Determination of the Tolman cone angle from crystallographic parameters and a statistical analysis using the crystallographic data base

Summary A new method of evaluating the Tolman cone angle from X-ray structural data available from the Cambridge Crystallographic Data Base has been developed and a statistical analysis of the cone angles of the phosphines PPh₃, PMe₂Ph, PMePh₂, PMe₃, PEt₃ and PCy₃ (Cy = cyclohexyl) in transition metal complexes has been completed.     

Quark masses from regularized integrals of vector current spectral functions

We give estimates of quark masses from a comparison of two methods of regularizing the coefficient of the Schwinger term. The masses of the first radial excited states of ?, ω, and ? would have to be slightly higher than indicated by the new Orsay data for this method to yield real solutions for the masses of theu, d, ands quarks.     

The Efimov effect in a four-body system

It is shown, using a Born-Oppenheimer model, that the four-body Efimov effect may occur in a system consisting of three identical heavy particles and one light particle, if the light-heavy interaction leads to a zeroenergy two-heavy-one-light bound state.     

Stability criteria for controlled queueing systems

We give an almost complete classification of ergodicity and transience conditions for a general multi-queue system with the following features: arrivals form Poisson streams and there are various routing schemes for allocating arrivals to queues; the servers can be configured in a variety of ways; completed jobs can feed back into the system; the exponential service times and feedback probabilities depend upon the configuration of the servers (this model includes some types of multi-class queueing system); switching between service regimes is instantaneous. Several different levels of control of the service regimes are considered. Our results for the N-queue system require randomisation of service configurations but we have studied the two queue system in situations where there is less control. We use the semi-martingale methods described in Fayolle, Malyshev and Menshikov [3] and our results generalise Kurkova [8] and complement Foley and McDonald [4] and [5]. AMS 2000 subject classification: Primary: 90B22; Secondary: 60J10 90B15     

Coherent backscattering of light from saturated atoms

We survey recent progress achieved in understanding the impact of inelastic processes on coherent backscattering of light from cold atoms that are saturated by a powerful laser field.     

Surface analysis and surface measuring techniques in firearm offences

Summary When a shot is fired, the projectile and the cartridge case are released from the weapon, as well as components of the priming charge and propellant, the so-called powder-gunshot residues. In order to solve firearm offences, it is therefore very important to determine the topography of trace-bearing areas on the bullet and the cartridge case, as well as the chemical composition of gunshot residue particles. Gunshot residue particles are made visible with the scanning electron microscope (SEM) and are analysed by means of energy-dispersive X-ray spectroscopy (EDXS) and lately also by means of wavelength-dispersive X-ray spectroscopy (WDXS). In addition to this, analyses of these particles are displayed by means of Auger electron spectroscopy (AES) and secondary ion mass spectroscopy (SIMS) and depth profiles are prepared. To determine the local distributions of gunshot residue elements with regard to their quantity, the direct Zeeman atomic absorption spectroscopy (DZ-AAS) is employed. Besides the determination of the chemical composition, the topography of the trace-bearing areas on the bullet and cartridge case plays an important part. For the detection of these surfaces, light optical and electron-optical methods are employed. Moreover, the use of opto-electronical testing systems has been attracting more and more attention recently.