Quantum field theories of vortices and anyons

We develop the quantization of topological solitons (vortices) in three-dimensional quantum field theory, in terms of the Euclidean region functional integral. We analyze in some detail the vortices of the abelian Higgs model. If a Chern-Simons term is added to the action, the vortices turn out to be anyons, i.e. particles with arbitrary real spin and intermediate () statistics. Localization properties of the interpolating field, scattering theory and spin-statistics connection of anyons are discussed. Such analysis might be relevant in connection with the fractional quantum Hall effect and two-dimensional models of HighT _csuperconductors.     

Precipitation structure in an Al-2·0 at. % Zn-1·0 at. % Mg alloy within and close to the grain boundaries and its effects on mechanical properties

During ageing the Al-2·0 at. %Zn-1·0 at. % Mg alloy at elevated temperatures the width of the precipitation free zone (PFZ) at both sides of the grain boundaries (GB) is identical with that free of quenched-in dislocation loops (DL). After sufficiently long ageing a band of precipitates is growing inside the former PFZ and the DLs in the midgrain regions act as sites for the heterogeneous nucleation of the-phase. Two precipitation processes significantly affect the mechanical properties. TEM correlates grain boundary precipitate density and morphology with grain boundary misorientation.     

Periodic solutions of some infinite-dimensional Hamiltonian systems associated with non-linear partial difference equations. II

This is our second paper devoted to the study of some non-linear Schrödinger equations with random potential. We study the non-linear eigenvalue problems corresponding to these equations. We exhibit a countable family of eigenfunctions corresponding to simple eigenvalues densely embedded in the band tails. Contrary to our results in the first paper, the results established in the present paper hold for an arbitrary strength of the non-linear (cubic) term in the non-linear Schrödinger equation.     

Speeding-up and scaling of domain-wall relaxation nearT c of a uniaxial ferromagnet

The dynamic susceptibility () measured between 10 Hz and 10 MHz on different GdCl₃-ellipsoids (T _c=2.21 K) reveals a completely reversible motion of the domain walls. Taking into account the contribution of the fast adiabatic intradomain magnetization to the nearly Debye-shaped (), we determine for the first time the kinetic Onsager coefficientL _d of the domain wall relaxation of a ferromagnet. Approaching the CurietemperatureL _d speeds up critically, which by a novel simple relaxational model can be related to the increasing width (=correlation length) of linear Bulaevskii-Ginzburg domain-walls and to the shrinking domain period. The reduction ofL _d by an external field can be represented by a universal scaling function, and within the same dynamical model, this effect is ascribed to the increase of the domain period, predicted for a bubble phase. However, the effect of sample size onL _d is much smaller than expected.     

4-Amino-imidazole durchThorpe-Cyclisierung

The alkylation of arylaminomethylenecyanamides1 or cyano-imidothiocarbamates2 with -halogen carbonyl compounds followed by base catalysed cyclization yields substituted 4-amino-imidazoles4. Imidazo[4,5-d]pyrimidones5, 6 and imidazo[4,5-b]pyridines7 can be obtained from4.     

The electrocapillarity of polyacrylates

Summary The electrocapillary properties of polyacrylic acid have been studied by two methods. Exploratory measurements have been made of the effect of the polymer on the differential capacity of a mercury drop in 0.1 m sodium perchlorate. They showed that the polymer was strongly adsorbed over a wide range of potentials but that it did not appear to form a monolayer. The surface excess of polymer obtained from drop weight data showed a maximum at very low concentrations and then a decline at higher concentrations. The bulk of the work was carried out by making surface tension measurements, using a sessile mercury drop, in solutions of a fraction of polyacrylic acid (mol. wt. 7.02×10⁴) in potassium chloride at 0.01, 0.1, 0.2, and 0.5 m at 25°C.The data have been used to evaluate the surface excesses of the polymer and of the inorganic ions. The distribution of K⁺ and Cl^– in the electrical double layer and the contact adsorption of Cl^– on the mercury were very little affected by the presence of the polymer. The surface excess of polymer was always found to be greatest at low concentrations, to decrease steeply at first as the concentration was increased and then to decrease more slowly at higher concentrations.Possible explanations of this behaviour are discussed and it is concluded that the rapid decrease is a consequence of molecular weight dispersion and the stronger adsorption of high molecular weight polymer. The slow decrease in surface excess at higher concentrations may be a result of configurational changes of the polymer molecules.Surface pressure data show that, despite this decrease in the surface excess, the surface coverage reaches a high level at very low polymer concentrations and then continues to increase slowly as the concentration of polymer is increased. This apparent contradiction is due to changes in configuration of the adsorbed polymer molecules. At higher bulk concentrations the chain configurations are more compact and each adsorbed molecule makes more contacts with and so occupies a greater area of the mercury surface than at low concentrations.The conclusion is reached that the surface excess of polymer is mostly contained in a layer probably more than 1000 Å thick. It consists of a concentrated and entangled mass of polymer chains. Relatively few of these chains are in contact with the mercury at any istant. The concentration in this surface layer decreases steadily with increasing distance from the mercury surface and it merges without discontinuity into the bulk solution.With 10 figures in 22 details