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161.
162.
Radiophysics and Quantum Electronics - A well-known simplified model of turbulent convection from local sources of buoyancy and/or momentum acting for a short time has been developed and... 相似文献
163.
Haruki Inoue Dr. Shin-ichi Naya Atsunobu Akita Dr. Hisashi Sugime Prof. Dr. Hiroaki Tada 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(46):e202201653
Gold nanoparticles with different mean sizes were formed on antimony-doped tin oxide nanocrystals by the temperature-varied deposition-precipitation method (Au/ATO NCs). Au/ATO NCs possess strong absorption in the near-infrared region due to Drude excitation in addition to the localized surface plasmon resonance (LSPR) of AuNPs around 530 nm. Au/ATO NCs show thermally activated catalytic activity for the oxidation of cinnamyl alcohol to cinnamaldehyde by hydrogen peroxide. The catalytic activity increases with a decrease in the mean Au particle size (dAu) at 5.3 nm≤dAu≤8.2 nm. Light irradiation (λex >660 nm, ∼0.5 sun) of Au/ATO NCs increases the rate of reaction by more than twice with ∼95 % selectivity. Kinetic analyses indicated that the striking enhancement of the reaction stems from the rise in the temperature near the catalyst surface of ∼30 K due to the photothermal effect of the ATO NCs. 相似文献
164.
Ibotov Sh. Kh. Yuldasheva N. K. Mukarramov N. I. Zakirova R. P. Gusakova S. D. 《Chemistry of Natural Compounds》2022,58(4):728-731
Chemistry of Natural Compounds - 相似文献
165.
166.
Svetlakova A. V. Mendez M. Sanchez Tuchin E. S. Khodan A. N. Traore M. Azouani R. Kanaev A. Tuchin V. V. 《Optics and Spectroscopy》2021,129(8):846-850
Optics and Spectroscopy - We study the photocatalytic activity of nanocomposites based on θ-phase alumina (Al2O3) with different TiO2 concentrations for heterogeneous photocatalysis and... 相似文献
167.
Kolesnikov A. O. Shatokhin A. N. Vishnyakov E. A. Ragozin E. N. 《Journal of Russian Laser Research》2022,43(4):467-475
Journal of Russian Laser Research - We analyze the way of advancing to tender X-rays the short-wavelength bound of the operating range of flat-field grating spectrographs. We design two VLS grating... 相似文献
168.
Russian Chemical Bulletin - The N-methylation of primary carboxamides is based on two consecutive reactions. The silylation of the corresponding carboxamides with chloro(chloromethyl)dimethylsilane... 相似文献
169.
Journal of Structural Chemistry - Structural parameters and relative Gibbs free energies are calculated by density functional theory methods for four tetrafluoro derivatives of zinc(II)... 相似文献
170.
The molecular geometries and dissociation energies of AnO (An = Bk–Lr) molecules were first obtained at thecoupled-cluster single-, double-, and perturbative triple-excitations [CCSD(T)] level of theory. Four hybrid functionals,B3LYP, M06-2X, TPSSh, and PBE0, were also employed in the calculations for the sake of comparison. In comparison ofthe CCSD(T) results, B3LYP, TPSSh, and PBE0 functionals can obtain more appropriate results than M06-2X and MP2.The analyses on molecular orbitals show that the 7s, 6d, and 5f atomic orbitals of actinide (An) atoms participate in thebonding of An–O bonds. The partial covalent nature between An and O atoms is revealed by QTAIM analyses. 相似文献