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931.
Holger Ott Christoph Matthes Dr. Arne Ringe Dr. Jörg Magull Prof. Dr. Dietmar Stalke Prof. Dr. Uwe Klingebiel Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(18):4602-4609
Borenes and boranes : Silylaminoiminoborenes, such as depicted, were isolated after treatment of halogen triels with silylaminofluoroboranes. In addition, novel aryl‐ and silyl‐substituted diaminofluoroboranes were also prepared in order to substantiate this reaction route.
932.
Benito Alcaide Prof. Dr. Pedro Almendros Dr. Rocío Carrascosa Dipl.‐Chem. Teresa Martínez del Campo Dipl.‐Chem. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(11):2496-2499
Positive discrimination : Chemo‐ and regioselective palladium‐catalyzed cycloetherification of allendiols, namely β,γ‐ and γ,δ‐allendiols, may occur by judicious choice of palladium‐catalyzed conditions owing to their potential ability to discriminate between both nucleophilic sites (see scheme).
933.
Roberto E. Di Paolo Dr. Hugh D. Burrows Prof. Jorge Morgado Prof. António L. Maçanita Prof. 《Chemphyschem》2009,10(2):448-454
Non‐Stokes–Einstein relaxation : The rate constant of conformational relaxation of a phenylenevinylene trimer (see picture) in different solvents is proportional to η?α, with α values decreasing from close to unity (low viscosity) to zero at sufficiently high solvent viscosity. This behaviour is attributed to the flexible methylbutyl side chains of the trimer, which partially screen the solvent friction.
934.
Reza Latifi Mojtaba Bagherzadeh Prof. Dr. Sam P. de Visser Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(27):6651-6662
A series of hydrogen‐abstraction barriers of a nonheme iron(IV)–oxo oxidant mimicking the active species of taurine/α‐ketoglutarate dioxygenase (TauD) are rationalized by using a valence‐bond curve‐crossing diagram (see figure). It is shown that the barriers correlate with the strength of the C? H bond. Furthermore, electronic differences explain the differences between nonheme and heme iron(IV)–oxo hydrogen‐abstraction barriers.
935.
Yong S. Chong Dr. William R. Carroll William G. Burns Mark D. Smith Ken D. Shimizu Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(36):9117-9126
An atropisomeric molecular balance was developed to study face‐to‐face arene–arene interactions. The balance has a large central 1,4,5,8‐naphthalene diimide surface that forms intramolecular arene–arene interactions with two pendent arms. The balance adopts distinct syn and anti isomers with varying numbers of intramolecular interactions. Thus, the strength of the arene–arene interaction could be quantitatively measured by NMR spectroscopy from the anti/syn ratios. The size of the arene arms was easily varied, which allowed examination of the relationship between arene size and strength of the interaction. A nonlinear size dependence was observed in solution with larger arene arms having a disproportionately stronger arene–arene interaction. The intramolecular arene–arene interactions were also characterized in the solid state by X‐ray crystallography. These studies were facilitated by the kinetic stability of the syn and anti isomers at room temperature due to the high isomerization barrier (ΔG=27.0 kcal mol?1). Thus, the anti isomer could be selectively isolated and crystallized in its folded conformation. The X‐ray structures confirmed that the anti isomers formed two strong intramolecular arene–arene interactions with face‐to‐face geometries. The solid‐state structure analysis also reveals that the rigid framework may contribute to the observed nonlinear size trend. The acetate linker is slightly too long, which selectively destabilizes the balances with smaller arene arms. The larger arene arms are able to compensate for the longer linker and form effective intramolecular arene–arene interactions. 相似文献
936.
Victoria E. Campbell Xavier de Hatten Dr. Nicolas Delsuc Dr. Brice Kauffmann Dr. Ivan Huc Dr. Jonathan R. Nitschke Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(25):6138-6142
Systemic change : A system of transformations between helical structures was observed to be governed by interactions mediated by the electronic effects of substituents, entropic effects, the conformational preferences of organic building blocks, and the coordinative preferences of the metal ion. All of these effects were important, but all must be considered together to allow the prediction of the product observed (see scheme).
937.
Ramón Valencia Antonio Rodríguez‐Fortea Dr. Anna Clotet Dr. Coen de Graaf Dr. Manuel N. Chaur Luis Echegoyen Prof. Dr. Josep M. Poblet Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(41):10997-11009
An extensive study of the redox properties of metal nitride endohedral fullerenes (MNEFs) based on DFT computational calculations has been performed. The electronic structure of the singly oxidized and reduced MNEFs has been thoroughly analyzed and the first anodic and cathodic potentials, as well as the electrochemical gaps, have been predicted for a large number of M3N@C2n systems (M=Sc, Y, La, and Gd; 2n=80, 84, 88, 92, and 96). In particular, calculations that include thermal and entropic effects correctly predict the different anodic behavior of the two isomers (Ih and D5h) of Sc3N@C80, which is the basis for their electrochemical separation. Important differences were found in the electronic structure of reduced M3N@C80 when M=Sc or when M is a more electropositive metal, such as Y or Gd. Moreover, the changes in the electrochemical gaps within the Gd3N@C2n series (2n=80, 84, and 88) have been rationalized and the use of Y‐based computational models to study the Gd‐based systems has been justified. The redox properties of the largest MNEFs characterized so far, La3N@C2n (2n=92 and 96), were also correctly predicted. Finally, the quality of these predictions and their usefulness in distinguishing the carbon cages for MNEFs with unknown structures is discussed. 相似文献
938.
Gaiping Li Dan Li Lixue Zhang Junfeng Zhai Erkang Wang Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(38):9868-9873
We report here a facile method to obtain folic acid (FA)‐protected gold nanoparticles (Au NPs) by heating an aqueous solution of HAuCl4/FA in which FA acts as both the reducing and stabilizing agent. The successful formation of FA‐protected Au NPs is demonstrated by UV/Vis spectroscopy, transmission electron microscopy (TEM), selected‐area electron diffraction (SAED), X‐ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectroscopy (FTIR). The intracellular uptake of these nanoparticles is facilitated by HeLa cells overexpressing the folate reporter, which itself is significantly inhibited by free FA in a competitive assay as quantified by inductively coupled plasma mass spectroscopy (ICP‐MS). This simple one‐step approach affords a new perspective for creating functional nanomaterials, and the resulting biocompatible, functional Au NPs may find some prospective applications in various biomedical fields. 相似文献
939.
Dieter Hauchecorne Dr. Roman Szostak Dr. Wouter A. Herrebout Prof. Benjamin J. van der Veken Prof. 《Chemphyschem》2009,10(12):2105-2115
The formation of weakly bound molecular complexes between dimethyl ether (DME) and the trifluoromethyl halides CF3Cl, CF3Br and CF3I dissolved in liquid argon and in liquid krypton is investigated, using Raman and FTIR spectroscopy. For all halides evidence is found for the formation of C? X???O halogen‐bonded 1:1 complexes. At higher concentrations of CF3Br, a weak absorption due to a 1:2 complex is also observed. Using spectra recorded at temperatures between 87 and 125 K, the complexation enthalpies for the complexes are determined to be ?6.8(3) kJ mol?1 (DME?CF3Cl), ?10.2(1) kJ mol?1 (DME?CF3Br), ?15.5(1) kJ mol?1 (DME?CF3I), and ?17.8(5) kJ mol?1 [DME(?CF3Br)2]. Structural and spectral information on the complexes is obtained from ab initio calculations at the MP2/ 6‐311++G(d,p) and MP2/6‐311++G(d,p)+LanL2DZ* levels. By applying Monte Carlo free energy perturbation calculations to account for the solvent influences, and statistical thermodynamics to estimate the zero‐point vibrational and thermal influences, the ab initio complexation energies are converted into complexation enthalpies for the solutions in liquid argon. The resulting values are compared with the experimental data deduced from the cryosolutions. 相似文献
940.
Rui Xu Dr. W. Bernd Schweizer Dr. Holger Frauenrath Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(36):9105-9116
A series of symmetrically and unsymmetrically substituted octa‐2,4,6‐triyne‐1,8‐diol derivatives with benzoyl, 4‐dodecyloxybenzoyl, as well as perfluorobenzoyl substituents were prepared and investigated with respect to their crystal structures and topochemical polymerizability. Single‐crystal structures for several of these triacetylene monomers have been obtained and proved that the perfluorophenyl–phenyl interactions played a decisive role in the molecular packing. As a consequence of the geometric requirements imposed by the perfluorophenyl–phenyl interactions, packing parameters appropriate for a topochemical triacetylene polymerization in the sense of either a 1,6‐ or a 1,4‐polyaddition along different crystallographic axes were observed in two cases, and UV irradiation led to successful polymerization. Raman as well as solid‐state 13C NMR spectra of the obtained polymers revealed that the polymerization had predominantly proceeded in the form of a 1,4‐polyaddition. 相似文献