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961.
A derivatographic method has been developed for the identification and determination of the pyrites content of bauxites and clay minerals. If the sample contains at least 0.2% of pyrite, then at 400–450° a weight increase is indicated on the DTG curve, while a heat liberation is shown on the DTA curve. The amplitude of or the area under, these maxima is proportional to the pyrites content of the sample, although the correlation is not linear. In addition, the effect of experimental conditions on the thermal decomposition of pyrites has been studied. 相似文献
962.
T. F. Sysoeva Z. A. Starikova S. D. Ershova N. M. Dyatlova 《Journal of Structural Chemistry》1991,32(2):293-296
All-Union Scientific-Research Institute of Chemical Reagents and Ultrapure Chemical Substances. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 2, pp. 163–166, March–April, 1991. 相似文献
963.
964.
Fluorescence lifetimes of isolated membranes of Rhodopseudomonas viridis were measured in the temperature range of 77 K to 25 K. At room temperature, the main component of the fluorescence decay of bacteriochlorophyll (BChl) b had a time constant of 50 ps. In contrast to other purple bacteria, the emission at low temperature was spectrally homogeneous and showed essentially single lifetimes of 140 ps at 77 K and 180 ps at 25 K, with the primary electron donor in the oxidized state. Taking into account the relative fluorescence yields with open and closed reaction centers, we arrive at numbers of 125 ps and 215 ps, respectively, for open reaction centers. These numbers are significantly smaller than expected on the basis of measurements of the efficiency of charge separation, perhaps suggesting that the excitation decay in the absence of reaction centers is considerably faster at low temperature than at room temperature. At least four different spectral components with different lifetimes were observed at 25 K in the emission of Heliobacterium chlorum, a short-wavelength component of about 30 ps and three longer-wavelength components of about 100 ps, 300 ps, and 900 ps. This indicates a strong heterogeneity in the emitting pigment, BChl g-808. The component with the shortest lifetime does not appear to be affected by the redox state of the reaction center and might reflect energy transfer to BChl g species which are connected to the reaction center. 相似文献
965.
Ferbinteanu M Roesky HW Cimpoesu F Atanasov M Köpke S Herbst-Irmer R 《Inorganic chemistry》2001,40(19):4947-4955
A general synthetic strategy starting from metal alkyls is reported based on the hydrogen difluoride anion as a suitable reagent for obtaining organometallic fluorides. The newly prepared compounds are [Me(4)N][(i-Bu)(2)AlF(2)] (1), [Ph(4)P][(i-Bu)(2)AlF(2)] (2), and [Ph(4)P][AlF(4)] (3), containing the tetrahedral anions [(i-Bu)(2)AlF(2)](-) and [AlF(4)](-). The actual structures are prototypes that allowed a comparison of inorganic and organometallic fluorides in the frame of the hard and soft acid and base principle, by means of ab initio calculations. A new theoretical model is designed to put in equation form the qualitative statements of the Bent rule. The model allows the rationalization of the tendencies of bond angle variation in [R(2)MX(2)] systems containing a main group metal (M), in terms of hybridization of the central atom and the reciprocal influence of hard and soft ligands. 相似文献
966.
Using a version of density-functional theory which combines Onsager approximation and fundamental-measure theory for spatially nonuniform phases, we have studied the phase diagram of freely rotating hard rectangles and hard discorectangles. We find profound differences in the phase behavior of these models, which can be attributed to their different packing properties. Interestingly, bimodal orientational distribution functions are found in the nematic phase of hard rectangles, which cause a certain degree of biaxial order, albeit metastable with respect to spatially ordered phases. This feature is absent in discorectangles, which always show unimodal behavior. This result may be relevant in the light of recent experimental results which have confirmed the existence of biaxial phases. We expect that some perturbation of the particle shapes (either a certain degree of polydispersity or even bimodal dispersity in the aspect ratios) may actually destabilize spatially ordered phases thereby stabilizing the biaxial phase. 相似文献
967.
An expression for the extreme values of mean-square amplitudes of vibrations in polyatomic molecules has been derived which permits estimation of the mean-square amplitude without solving the vibrational problem. This expression can be improved for the stretching and scissoring modes when the assignment of frequencies is known. In turn, the corresponding vibrational frequency may be estimated from the experimental value of the mean-square amplitude. The mean-square amplitudes of the butadiene-1,3 molecule are considered as an example. 相似文献
968.
V. F. Borodkin V. A. Burmistrov M. K. Islyaikin 《Chemistry of Heterocyclic Compounds》1981,17(1):49-51
The PMR spectra of the macroheterocyclic compound obtained by the reaction of 5-tert-butyl-1,3-diiminoisoindoline with 1,3-phenylenediamine in refluxing butyl alcohol and purified by chromatography on aluminum oxide were recorded. It is shown that the compound does not contain a unified conjugated macroring system. The dependence of the chemical shift of the protons of the endocyclic imino groups on the nature of the solvent was investigated. It is shown that the formation of compound-solvent intermolecular hydrogen bonds is complicated by steric factors.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 62–64, January, 1981. 相似文献
969.
Using recently developed theoretical techniques it has been possible to achieve an exact variational solution of the Schrödinger equation within a modest basis set or one-eleltron functions. The full configuration interaction for this system included a total of 256473 1A1 spin-and space-adapted configurations. Comparison with many-body perturbation theory proves to be quite interesting. 相似文献
970.