首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   96356篇
  免费   23316篇
  国内免费   5707篇
化学   89576篇
晶体学   687篇
力学   5103篇
综合类   328篇
数学   8580篇
物理学   21105篇
  2024年   502篇
  2023年   4737篇
  2022年   3422篇
  2021年   4568篇
  2020年   6507篇
  2019年   4351篇
  2018年   3912篇
  2017年   2321篇
  2016年   7845篇
  2015年   7891篇
  2014年   7791篇
  2013年   8830篇
  2012年   7860篇
  2011年   5748篇
  2010年   6583篇
  2009年   6358篇
  2008年   4324篇
  2007年   3662篇
  2006年   2743篇
  2005年   2341篇
  2004年   1783篇
  2003年   1427篇
  2002年   1306篇
  2001年   1057篇
  2000年   913篇
  1999年   1071篇
  1998年   878篇
  1997年   886篇
  1996年   870篇
  1995年   864篇
  1994年   694篇
  1993年   729篇
  1992年   526篇
  1991年   458篇
  1990年   386篇
  1989年   315篇
  1988年   292篇
  1987年   261篇
  1986年   238篇
  1985年   236篇
  1977年   327篇
  1976年   381篇
  1975年   477篇
  1974年   479篇
  1973年   300篇
  1972年   388篇
  1971年   362篇
  1970年   551篇
  1969年   419篇
  1968年   461篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
201.
This paper deals with the global classical solvability of the Cauchy problem for nonlinear wave equations of higher order of the following form where denotes the Laplacian, a real constant, m a positive integer, and f the nonlinearity. Using results of the first part [6] concerning estimations for the kernel of the associated integral equation a priori estimates for certain LP-norms of the local regular solution are established for higher space dimensions and for a class of nonlinearities satisfying certain growth and positivity conditions. This leads to completely regular solutions by means of the Sobolev embedding theorems.  相似文献   
202.
It is shown by a simple induction that any square-free natural number is the square-free kernel of Euler's -function of infinitely many natural numbers. Furthermore every square-free natural number >1 is the square-free kernel of Euler's -function of infinitely many square-numbers.  相似文献   
203.
Let ={e(u)|uI} be a one-parameter family of straight lines forming a ruledC r-2-surface E n (n2,r1) without singular generatorse(u) (uI). As a synopsis, a generalization and an improvement of various results already known about the strictional properties of ruled surfaces E n (especially in the casen=3) the author demonstrates a uniform geometrical way of defining and uniquely obtaining thestriction point S(u) and theparameter of distribution d(u) of a generatore(u) under the minimal assumptions thate(u)E n (n2) be noncylindrical andr1. Other methods of obtainingS(u) andd(u) are discussed in comparison, and special strictional properties ofskew ruled surfaces E n are proved.

Herrn Prof. Dr. H. R. Müller zum 65. Geburtstag  相似文献   
204.
The classical Gauss-Bonnet formula has the form I(gij)=2, where I(gij) represents a sum of three terms each of which depends on the metric tensor gij. It is shown that the first variation I of I(gij) with respect to the metric gij vanishes and that for the Euclidean metric ij we have I(ij)=2. From this the formula I(gij)=2 follows. In the process, explicit expressions are obtained for the first variation of each of the three terms which comprise I(gij). Furthermore, a general expression for the first variation of a multiple integral whose integrand is a scalar density depending on the metric tensor gij and its derivatives up to the second order is obtained with the aid of results of Rund [1].  相似文献   
205.
LetQ(u) be a positive definite quadratic form inr2 variables with a real symmetric coefficient matrix of determinantD. Given a real vectorb with 0b j <1, forx>0 letA(x) be the number of lattice points in the ellipsoidQ(u+b)x, letV(x) be the volume of this ellipsoid andP(x)=A(x)–V(x). Let . By introduction of a parameter we shall show how the treatment of estimates onP(x) and onM(x) can be unified.  相似文献   
206.
Summary Letf i :A R ben real-valued objective functions on a convex setA -K m ,K:=R orC, n, mN. Letg: A R n be defined by , where for eachxA, (i 1 (x), ..., i n (x)) is a permutation of (1, ...,n) such that . In this paper we treat the problem of findingx *A such that , wherel-max denotes the lexicographic maximum. If the fi's are strongly quasiconcave we can reduce the problem stepwise until finally it is in the form of a scalar programming problem. Further, we consider conditions for the existence and uniqueness of a solution and discuss the relationship of the problem to the vector maximum (i.e. Pareto) and maxmin (i.e. Chebychev) problems.
Zusammenfassung f i :AR seienn reellwertige Zielfunktionen über einer konvexen MengeA-K m ,K:=R oderC, n, mN. g:AR n sei definiert durch , wobei für jedesxA (i 1 (x), ... i n (x)) eine Permutation von (1, ...,n) derart ist, daß Wir betrachten das Problem, einx *A so zu finden, daß , wobeil-max das lexikographische Maximum bedeute. Falls dief i stark quasikonkav sind, läßt sich das Problem stufenweise reduzieren, bis es schließlich die Gestalt eines skalaren Optimierungsproblems annimmt. Wir geben Existenz- und Eindeutigkeitsbedingungen an und besprechen Zusammenhänge mit dem Vektormaximumproblem (d.h. Pareto-Optimierung) und dem Maxmin-Problem (d.h. Tschebyscheff-Optimierung).
  相似文献   
207.
Cellulose acetate (CA) ultrafiltration hollow fibers were spun via the dry-jet wet spinning technique. The effect of the take-up speed on the mechanical properties, morphology, thermal properties, pure water permeation, retention, and surface characterization of hollow fiber membranes were investigated. Both the inner and outer diameters of the hollow fiber decreased with the increase of take-up speed. Macrovoids were observed on the inner surface of the drawn hollow fibers. The d-space decreased with the increase of the take-up speed. The ultimate tensile stress (UTS) increased and the breaking elongation decreased with the increase of take-up speed. The permeation performance was measured. The hydraulic permeability increased and the retention decreased slightly with the increase of the take-up speed. The surface roughness increased with the increase of the take-up speed. The thermal analysis results showed that the endothermic peak shifts to the higher temperature region and coefficient of thermal expansion (CTE) decrease for a higher take-up speed.  相似文献   
208.
The biosorption of radionuclide 241Am from solution by Saccharomyces cerevisiae (S. cerevisiae), and the effects of experimental conditions on the adsorption were investigated. The preliminary results showed thatS. cerevisiae is a very efficient biosorbent. An average of more than 99% of the total 241Am could be removed by S. cerevisiae of 2.1 g/l (dry weight) from 241Am solutions of 17.54–4386.0 mg/l (2.22 MBq/l–555 MBq/l) with adsorption capacities of 7.45–1880.0 mg/g biomass (dry weight) (0.94 MBq/g–237.9 MBq/g). The adsorption equilibrium was achieved within 1 hour and the optimum pH ranged 1–3. No significant differences on 241Am adsorption were observed at 10–45 °C, or in solutions containing Au3+ or Ag+, even 2000 times above 241Am concentration. The relationship between concentrations and adsorption capacities of 241Am indicated the biosorption process should be described by the Freundlich adsorption isotherm.  相似文献   
209.
We report here porphodilactol derivatives and their corresponding metal complexes. These systems show promise as “all-in-one” phototheranostics and are predicated on a design strategy that involves controlling the relationship between intersystem crossing (ISC) and photothermal conversion efficiency following photoexcitation. The requisite balance was achieved by tuning the aromaticity of these porphyrinoid derivatives and forming complexes with one of two lanthanide cations, namely Gd3+ and Lu3+. The net result led to a metalloporphodilactol system, Gd-trans-2, with seemingly optimal ISC efficiency, photothermal conversion efficiency and fluorescence properties, as well as good chemical stability. Encapsulation of Gd-trans-2 within mesoporous silica nanoparticles (MSN) allowed its evaluation for tumour diagnosis and therapy. It was found to be effective as an “all-in-one” phototheranostic that allowed for NIR fluorescence/photoacoustic dual-modal imaging while providing an excellent combined PTT/PDT therapeutic efficacy in vitro and in vivo in 4T1-tumour-bearing mice.

We report here porphodilactol derivatives and their corresponding metal complexes as “all-in-one” phototheranostics by controlling the relationship between intersystem crossing (ISC) and photothermal conversion efficiency following photoexcitation.  相似文献   
210.
Near infrared luminescence is observed in tetrametallic [Zn2Yb2L2(mu-OH)2Cl4].2MeCN which is obtained from the Zn3 Schiff-base complex [Zn3L2(NO3)2].MeOH, (H2L =N,N'-bis(5-bromo-3-methoxysalicylidene)propylene-1,3-diamine).  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号