The nucleon excitation spectrum remains poorly known, with the masses, widths, EM couplings and even existence of many states not well established. A program of experiments using meson photoproduction off the nucleon is being carried out to improve this situation. A new large acceptance recoil polarimeter has been developed by the Edinburgh group for use in such reactions with the Crystal Ball at MAMI. This work summarizes the procedure used to measure recoil polarization with the new device and presents some preliminary results for the double polarization observable Cx in the reaction γp→pπ, compared to the current partial wave analysis. 相似文献
Journal of Thermal Analysis and Calorimetry - In order to be recycled, polymers with different molecular masses, designed to be initially processed by different technologies such as thermoforming,... 相似文献
Kynurenic acid (KYN; systematic name: 4‐hydroxyquinoline‐2‐carboxylic acid, C10H7NO3) displays a therapeutic effect in the treatment of some neurological diseases and is used as a broad‐spectrum neuroprotective agent. However, it is understudied with respect to its solid‐state chemistry and only one crystal form (α‐KYN·H2O) has been reported up to now. Therefore, an attempt to synthesize alternative solid‐state forms of KYN was undertaken and six new species were obtained: five solvates and one salt. One of them is a new polymorph, β‐KYN·H2O, of the already known KYN monohydrate. All crystal species were further studied by single‐crystal and powder X‐ray diffraction, thermal and spectroscopic methods. In addition to the above methods, differential scanning calorimetry (DSC), in‐situ variable‐temperature powder X‐ray diffraction and Raman microscopy were applied to characterize the phase behaviour of the new forms. All the compounds display a zwitterionic form of KYN and two different enol–keto tautomers are observed depending on the crystallization solvent used. 相似文献
Summary: The paper presents evaluation hemolytic and hemostatic activity of gelatin-alginate matrixes in contact with human blood in vitro studies. The percentage of hemolysis and free hemoglobin concentration were normal. The blood recalcyfication time (CT) was shortened and activated partial thromboplastin time (APTT) was prolonged. That sugested that coagulation processes were activated. Discrabed changes were depended an component composition of sponge. 相似文献
A molecular umbrella composed of two O-sulfated cholic acid residues was applied for the construction of conjugates with cispentacin, containing a “trimethyl lock” (TML) or o-dithiobenzylcarbamoyl moiety as a cleavable linker. Three out of five conjugates demonstrated antifungal in vitro activity against C. albicans and C. glabrata but not against C. krusei, with MIC90 values in the 0.22–0.99 mM range and were not hemolytic. Antifungal activity of the most active conjugate 24c, containing the TML–pimelate linker, was comparable to that of intact cispentacin. A structural analogue of 24c, containing the Nap-NH2 fluorescent probe, was accumulated in Candida cells, and TML-containing conjugates were cleaved in cell-free extract of C. albicans cells. These results suggest that a molecular umbrella can be successfully applied as a nanocarrier for the construction of cleavable antifungal conjugates. 相似文献
Summary: A reduced high‐coordination lattice protein model and the Replica Exchange Monte Carlo sampling were employed in de novo folding simulations of a set of representative small proteins. Three distinct situations were analyzed. In the first series of simulations, the folding was controlled purely by the generic force field of the model. In the second, a bias was introduced towards the theoretically predicted secondary structure. Finally, we superimposed soft restraints towards the native‐like local conformation of the backbone. The short‐range restraints used in these simulations are based on approximate values of ϕ and ψ dihedral angles, which may simulate restraints derived from inaccurate experimental measurements. Incorporating such data into the reduced model required developing a procedure, which transforms the ϕ and ψ coordinates into coordinates of the protein alpha carbon trace. It has been shown that such limited data are sufficient for de novo determination of three‐dimensional structures of small and topologically not too complex proteins.
Protein folding based on secondary structure prediction and simulated torsion angles data. 相似文献
We have isolated flexible Sb2O3 nanoribbons and nanorods as the main product from the disintegration of nanoporous oxoselenoantimonates of the cetineite type, the size of the one-dimensional nanomaterials obtained ranging up to 15 microm in length with diameters between 8 and 50 nm. 相似文献
Alpha particles have been measured in coincidence with heavy recoil nuclei from the 28Si + 12C reaction. At Elab = 87 MeV angular correlations for alphas between 15° and 55° and heavy ions at angles ?9°, ?12° and ?15° have been taken. An excitation function of coincidence events with θα = 30° and θHI = ?12° has been measured for 84 MeV < Elab < 91.5 MeV. The results are well described by a statistical-model calculation for compound nucleus decay. No evidence is found for additional processes. 相似文献
L. Kauffman conjectured that a particular solution of the Chinese Rings puzzle is the simplest possible. We prove his conjecture by using low-dimensional topology and group theory. We notice also a surprising connection between the Chinese Rings and Habiro moves (related to Vassiliev invariants).
Differential cross sections for nonresonant radiative capture of low energy protons (Ep = 1,348 keV and 1,370 keV) by23Na nuclei exhibit features pointing to the virtual excitation of the giant dipole resonance (GDR) mode. Theoretical analysis carried out within the framework of the direct — semidirect capture model reveals an enhanced coupling of the GDR with the incident protonf-wave consistent with the microscopic structure of the GDR in thes-d shell nuclei. 相似文献