Redox potentials of gold-palladium powders in aqueous solutions of H2PdCl4

The redox potential of fine-dispersed and compact bimetallic powders of the palladium-gold system in hydrochloric acid solutions of H₂PdCl₄ at a temperature of 60°C was studied. It was found that the redox potential increases with gold enrichment of the solid solution in accordance with the Nernst equation. The effect of gold-palladium particle size on this redox potential is shown. The morphology, sizes, and composition of bimetallic particles are determined via transmission electron microscopy and X-ray diffraction analysis.     

FC-空间中新的连续选择定理及其对广义模糊约束多目标对策的应用

建立了非紧FC-空间中新的连续选择定理,作为应用,获得了非紧FC-空间中广义模糊约束多目标对策的弱Pareto平衡存在定理.我们的结论统一、改进和推广了一些近期文献的已知结果.     

Current filamentation in GaAs/AlGaAs heterojunctions preceding quantum-Hall-effect breakdown

Self-induced filamentation of the current near the edges of a sample in the Hall geometry has been observed in the quantum-Hall-effect regime in a two-dimensional electronic system arising near a GaAs/AlGaAs heterojunction. If in the case of integer values of the filling factor ν averaged over the sample the currents flowing along opposite edges are approximately the same, then away from such a value within the quantum plateau the current is increasingly concentrated near that edge of the sample where the local value of ν is closer to being an integer. When the direction of the magnetic field or of the current changes, the filament switches to the opposite edge of the sample. Pis’ma Zh. éksp. Teor. Fiz. 68, No. 9, 700–704 (10 November 1998)     

Magnetocapacitance study of the fractional-quantum-Hall effect: Quasiparticle charge and spin polarization

By the method of capacitance spectroscopy and of magnetotransport we have investigated the and fractional-quantum-Hall-effect (FQHE) states in gated GaAs AlGaAs heterojunctions with tuned electron areal density. Our experimental results confirm the theoretical prediction of the fractional quasiparticle charge in the FQHE state and of the existence of spin-aligned quasiholes and spin-reversed quasielectrons in the fully spin-polarized FQHE state.     

Spectral effects of intramolecular interaction in the chloranhydrides of unsaturated phosphorus acids

Measurements have been made of the integral Raman line strength of unsaturated phosphorus acids; it is concluded that the phosphorus-bearing group interacts with the-electron system of the aromatic radical in the excited state. It is found that the -PCl₂, -P(O)Cl₂ and -P(S) · Cl₂ will show acceptor behavior in the conjugated system when interacting with donor substituents. The role of the vacant orbitals of the chlorine attached to the phosphorus is discussed.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, No. 11, pp. 25–28, November, 1972.     

The Dependence of the PdCl 4 2− /Pd0 Electrode Potential on the Dispersity of Metallic Palladium

It was found that metastable equilibrium in the heterogeneous reaction

Phytochemical characterisation of Phlomis linearis Boiss. & Bal and screening for anticholinesterase,antiamylase, antimicrobial,and cytotoxic properties

In the present work, essential oil and fatty acids and extracts obtained from aerial parts of Phlomis linearis Boiss. & Bal. were investigated for chemical composition and biological activities. The phytochemical analyses were conducted with gas chromatography-mass spectrometry/flame ionisation detector (GC-MS/FID) and liquid chromatography-mass spectromtetry (LC-MS/MS) techniques. The extracts and essential oil were studied for α-amylase and acetylcholinesterase activities with two different spectrophotometric methods. Antimicrobial activities of the extracts were investigated by microdilution. The extracts were evaluated in vitro for cytotoxic effects against cancer and normal cell lines by MTT assay. The essential oil (EO) contained α-pinene (12.5%) and β-caryophyllene (10.7%) as main compounds. Palmitic (26.5%) and nonadecanoic acids (26.6%) were determined as fatty acids. Phytochemical analysis of the extracts found phenolic acids, phlinosides, verbascoside, and flavonoids. The extracts and essential oil demonstrated poor α-amylase inhibitory activity. The best acetylcholinesterase inhibitory activity was obtained for diethly ether extract of P. linearis (67.2 ± 3.4%) at 10 mg /mL concentration. Ethyl acetate extract found to be effective against Staphlococcus aureus at a minimum inhibitory concentration (MIC) of 156.26 µg/mL. Diethyl ether extract of P. linearis was active on A549 cell lines with an IC₅₀ = 316 ± 4.16 µg/mL when compared with cisplatin IC₅₀ = 24.43 ± 0.14 µg/mL. To the best of our knowledge, the present work is the first comprehensive report on anti-acetylcholinesterase, anti-α-amylase, and antimicrobial activities, as well as cytotoxic effects of P. linearis.     

怀菊花总黄酮的提取工艺及其抗氧化活性

以新鲜怀菊花为原料,用芦丁为对照品,硝酸铝作为显色剂,正交设计优化怀菊花中总黄酮提取条件,采用超声波和水浴提取法等2种工艺提取怀菊花中总黄酮,研究单因素对总黄酮提取率的影响,确定提取总黄酮的最佳条件,同时用碘量法研究对猪油的抗氧化性作用.水浴提取怀菊花总黄酮以A1B1C3组合为最佳提取条件,提取率为109.74mg/g.超声波提取怀菊花总黄酮以A2B2C2组合为最佳提取条件,提取率为114.47mg/g.实验结果表明,超声波法提取效果优于水浴提取法,怀菊花黄酮对猪油有一定的抗氧化能力.     

苦瓜果实中盐酸小檗碱的提取工艺

以新鲜苦瓜为原料,用盐酸小檗碱为对照品,正交设计优化苦瓜中盐酸小檗碱提取条件,采用超声波和水浴提取法等2种工艺提取苦瓜中盐酸小檗碱,研究单因素对盐酸小檗碱提取率的影响,确定提取盐酸小檗碱的最佳条件.水浴提取苦瓜盐酸小檗碱以A2C1B1组合为最佳提取条件,提取率为5.1642mg/g.超声波提取苦瓜盐酸小檗碱以A3B2C2组合为最佳提取条件,提取率为6.3267mg/g.实验结果表明,超声波法提取效果优于水浴提取法.     

Investigation of physico-chemical properties and structural parameters of diene-vinyl aromatic thermoplastic elastomers as a polymeric base of adhesive compositions

Adhesion and mechanical properties of vinyl aromatic thermoplastic elastomers on the Russian market were studied. Significant differences between the materials were shown that are due to differences in the chemical natures and structural parameters of block copolymers.