全文获取类型
收费全文 | 6581篇 |
免费 | 1074篇 |
国内免费 | 657篇 |
专业分类
化学 | 4863篇 |
晶体学 | 56篇 |
力学 | 319篇 |
综合类 | 15篇 |
数学 | 714篇 |
物理学 | 2345篇 |
出版年
2024年 | 23篇 |
2023年 | 175篇 |
2022年 | 280篇 |
2021年 | 267篇 |
2020年 | 309篇 |
2019年 | 291篇 |
2018年 | 239篇 |
2017年 | 234篇 |
2016年 | 362篇 |
2015年 | 343篇 |
2014年 | 391篇 |
2013年 | 474篇 |
2012年 | 608篇 |
2011年 | 637篇 |
2010年 | 407篇 |
2009年 | 408篇 |
2008年 | 399篇 |
2007年 | 378篇 |
2006年 | 307篇 |
2005年 | 281篇 |
2004年 | 192篇 |
2003年 | 179篇 |
2002年 | 153篇 |
2001年 | 109篇 |
2000年 | 95篇 |
1999年 | 113篇 |
1998年 | 94篇 |
1997年 | 89篇 |
1996年 | 83篇 |
1995年 | 68篇 |
1994年 | 59篇 |
1993年 | 47篇 |
1992年 | 58篇 |
1991年 | 38篇 |
1990年 | 27篇 |
1989年 | 28篇 |
1988年 | 18篇 |
1987年 | 12篇 |
1986年 | 8篇 |
1985年 | 11篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有8312条查询结果,搜索用时 15 毫秒
221.
Zhu Kai Li Cui Wu Kingsley Y. Mohr Christopher Li Xun Lanman Brian 《Journal of computer-aided molecular design》2022,36(8):591-604
Journal of Computer-Aided Molecular Design - KRAS has long been referred to as an ‘undruggable’ target due to its high affinity for its cognate ligands (GDP and GTP) and its lack of... 相似文献
222.
Cui‐Wei Wang Chao Liu Xiao‐Wei Zhu Zi‐Ying Yang Hong‐Fan Sun De‐Ling Kong Jing Yang 《Journal of polymer science. Part A, Polymer chemistry》2016,54(3):407-417
Well‐defined star‐shaped hydrophobic poly(ε‐caprolactone) (PCL) and hydrophilic poly(ethylene glycol) (PEG) amphiphilic conetworks (APCNs) have been synthesized via the combination of ring opening polymerization (ROP) and click chemistry. Alkyne‐terminated six arm star‐shaped PCL (6‐s‐PCLx‐C?CH) and azido‐terminated PEG (N3‐PEG‐N3) are characterized by 1H NMR and FT‐IR. The swelling degree of the APCNs is determined both in water and organic solvent. This unique property of the conetworks is dependent on the nanophase separation of hydrophilic and hydrophobic phases. The morphology and thermal behaviors of the APCNs are investigated by SEM and DSC respectively. The biocompatibility is determined by water soluble tetrazolium salt reagents (WST‐1) assay, which shows the new polymer networks had good biocompatibility. Through in vitro release of paclitaxel (PTX) and doxorubicin (DOX), the APCNs is confirmed to be promising drug depot materials for sustained hydrophobic and hydrophilic drugs. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 407–417 相似文献
223.
224.
225.
226.
Cobalt‐based metal coordination polymers with 4,4′‐bipyridinyl groups: highly efficient catalysis for one‐pot synthesis of 3,4‐dihydropyrimidin‐2(1H)‐ones under solvent‐free conditions
下载免费PDF全文
![点击此处可从《应用有机金属化学》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Jin‐Hua Wang Gui‐Mei Tang Shi‐Chen Yan Yong‐Tao Wang Shi‐Jie Zhan E Zhang Yu Sun Yuan Jiang Yue‐Zhi Cui 《应用有机金属化学》2016,30(12):1009-1021
Three new metal coordination complexes, namely [Co(BPY)2(H2O)2](BPY)(BS)2(H2O)4 ( 1 ), [Co(BPY)2(H2O)4](ABS)2(H2O)2 ( 2 ) and [Co(BPY)(H2O)4](MBS)2 ( 3 ) (BPY = 4,4′‐bipyridine, BS = phenylsulfonic acid, ABS = p‐aminobenzenesulfonic acid, MBS = p‐methylbenzenesulfonic acid), were obtained under hydrothermal conditions. Complexes 1 , 2 , 3 were structurally characterized using single‐crystal X‐ray diffraction and infrared spectroscopy. All of them display low‐dimensional motifs: complex 1 displays a two‐dimensional structure; and complexes 2 and 3 exhibit a one‐dimensional tape structure. Through strong intermolecular hydrogen bonding interactions and weak packing interactions, all of them further stack to generate a three‐dimensional supramolecular architecture. Catalysts 1 , 2 , 3 were involved in the green synthesis of a variety of 3,4‐dihydropyrimidin‐2(1H)‐ones under solvent‐free conditions through Biginelli reactions. The corresponding catalytic product was obtained in quantitative yields (99%) under eco‐friendly synthesis conditions for the variety of reactions. Catalysts 1 , 2 , 3 exhibit excellent efficiency for the desired product, and their catalytic performance shows the following order: 2 > 1 ≈ 3 , which can be ascribed to the hydrophobic interactions of different phenylsulfonate groups. The catalytic performance for the Biginelli reaction is not only dependent on the selected solvents, but also inversely proportional to the polarities of the solvents. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
227.
Vegetables and fruits are necessary for human health, and traditional Chinese medicine that uses plant materials can cure diseases. Thus, understanding the composition of plant matrix has gained increased attention in recent years. Since plant matrix is very complex, the extraction, separation and quantitation of these chemicals are challenging. 相似文献
228.
Polyphenol microspheres were prepared by template polymerization of phenol in the presence of horseradish peroxidase as bio‐enzyme catalyst and aqueous 1,4‐dioxane as solvent. The morphology of polyphenol microspheres thus obtained was observed with a scanning electron microscope. Further, polyphenol microspheres as obtained were loaded with palladium to generate polyphenol microsphere‐supported Pd complex. Resultant Pd complex catalyst supported by polyphenol microspheres was characterized by means of Fourier transformation infrared spectrometry, X‐ray diffraction, X‐ray photoelectron spectroscopy and scanning electron microscopy, and its thermal stability was examined. Moreover, the catalytic activity of polyphenol microsphere‐supported Pd catalyst as synthesized for the Heck reactions of acrylic acid with aryl iodides was evaluated. Results indicate that the polyphenol microsphere as obtained has a diameter of about 500 nm. Polyphenol microsphere‐supported Pd catalyst, as synthesized, at a dosage of 0.37 mol% Pd, possesses good catalytic activity for the Heck reactions of acrylic acid with aryl iodides in air at a low temperature of 50°C, and it also exhibits catalytic activity for bromide and activated chlorobenzene. The polyphenol microsphere‐supported Pd complex has good thermal stability, and it can be readily separated and reused; the yield of the reaction of iodobenzene with acrylic acid remains at 82% after five recycle runs, showing promising potential as a catalyst for Heck reactions. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
229.
Acta Mathematicae Applicatae Sinica, English Series - This paper introduces two local conditional dependence matrices based on Spearman’s ρ and Kendall’s τ given the condition... 相似文献
230.
Nanosized Ni particles with an average diameter of about 8 nm were prepared by reducing of NiCl 2 with sodium borohydride (NaBH 4 ) in aqueous solution. By moderate annealing in protective atmosphere, the composite grew up to be 15-20 nm particles. Both of the as-prepared and annealed Ni particles were coated by a layer of manganese oxide via decomposition reaction in aqueous KMnO4 solution. Hysteresis loops of as-prepared samples show a large increase in the magnetization with decreasing temperature and an unsaturated component at high magnetic field. In contrast, the ferromagnetic characteristics of annealed one are much stronger with large magnetization and coercivity. The thermomagnetic curves verified the coexistence of ferromagnetic Ni and antiferromangetic Mn oxide phases. But there exists no exchange bias behavior in the samples, even though the interface structure between the ferromagnetic Ni core and the antiferromagnetic manganese oxides has been distinctly formed. The absence of exchange bias probably originates from the weak ferromagnetic characteristic of Ni cores. 相似文献