlorination in pos. 8 are described.     

Berechnung von mittleren Schwingungsamplituden einiger tetraedrischer Moleküle und Ionen nach der Methode der charakteristischen Schwingungen

Mean amplitudes of vibration of a series of tetrahedralXY ₄ molecules and ions (hydrides, halides, oxides and oxoanions) have been calculated using the “Method of the Characteristic Vibrations” ofA. Müller. The results indicate that this method leads to very good values for most of the investigated species, and especially in the cases of highM _X/M_Y mass ratio.