Dependence of an equilibrium state of a two-phase medium on surface tension coefficient and on temperature

An existence theorem for the variational problem for the two-phase medium energy functional is proved. Dependence of the solution on the surface tension coefficient and on the temperature is investigated. Bibliography: 7 titles. Dedicated to V. A. Solonnikov on his sixtieth anniversary Translated fromZapiski Nauchnykh Seminarov POMI, Vol. 213, 1994, pp. 131–150. Translated by S. Yu. Pilyugin.     

Using completely implicit methods to solve the direct problem of nozzle theory

An iterative method from the class of completely implicit methods (CIM) is proposed for solving the equation of the velocity potential of elliptical-hyperbolic type. The advantage of the proposed method compared to other CIM schemes is demonstrated in application to mixed perfect gas flows in a nozzle of a given shape. Accuracy issues, rate of convergence, and various techniques of ensuring stability in the hyperbolic region are discussed. Translated from Chislennye Metody v Matematicheskoi Fizike, Published by Moscow University, Moscow, 1996, pp. 39–51.     

Effective potentials and Bogoliubov’s quasi-averages

The effective potential method, used in quantum field theory to study spontaneous symmetry violation, is discussed from the point of view of Bogoliubov’s quasi-averaging procedure. It is shown that the effective potential method is a disguised type of this procedure. The catastrophe theory approach to the study of phase transitions is discussed and the existence of the potentials used in that approach is proved from the statistical point of view. It is shown that in the case of broken symmetry, the nonconvex effective potential is not a Legendre transform of the generating functional for connected Green’s functions. Instead, it is a part of the potential used in catastrophe theory. The relationship between the effective potential and the Legendre transform of the generating functional for connected Green’s functions is given by Maxwell’s rule. A rigorous rule for evaluating quasi-averaged quantities within the framework of the effective potential method is established. Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 113, No. 1, pp. 149–161, October, 1997.     

New derivatives of coumarin: 2-(N-R-imino)-2H-1-benzopyrans

Methods of synthesizing previously unknown derivatives of coumarin — 2-(N-R-imino)-2H-1-benzopyrans, where R = Alk, Ar — are proposed. Possibilities of alternative synthetic schemes are discussed, and hypotheses concerning probable mechanisms of the reactions are formulated.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 760–766, June, 1994. Original article submitted May 23, 1994.     

Thermal activation of complexation reaction on aerosil surface

The influence of temperature in the 20–100°C range on processes of bimolecular interaction in the aerosil-phenanthrene-trinitrobenzene system has been studied. Temperature-stimulated CTC accumulation on the surface is found. Activation energies of complex formation are estimated. Quenching of phenanthrene fluorescence by acceptor has a mixed static and dynamic character.     

Reactivity of sites on Al2O3 surface modified by Ni

It has been established that CO oxidation with excess O₂ on Ni/Al₂O₃ forms an inhomogeneous NiO contact surface that smoothes critical effects in the sharp reactivity change.     

A branching process model for sand avalanches

An analytically solvable model for sand avalanches of noninteracting grains of sand, based on the Chapman-Kolmogorov equations, is presented. For a single avalanche, distributions of lifetimes, sizes of overflows and avalanches, and correlation functions are calculated. Some of these are exponentials, some are power laws. Spatially homogeneous distributions of avalanches are also studied. Computer simulations of avalanches of interacting grains of sand are compared to the solutions to the Chapman-Kolmogorov equations. We find that within the range of parameters explored in the simulation, the approximation of noninteracting grains of sand is a good one.     

XPS and XAES study of the interaction of palladium and copper overlayers with fullerene films

X-ray photoelectron and Auger spectroscopies were used to examine surface bonding and overlayer growth during palladium and copper deposition onto films of fullerene, C₆₀ The results were consistent with metal cluster formation on C₆₀. The observed positive core electron binding energy shifts in small metallic clusters supported on C₆₀ were shown to originate in metal-fullerene interaction accompanied by charge transfer. Palladium-fullerene intermixing at temperatures as low as ss 50°C was observed for small Pd coverages.