Begleitfiguren und Invariantensystem minimaler Differentiationsordnung von Kurven im reellenn-dimensionalen affinen Raum

For such curves we know a moving frame and a complete system of invariants (affine curvatures) with respect to the group of volume-conserving transformations (unimodular group) of the order 2n?1 respectively 2n (see [1], p. 171). In this paper we study for a curvec a moving frame and a system of invariants of the minimal ordern+1, respectivelyn+2, by means of a curve with vanishing affine curvatures that has contact of maximal order withc. Forn=3 this is a result ofA. Winternitz ([1], p. 171 or [3], p. 86).     

Heuristische Verfahren zur Tourenplanung bei der Hausmüllentsorgung in ländlichen Regionen

Zusammenfassung Tourenprobleme bei der Hausmüllsammlung lassen sich in die Reihe der Lieferplanprobleme einordnen. Zur Lösung praktischer Größenordnungen werden hier einfache heuristische Verfahren (Prioritätsregeln) vorgestellt, weniger um der Vielzahl heuristischer Verfahren weitere hinzuzufügen als vielmehr dem Praktiker einen vielversprechenden Weg beim Lösen seiner Probleme aufzuzeigen.

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Summary The discussed solid waste collection problem shows the properties of the so called truck dispatching problem. To solve problems for typical problem structure heuristic rules are pointed out in order to show the planner an efficient way of problem solving.

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Zusammenfassung dreier Vorträge im 4. planungstechnischen Seminar Tourenplanung bei der Abfallbeseitigung am Institut für Siedlungswasserwirtschaft der Universität Karlsruhe am 1.10.1976.     

Kriterien in der Theorie der Gleichverteilung

It is the aim of this paper to introduce two new notions of discrepancy. They are defined by the formulas $$\begin{gathered} \Delta _N^r \left( {\omega ;f} \right) = \mathop {\sup }\limits_{\left| z \right| = r} \left| {\left( {{1 \mathord{\left/ {\vphantom {1 N}} \right. \kern-\nulldelimiterspace} N}} \right)\sum\limits_{n = 1}^N {f\left( {z e^2 \pi i\omega \left( n \right)} \right)} - f\left( 0 \right)} \right|, and \hfill \\ \delta _N^r \left( {\omega ;f} \right) = \mathop {\sup }\limits_{\left| z \right| = r} \left| {\left( {{1 \mathord{\left/ {\vphantom {1 N}} \right. \kern-\nulldelimiterspace} N}} \right)\sum\limits_{n = 1}^N {f\left( {z \omega \left( n \right)} \right)} \cdot z - \int\limits_0^z {f\left( \zeta \right)d\zeta } } \right|, \hfill \\ \end{gathered} $$ wheref is a holomorphic function defined in the unit disc withf ^(k) (0)≠0 for allk∈?,r<1 is a positive number, and ω is a sequence in [0, 1]. The first of these discrepancies can be generalized for multidimensional sequences. ω is uniform distributed if and only if lim _N→∞ Δ _N ^r (ω;f)=0 resp. lim _N→∞δ _N ^r (ω;f)=0. These results are proved in a quantitative way by estimating the classical discrepancyD _N (ω) by means ofΔ _N ^r (ω;f) and δ _N ^r (ω;f): $$\begin{gathered} \Delta _N^r \left( {\omega ;f} \right) \ll D_N \left( \omega \right) \ll \Phi \left( {\Delta _N^r \left( {\omega ;f} \right)} \right), \hfill \\ \delta _N^r \left( {\omega ;f} \right) \ll D_N \left( \omega \right) \ll \Psi \left( {\delta _N^r \left( {\omega ;f} \right)} \right). \hfill \\ \end{gathered} $$ The functions Φ and Ψ only depend onf andr. These estimations are based on the inequalities ofKoksma-Hlawka andErdös-Turán.     

Strukturviskosität von verdünnten Lösungen von Biopolymeren

The importance of the rheological behaviour of solutions of macromolecules is briefly evaluated. The viscosity of the solutions depends on concentration, shear rate and time of shear, this relation being determined by the structure of the dissolved molecules. In dilute solutions shear dependence of viscosity is very frequently caused by the preferential orientation of anisotropic molecules. In such a case the particle dimensions can be calculated from the true limiting viscosity number, an anisotropy factor, the rotational diffusion constant and the effective particle density. These numbers can be derived from the flow curve, which has been extrapolated to zero concentration. It is necessary to measure the flow curve at shear gradients, which are sufficiently low to allow for an extrapolation to vanishing shear rate. By comparing the experimental flow curve with a choice of theoretical ones, the rotational diffusion constant and the anisotropy factor (axial ratio) can be found. From the limiting viscosity number and the axial ratio, the particle density can be calculated.     

Komplexe von 2,6-Dimethylpyridin-1-oxid mit Lanthanidjodiden

Complexes of 2,6-dimethylpyridine 1-oxide with lanthanide iodides of the formulaeLn(2,6-LTNO)₅I₃ whereLn=La, Tb and Yb,Ln(2,6-LTNO)₄I₃ whereLn=Pr and Nd and Er(2,6-LTNO)_4.5I₃ have been prepared and characterised by chemical analysis, infrared and conductance studies. Infrared and conductance data have been interpreted in terms of dimeric (or polymeric) structures involving bridging amine oxide groups.

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Mit 2 Abbildungen     

Über die Synthese von 5-(o-Trifluormethylphenyl)-1H-thieno[3,4—e]-1,4-diazepin-2(3H)-onen

The synthesis of 5-(o-trifluoromethylphenyl)-1H-thieno-[3,4-e]1,4-diazepin-2(3H)-one (7) and its nitration and chlorination in pos. 8 are described.     

Berechnung von mittleren Schwingungsamplituden einiger tetraedrischer Moleküle und Ionen nach der Methode der charakteristischen Schwingungen

Mean amplitudes of vibration of a series of tetrahedralXY ₄ molecules and ions (hydrides, halides, oxides and oxoanions) have been calculated using the “Method of the Characteristic Vibrations” ofA. Müller. The results indicate that this method leads to very good values for most of the investigated species, and especially in the cases of highM _X/M_Y mass ratio.     

An electronic aid for line selection for scanning inductively coupled plasma atomic emission spectrometers

This article is an electronic publication in Spectrochimica Acta Electronica (SAE), the electronic section of Spectrochimica Acta Part B (SAB). Accompanying this hard copy text is a disk containing the program, source flies, data files and a brief manual along with a few programming notes. The main article discusses the purpose of this work, and the Appendix provides brief instruction on the use of the program, manipulation of the data, and source code. An automatic file selection system for the control of a rapid scanning spectrometer performing atomic emission spectrometry has been developed using the PROLOG language. The system can be “taught” the elemental composition of a given sample type. It uses this information (when available) to generate a linear search strategy which minimizes the number of lines that need to be measured. The rules used by the system can be observed during system operation to allow a trace of the logic. Reading of the initial data base takes no more than 6 s and then decisions are made in less than 1 s per line.     

Die Hydrohalogenierung von Hexaphenyldigerman und die Schwingungsspektren einiger Ge2(C6H5) n X6−n -Verbindungen

The reactions of Ge₂(C₆H₅)₆ with HCl and HBr lead in nearly quantitative yields to the 1,1,2,2-tetrahalo derivatives Cl₂(C₆H₅)GeGe(C₆H₅)Cl₂ (I) and Br₂(C₆H₅)GeGe(C₆H₅)Br₂ (II), resp. The Si?Ge bond of (C₆H₅)₃SiGe(C₆H₅)₃ is cleaved under the conditions of hydrohalogenation. The vibrational spectra of Ge₂Br₆, Ge₂(C₆H₅)₆, I, and II are reported. The influence of vibrational coupling on ν GeGe in these compounds is discussed in detail, including vibrational calculations.     

Lysine peroxycarbamates: free radical-promoted peptide cleavage

Strategies are reported that combine in one step a predictable chemical-based protein digestion with mass spectrometry. Lysine residue amino groups in peptides and proteins are modified by reaction with a peroxycarbonate derived from p-nitrophenol, and tert-butyl hydroperoxide. The peroxycarbonate reacts with lysine residues in peptides and proteins, and the resulting lysine peroxycarbamates undergo homolytic fragmentation under conditions of low-energy collision-induced dissociation (CID). Observed fragmentation of the peptides involves apparent free radical processes including Hofmann-L?ffler-type rearrangements that lead to peptide chain fragmentation. Strategies for directed cleavage of peptides by free radical promoted processes are feasible, and such strategies may well simplify schemes for protein analysis.