A two-step biomimetic synthesis of antimalarial robustadials A and B

The antimalarial robustadials A and B have been synthesized in two steps starting from commercially available phloroglucinol comprising a key biomimetic three-component reaction that involves in situ generation of an o-quinone methide via Knoevenagel condensation and subsequent Diels-Alder cycloaddition with (−)-β-pinene.     

Synchrotron radiation total reflection X-ray fluorescence (SR-TXRF) for evaluation of food contamination

Summary The objective of this study was to use synchrotron radiation total reflection X-ray fluorescence analysis (SR-TXRF) for the determination of metals and other elements in food available to the population in commercial establishments, in order to evaluate the risks of contamination by these products. The analyzed species were vegetables, leafy vegetables, fruits, cereal and grain. The results indicated that some species were contaminated by Cr, Cu, Zn and Pb with concentrations much higher than the reference values.     

Resonances in Muon Transfer from Muonic Hydrogen to Oxygen and Neon

The influence of resonances on the muon transfer processes from muonic hydrogen to oxygen and neon (pμ)_1s + O⁸⁺ → p + (μO)_nl⁷⁺ and (pμ)_1s + Ne¹⁰⁺ → p + (μNe)_nl⁹⁺ is considered using the Smith lifetime matrix formalism. It is shown that the existence of a long lived resonance in the case of Ne induces a stronger dependence on collision energy of the muon transfer cross-section for this system. Present address: Chemistry Department, Vancouver University, Vancouver, BC V6T 1Z3, Canada     

Spin tunneling properties in mesoscopic magnets: effects of a magnetic field

The tunneling of a giant spin at excited levels is studied theoretically in mesoscopic magnets with a magnetic field at an arbitrary angle in the easy plane. Different structures of the tunneling barriers can be generated by the magnetocrystalline anisotropy, the magnitude and the orientation of the field. By calculating the nonvacuum instanton solution explicitly, we obtain the tunnel splittings and the tunneling rates for different angle ranges of the external magnetic field ( θ _H = π/2 and π/2 < θ _H < π). The temperature dependences of the decay rates are clearly shown for each case. It is found that the tunneling rate and the crossover temperature depend on the orientation of the external magnetic field. This feature can be tested with the use of existing experimental techniques. Received 12 March 2001 and Received in final form 18 October 2001     

The high-T c superconductor Sr0.2Lai1.8CuO4: A direct and inverse-photoemission study

We have measured ultraviolet and inverse-photoemission spectra of the novel superconductor Sr₀₂La_1.8CuO₄. Our results compare favorably with recent band-structure calculations for La₂CuO₄.A full account of this work will be published elsewhere [1]     

Properties of (InGa)As/GaAs QW (λ ≈ 1.2 µm) facet-coated edge emitting diode laser

In this paper, we report on the design and optical properties of laser diodes with an emission wave-length of ～1170 nm based on an (InGa)As/GaAs double quantum well active layer. The back and front facet of the laser diodes were coated with SiO_x dielectric films that influence the output optical power by enhancing or lowering the facet reflectivity. The measurements show improvement of the facet-coated laser diode properties in the threshold-current-density reduction along with light output power enhancement. Furthermore, a narrow far field pattern and high side mode suppression have been observed.     

A NOVEL METHOD FOR FABRICATING COMPOSITE MOSAIC MEMBRANE WITH UNIQUE NF SELECTIVITY

A novel method of fabricating composite mosaic membranes was studied on the basis of interracial polymerization （IP） by coating a thin selective layer onto the surface of a micro-porous hollow-fiber membrane, in which, 2,5-diaminobenzene sulfonic acid was used as one monomer of the IP reaction, and a mixture of trimesoyl chloride （TMCI） and 4-（chloromethyl） benzoyl chloride as the other monomer. Through the IP reaction a thin selective layer with negatively charged groups could be first formed on the polyethersulfone （PES） support membrane. Then trimethylamine solution was introduced to modify the IP layer through a quaternization reaction. Thus the selective layer of this composite membrane contained both negatively charged and positively charged groups to perform the mosaic functionality. Characterization of the composite mosaic membranes was carried out through permeation experiments using different inorganic salts and dyes. The experimental results showed that the membranes could permeate both mono- and bi-valent inorganic salts, but reject larger organic molecules. Such a mosaic membrane is potentially useful for the separation of salts from water-soluble organics, especially in dye and textile industries.     

有关力学谱和内耗工作的综合与回顾

本文广泛地收集了有关内耗，力学谱，超声衰减方面的专著及会议文集。反映了20世纪在此领域的英文，俄文出版的书籍。也列出了历次国际会议及前苏联，乌克兰，中国的国内会议。文中包括了点缺陷，电，声子，位错，晶界，电畴等诸方面在内的内耗与力学谱工作。     

Theoretical investigations of the processes of laser interaction with ocular tissues for laser applications in ophthalmology

Theoretical investigations and the results of computer modeling of the optical, thermophysical, and thermochemical processes during laser interaction with ocular tissues are reviewed in this paper. Physical-mathematical models and results of numerical simulation of the processes are presented. The computer modeling was applied for investigations of laser heating and coagulation of ocular tissues for treatment of retina diseases and intraocular tumors, cyclophotocoagulation of the ciliary body for treatment of glaucoma, and laser thermal keratoplasty of the cornea. The influence of radiation parameters on the selectivity of laser coagulation of laminated ocular tissues is considered. The results obtained are of essential interest for laser applications in ophthalmology and can be used for investigation of heating and coagulation of tissues in different fields of laser medicine.     

Study of the dielectric properties of water in the frequency range 75–120 GHz

We study experimentally the frequency dependences of the refractive index n and the absorption coefficient k of distilled, sea, and river water. The measurements were performed using a quasioptical device with a backward-wave oscillator as the radiation source and OAP-7 optical-acoustic receivers at a water temperature of 27°C in the cell. The quantities n and k were determined from the measured transmission and reflection coefficients of the cell with water by means of joint numerical solution of the equations for these quantities. For distilled water in the frequency range f = 75–120 GHz, we obtained n = 6.142–3.926 · 10–2f[GHz] + 1.307 · 10–4(f[GHz])² and k = 3.607–2.101 · 10⁻² f[GHz] + 5.252 · 10–5(f[GHz])². On the whole, these data are in good agreement with the measurement results obtained by other authors at several frequencies of the indicated range and coincide with the calculation data based on the models by Meissner and Wentz and by Liebe et al. within the limits of the rms determination errors 0.05 and 0.02 for the parameters n and k, respectively. The values of n and k for different seawater samples and river water containing insoluble admixtures coincide with the values of these quantities for distilled water within the limits of the experimental measurement errors 3–5% and 1–2%, respectively. The dependences n(f) and k(f) obtained experimentally for seawater are compared with those calculated on the basis of the developed models. Measurements of the transmission spectrum of a cell with double distilled water were performed for low power density of radiation (less than μW/cm²) to reproduce the effect of water resonant transparency reported many times in the literature. Our measurements did not reveal any resonant features in the spectral behavior of the refractive index n and the absorption coefficient k of water and gave the same result as for a power density exceeding the threshold of appearance of this effect. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 49, No. 6, pp. 489–501, June 2006.