An analysis on forced convection in a channel filled with a Brinkman-Darcy porous medium: Exact and approximate solutions

An analysis was made to investigate non-Darcian fully developed flow and heat transfer in a porous channel bounded by two parallel walls subjected to uniform heat flux. The Brinkmanextended Darcy model was employed to study the effect of the boundary viscous frictional drag on hydrodynamic and heat transfer characteristics. An exact expression has been derived for the Nusselt number under the uniform wall heat flux condition. Approximate results were also obtained by exploiting a momentum integral relation and an auxiliary relation implicit in the Brinkmanextended Darcy model. Excellent agreement was confirmed between the approximate and exact solutions even in details of velocity and temperature profiles.     

Heat transfer between gas-liquid spray stream flowing perpendicularly to the row of the cylinders

Experimental investigation and analysis of heat transfer process between a gas-liquid spray flow and the row of smooth cylinders placed in the surface perpendicular to the flow has been performed. Among others, there was taken into account in the analysis the phenomenon of droplets bouncing and omitting the cylinder as well as the phenomenon of the evaporation process from the liquid film surface.In the experiments test cylinders were used, which were placed between two other cylinders standing in the row.From the experiments and the analysis the conclusion can be drawn that the heat transfer coefficients values for a row of the cylinders are higher than for a single cylinder placed in the gasliquid spray flow.

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Wärmeübergang an eine senkrecht anf eine Zylinderreihe auftreffende Gas-Flüssigkeits-Sprüh-Strömung

Zusammenfassung Es wurden Messungen und theoretische Analysen des Wärmeübergangs zwischen einer Gas-FlüssigkeitsSprüh-Strömung und den glatten Oberflächen einer Zylinderreihe durchgeführt, die senkrecht zum Sprühstrahl angeordnet waren. Dabei wurde in der Analyse unter anderem das Phänomen betrachtet, daß die Tropfen die Zylinderwand treffen und verfehlen können und daß sich ein Verdampfungsprozeß aus dem flüssigen Film an der Zylinderoberfläche einstellt.Gemessen wurde an einem zwischen zwei Randzylindern befindlichen Zylinder.Die Experimente und die Analyse gestatten die Schlußfolgerung, daß der Wärmeübergangskoeffizient für eine Zylinderreihe höher ist als für einen einzelnen Zylinder in der Sprühströmung.

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Nomenclature a distance between axes of cylinders, m - c _l specific heat capacity of liquid, J/kg K - c _g specific heat capacity of gas, J/kg K - D cylinder diameter, m - g _l mass velocity of liquid, kg/m²s - ¯k average volume ratio of liquid entering film to amount of liquid directed at the cylinder in gas-liquid spray flow, dimensionless - k() local volume ratio of liquid entering film to amount of liquid directed at the cylinder in gas-liquid spray flow, dimensionless - L specific latent heat of vaporisation, J/kg - m mass fraction of water in gas-liquid spray flow, dimensionless - M constant in Eq. (9) - p pressure, Pa - p _g statical pressure of gas, Pa - p _w pressure of gas on the cylinder surface, Pa - p external pressure on the liquid film surface, Pa - r cylindrical coordinate, m - R radius of cylinder, m - T temperature, K, °C - T _l, t_l liquid temperature in the gas-liquid spray, K, °C - T _w,t_w temperature of cylinder surface, K, °C - T temperature of gas-liquid film interface, K - U liquid film velocity, m/s - w gas velocity on cylinder surface, m/s - w _g gas velocity in free stream, m/s - W _l liquid vapour mass ratio in free stream, dimensionless - W liquid vapour mass ratio at the edge of a liquid film, dimensionless - x coordinate, m - y coordinate, m - z complex variable, dimensionless - average heat transfer coefficient, W/m²K - local heat transfer coefficient, W/m² K - average heat transfer coefficient between cylinder surface and gas, W/m² K - _g, local heat transfer coefficient between cylinder surface and gas, W/m² K - mass transfer coefficient, kg/m²s - liquid film thickness, m - _lg dynamic diffusion coefficient of liquid vapour in gas, kg/m s - pressure distribution function on a cylinder surface - function defined by Eq. (3) - _l liquid dynamic viscosity, kg/m s - _g gas dynamic viscosity, kg/m s - cylindrical coordinate, rad, deg - _l thermal conductivity of liquid, W/m K - _g thermal conductivity of gas, W/m K - mass transfer driving force, dimensionless - _l density of liquid, kg/m³ - _g density of gas, kg/m³ - _w shear stress on the cylinder surface, N/m² - _w shear stress exerted by gas at the liquid film surface, N/m² - air relative humidity, dimensionless - T -T _w - _w =T _wT_l Dimensionless parameters I= enhancement factor of heat transfer - m ^*=M _l/M_g molar mass of liquid to the molar mass of gas ratio - Nu _g= D/ _g gas Nusselt number - Pr _g=c _{g g}/_g gas Prandtl number - Pr _l=c_lll liquid Prandtl number - ¯r=(r–R)/ dimensionless coordinate - Re _g=w_gD _g/_g gas Reynolds number - Re _g,max=w_g,max D _g/_g gas Reynolds number calculated for the maximal gas velocity between the cylinders - Sc=m ^* _g/_l–g Schmidt number =/R dimensionless film thickness     

Free convection from a vertical plate with concentrated and distributed thermal sources

An analysis is developed for the laminar free convection from a vertical plate with uniformly distributed wall heat flux and a concentrated line thermal source embedded at the leading edge. We introduce a parameter=(1 +Q _L/Q_w)^–1=(1 + Ra_L/Ra_w)^–1 to describe the relative strength of the two thermal sources; and propose a unified buoyancy parameter=( Ra_L+ Ra_w)^1/5 with=1/(1 +Pr ^–1) to properly scale the dependent and independent variables. The variables are so defined that the resulting nonsimilar boundary-layer equations can describe exactly the buoyancy-induced flow from the dual sources with any relative strength to fluids of any Prandtl number from very small values to infinity. These nonsimilar equations are readily reducible to the self-similar equations of an adiabatic wall plume for=0, and to those of free convection from uniform flux plate for=1. Rigorous finite-difference solutions for fluids of Pr from 0.001 to are obtained over the entire range of from 0 to 1. The effects of both relative source strength and Prandtl number on the velocity profiles, temperature profiles, and the variations of wall temperature, are clearly illustrated.

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Freie Konvektion an einer vertikalen Platte mit einer konzentrierten und einer gleichmäßig verteilten Wärmequelle

Zusammenfassung Für die freie Konvektion an einer vertikalen Platte mit einer gleichmäßig verteilten Wandwärmestromdichte und einer in der Vorderkante eingebetteten linienförmigen Wärmequelle wird eine Berechnungsmethode entwickelt. Zur Beschreibung der relativen Stärke der beiden Wärmequellen führen wir einen Parameter=(1 + Q_L/Q_w)^–1=(1 + Ra_L/Ra_w)^–1 ein und schlagen einen vereinheitlichten Auftriebsparameter=( Ra _L+ Ra _w)^1/5 mit=1/(1 +Pr ^–1 für die Skalierung der abhängigen und unabhängigen Variablen vor. Die Variablen werden so definiert, daß mit den sich ergebenden unabhängigen Grenzschichtgleichungen die von den beiden Wärmequellen beliebiger Stärke verursachte Auftriebsströmung von Fluiden beliebiger Prandtl-Zahl genau beschrieben werden kann. Diese unabhängigen Gleichungen können ohne weiteres auf die selbstähnlichen Gleichungen für den Fall einer lokalen Wärmezufuhr an einer sonst adiabatischen Wand für=0 und jenen der freien konvektion an einer Platte mit einheitlichem Wärmestrom für=1 zurückgeführt werden. Für Fluide mit der Prandtl-Zahl zwischen 0,001 und Unendlich werden nach der strengen finite Differenzen-Methode Lösungen im Bereich von zwischen 0 und 1 erhalten. Der jeweilige Einfluß der relativen Quellenstärke und der Prandtl-Zahl auf die Geschwindigkeits- und Temperaturprofile sowie die Veränderung der Wandtemperatur werden deutlich dargestellt.

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Nomenclature C _f friction coefficient - C _p specific heat - f reduced stream function - g gravitational acceleration - k thermal conductivity - L width of the plate - Nu local Nusselt number - Pr Prandtl number - q _w wall heat flux - Q _L heat generated by the line source - Q _w heat released by the uniform-flux wall from 0 tox, q _w Lx - Ra _L local Rayleigh number, g T _L ^* x ³/( ) - Ra _w local Rayleigh number,g T _w ^* w ³/( ) - T fluid temperature - T temperature of ambient fluid - T _L ^* characteristic temperature of the line source,Q _{L/(C p} L) - T _w ^* characteristic temperature of the uniform flux wall, =q _w x/k=Q _w /(C _p L) - u velocity component in then-direction - U₀ dimensionless velocity,u/(/x) Ra _L ^2/5 - U ₁ dimensionless velocity,u/(/x) Ra _w ^2/5 - velocity component in they-direction - x coordinate parallel to the plate - y coordinate normal to the plate - thermal diffusivity - thermal expansion coefficient - pseudo-similarity variable,(y/x) - dimensionless temperature, (T–T )/(T _L ^* +T _w ^* ) - ₀ dimensionless temperature, (Ra_l)^1/5 (T–T )/T _L ^* - ₁ dimensionless temperature, (Ra_w)Ra_w)^1/5 (T–T )/T _w ^* - (Ra _L+Ra_w)^1/5 - kinematic viscosity - (1 +Ra _L/Ra_w)^–1=(1 +T _L ^* /T _w ^* )^–1=(1 + Q_L/Q_w)^–1 - density - Pr/(1 +Pr) - _w wall shear stress - stream function     

Experimental NMR and MS study of benzoylguanidines. Investigation of E/Z isomerism

Molecules containing the guanidinic nuclei possess several pharmacological applications, and knowing the preferred isomers of a potential drug is important to understand the way it operates pharmacologically. Benzoylguanidines were synthesized in satisfactory to good yields and characterized by NMR, Electrospray Ionization Mass Spectrometry (ESI‐MS) and Fourrier Transform InfraRed Spectroscopy techniques (FTIR). E/Z isomerism of the guanidines was studied and confirmed by NMR analysis in solution (¹H‐¹³C Heteronuclear Single Quantum Coherence (HSQC) and Heteronuclear Multiple‐Bond Correlation (HMBC), ¹H‐¹⁵N HMBC, ¹H‐¹H Correlation Spectroscopy (COSY) and Nuclear Overhauser Effect Spectroscopy (NOESY) experiments) at low temperatures. Compounds with p‐Cl and p‐Br aniline moiety exist mainly as Z isomer with a small proportion of E isomer, whereas compounds with p‐NO2 moiety showed a decrease in proportion of isomer Z. The results are important for the application of these molecules as enzymatic inhibitors. Copyright © 2013 John Wiley & Sons, Ltd.     

The electrochemistry of arylated anthraquinones in room temperature ionic liquids

Arylated anthraquinone derivatives of different sizes and different π‐basicities have been prepared, and the electrochemical behaviour of these substances has been studied on screen printed graphite electrodes in the three room temperature ionic liquids (RTILs), 1‐butyl‐3‐methylimidazolium hexafluorophosphate ([C₄MIM][PF₆]), 1‐hexyl‐3‐methylimidazolium hexafluorophosphate ([C₆MIM][PF₆]) and 1‐octyl‐3‐methylimidazolium hexafluorophosphate ([C₈MIM][PF₆]). Half redox potentials for the first and second one electron reduction waves were identified, and the diffusion coefficient values were estimated from cyclic voltammetry measurements. The influence of the nature of the RTIL and of the substitution pattern of the anthraquinone on the solvodynamic radii were studied. A correlation of the reductive potentials with the corresponding Hammett constants of the substituents was tested. Copyright © 2013 John Wiley & Sons, Ltd.     

X‐ray absorption study of the local structure at the NiO/oxide interfaces

This work reports an X‐ray absorption near‐edge structure (XANES) spectroscopy study at the Ni K‐edge in the early stages of growth of NiO on non‐ordered SiO₂, Al₂O₃ and MgO thin films substrates. Two different coverages of NiO on the substrates have been studied. The analysis of the XANES region shows that for high coverages (80 Eq‐ML) the spectra are similar to that of bulk NiO, being identical for all substrates. In contrast, for low coverages (1 Eq‐ML) the spectra differ from that of large coverages indicating that the local order around Ni is limited to the first two coordination shells. In addition, the results also suggest the formation of cross‐linking bonds Ni—O—M (M = Si, Al, Mg) at the interface.     

Multiscale modeling of submonolayer growth for Fe/Mo (110)

We use a multiscale approach to study a lattice-gas model of submonolayer growth of Fe/Mo (110) by Molecular Beam Epitaxy. To begin with, we construct a two-dimensional lattice-gas model of the Fe/Mo (110) system based on our first-principles calculations of the monomer diffusion barrier and adatom-adatom interactions. The model is investigated by equilibrium Monte Carlo (MC) simulations to compute the diffusion coefficients of Fe islands of different sizes. These diffusion coefficients are used as input to the coarse-grained kinetic rate equation (KRE) approach. We also evaluate effects of the range of Fe-Fe interaction, restriction of interaction to third nearest neighbors allowed to develop feasible atomistic kinetic Monte Carlo (KMC) model. We calculate time evolution of the island size distributions by both KMC and KRE methods and find good agreement between the two methods.