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51.
R. Britton J. L. Burnett A. V. Davies P. H. Regan 《Journal of Radioanalytical and Nuclear Chemistry》2014,300(3):1253-1259
GEANT4 Monte Carlo simulations have been successfully utilised to characterise a Compton suppressed broad-energy HPGe detector. The detector setup has been fully recreated in the simulation, which has been optimised to consistently reproduce the detector response. The peak efficiencies for both the primary BEGe detector and NaI(Tl) guard detectors agree with the simulated values for multiple test sources within 3 %. Compton suppression has also been simulated, with good agreement seen between the simulated and actual CSF values (<10 %) for multiple radionuclides. A secondary reference source was also simulated, which contained up to 30 radionuclides in a different geometry to that of the previous source. This showed excellent agreement with experimental data in both unsuppressed and suppressed modes of operation. 相似文献
52.
A substituted donor–acceptor cyclobutenecarboxamide is synthesized with modest enantiocontrol through a chiral copper(I) complex catalyzed [3 + 1]-cycloaddition reaction of α-acyl diphenylsulfur ylides with 3-siloxy-2-diazo-3-butenamides. With a methyl substituent on the 4-position of the 3-butenamide, the cis-vicinal-3,4-disubstituted cyclobutenecarboxamide is formed with >20:1 diastereocontrol. Donor-acceptor 3-methyl-2-siloxycyclopropenecarboxamide is rapidly formed from the reactant enoldiazoamide and undergoes catalytic ring opening to give only the Z-γ-substituted metallo-enolcarbene. Elimination from 3-siloxy-2-diazo-3-pentenamide to form the conjugated 3-siloxy-2,4-pentadienamide is competitive but minimized at low temperature. 相似文献
53.
Shira D. Halperin Hope Fan Stanley Chang Dr. Rainer E. Martin Prof. Robert Britton 《Angewandte Chemie (International ed. in English)》2014,53(18):4690-4693
Fluorination reactions are essential to modern medicinal chemistry, thus providing a means to block site‐selective metabolic degradation of drugs and access radiotracers for positron emission tomography imaging. Despite current sophistication in fluorination reagents and processes, the fluorination of unactivated C? H bonds remains a significant challenge. Reported herein is a convenient and economic process for direct fluorination of unactivated C? H bonds that exploits the hydrogen abstracting ability of a decatungstate photocatalyst in combination with the mild fluorine atom transfer reagent N‐fluorobenzenesulfonimide. This operationally straightforward reaction provides direct access to a wide range of fluorinated organic molecules, including structurally complex natural products, acyl fluorides, and fluorinated amino acid derivatives. 相似文献
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55.
Dr. Melanie M. Britton 《Chemphyschem》2014,15(9):1731-1736
The development of improved energy‐storage devices, as well as corrosion prevention and metal‐electrofinishing technologies, requires knowledge of local composition and transport behaviour in electrolytes near bulk metals, in situ and in real time. It remains a challenge to acquire such data and new analytical methods are required. Recent work shows that magnetic resonance imaging (MRI) is able to map concentration gradients and visualise electrochemical processes in electrochemical cells containing bulk metals. This recent work, along with the challenges, and solutions, associated with MRI of these electrochemical cells are reviewed. 相似文献
56.
57.
α-Arylation and Ring Expansion of Annulated Cyclobutanones: Stereoselective Synthesis of Functionalized Tetralones 下载免费PDF全文
Dr. Stanley Chang Dr. Michael Holmes Dr. Jeffrey Mowat Michael Meanwell Prof. Robert Britton 《Angewandte Chemie (International ed. in English)》2017,56(3):748-752
α-Arylcyclobutanones display unique reactivity that makes them valuable synthetic intermediates and target molecules. We describe the preparation of α-aryl- and α-heteroarylcyclobutanones through a direct α-arylation reaction. Problematic fragmentations are avoided by the use of LiOtBu, which promotes a rapid but reversible self-aldol reaction that slowly releases the enolate required for α-arylation. We also demonstrate the ring expansion of α-arylcyclobutanones, a process that is highlighted in the stereoselective synthesis of 1-methoxy coniothyrinone D. 相似文献
58.
Michael Adamski Thomas J. G. Skalski Benjamin Britton Dr. Timothy J. Peckham Lukas Metzler Prof. Steven Holdcroft 《Angewandte Chemie (International ed. in English)》2017,56(31):9058-9061
Two classes of novel sulfonated phenylated polyphenylene ionomers are investigated as polyaromatic-based proton exchange membranes. Both types of ionomer possess high ion exchange capacities yet are insoluble in water at elevated temperatures. They exhibit high proton conductivity under both fully hydrated conditions and reduced relative humidity, and are markedly resilient to free radical attack. Fuel cells constructed with membrane-electrode assemblies containing each ionomer membrane yield high in situ proton conductivity and peak power densities that are greater than obtained using Nafion reference membranes. In situ chemical stability accelerated stress tests reveal that this class of the polyaromatic membranes allow significantly lower gas crossover and lower rates of degradation than Nafion benchmark systems. These results point to a promising future for molecularly designed sulfonated phenylated polyphenylenes as proton-conducting media in electrochemical technologies. 相似文献
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60.
Leibfried D DeMarco B Meyer V Rowe M Ben-Kish A Britton J Itano WM Jelenković B Langer C Rosenband T Wineland DJ 《Physical review letters》2002,89(24):247901
We show how an experimentally realized set of operations on a single trapped ion is sufficient to simulate a wide class of Hamiltonians of a spin-1/2 particle in an external potential. This system is also able to simulate other physical dynamics. As a demonstration, we simulate the action of two nth order nonlinear optical beam splitters comprising an interferometer sensitive to phase shift in one of the interferometer beam paths. The sensitivity in determining these phase shifts increases linearly with n, and the simulation demonstrates that the use of nonlinear beam splitters (n=2,3) enhances this sensitivity compared to the standard quantum limit imposed by a linear beam splitter (n=1). 相似文献