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951.
Yang Min Dr. Chuandong Dou Prof. Hongkun Tian Prof. Jun Liu Prof. Lixiang Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(13):4364-4372
The B←N unit has a large dipole and it is isoelectronic to C−C moiety with no dipole. Incorporating B←N units into π-conjugated system is a powerful strategy to design organic small molecules and polymers with intriguing opto-electronic properties and excellent opto-electronic device performance. However, it is unclear how the B←N unit affects electronic structures and opto-electronic properties of large π-conjugated molecules. In this work, to address this question, we developed three dibenzo-azaacene molecules in which two B←N units were introduced at different positions. Although the dibenzo-azaacene skeleton is fully π-conjugated, the effect of B←N unit on the electronic structures of the adjacent rings is much stronger than that of the distant rings. As a result, the three molecules with isomerized B←N incorporation patterns possess different electronic structures and exhibit tunable opto-electronic properties. Among the three molecules, the centrosymmetrical molecule exhibits higher LUMO/HOMO energy levels than those of the two axisymmetrical molecules. When used as the active layer in organic field-effect transistors (OFETs), while the two axisymmetrical molecules show unipolar electron transporting property, the centrosymmetrical molecule exhibits ambipolar hole and electron transporting behavior. This work not only deepens our understanding on organoboron π-conjugated molecules, but also indicates a new strategy to tune opto-electronic properties of organic semiconductors for excellent device performance. 相似文献
952.
953.
Steffen Maier Nikolai Hippchen Dr. Frank Rominger Dr. Jan Freudenberg Prof. Uwe H. F. Bunz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(66):16320-16324
The synthesis of novel (N−)acene-based cyclooligomers is reported. Glaser-Hay coupling of the bisethynylated monomers results in cyclodimers and cyclotrimers that are separable by column and gel-permeation chromatographies. For the diazatetracene, the use of sec-butyl-silylethynyl groups is necessary to achieve solubility. Diazatetracene-based cyclodimers and cyclotrimers were used as semiconductors in thin-film transistors. Although their optoelectronic properties are quite similar, their electron mobilities in proof-of-concept thin-film transistors differ by an order of magnitude. 相似文献
954.
955.
Dr. Kai-Stephan Feichtner Dr. Lennart T. Scharf Dr. Thorsten Scherpf Dr. Bert Mallick Nils Boysen Prof. Dr. Viktoria H. Gessner 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(69):17351-17360
The use of iminophosphoryl-tethered ruthenium carbene complexes to activate secondary phosphine P−H bonds is reported. Complexes of type [(p-cymene)-RuC(SO2Ph)(PPh2NR)] (with R = SiMe3 or 4-C6H4−NO2) were found to exhibit different reactivities depending on the electronics of the applied phosphine and the substituent at the iminophosphoryl moiety. Hence, the electron-rich silyl-substituted complex undergoes cyclometallation or shift of the imine moiety after cooperative activation of the P−H bond across the M=C linkage, depending on the electronics of the applied phosphine. Deuteration experiments and computational studies proved that cyclometallation is initiated by the activation process at the M=C bond and triggered by the high electron density at the metal in the phosphido intermediates. Consistently, replacement of the trimethylsilyl (TMS) group by the electron-withdrawing 4-nitrophenyl substituent allowed the selective cooperative P−H activation to form stable activation products. 相似文献
956.
957.
958.
Gintare Grybauskaite-Kaminskiene Dr. Dmytro Volyniuk Dr. Viktorija Mimaite Oleksandr Bezvikonnyi Dr. Audrius Bucinskas Dr. Gintautas Bagdziunas Prof. Juozas V. Grazulevicius 《Chemistry (Weinheim an der Bergstrasse, Germany)》2018,24(38):9581-9591
Derivatives of 9-phenyl-9H-carbazole were synthesized as efficient emitters exhibiting both thermally activated delayed fluorescence and aggregation-induced emission enhancement. Effects of methoxy and tert-butyl substituents at the different positions of carbazolyl groups on the properties of the emitters were studied. Depending on the substitutions, photoluminescence quantum yields (PLQY) of non-doped solid films of the compounds ranged from 17 % to 53 % which were much higher than those observed for the solutions in low-polarity solvent toluene. Compounds substituted at C-3 and C-6 positions of carbazole moiety by methoxy- and tert-butyl- groups showed the highest solid-state PLQY. Ionization potentials of the studied derivatives in solid-state were found to be in the short range of 5.75–5.89 eV. Well-balanced hole and electron mobilities were detected for tert-butyl-substituted compound. They exceeded 10−4 cm2 (V×s)−1 at electric fields higher than 3×105 V cm−1. Two compounds with the highest solid-state PLQYs showed higher efficiencies in non-doped organic light-emitting diodes than in the doped devices. Maximum external quantum efficiency of 7.2 % and brightness of 15000 cd m−2 were observed for the best device. 相似文献
959.
Back Cover: Rhodium‐Catalyzed Ketone Methylation Using Methanol Under Mild Conditions: Formation of α‐Branched Products (Angew. Chem. Int. Ed. 3/2014) 下载免费PDF全文