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101.
Half-lives of proton radioactivity are investigated with a deformed density-dependent model. The single folding potential which is dependent on deformation and orientation is employed to calculate the proton decay width through the deformed potential barrier. In addition, the spectroscopic factor is taken into account in the calculation, which is obtained in the relativistic mean field theory with NL3. The calculated results of semi-spherical nuclei are found to be in good agreement with the experimental data, and the results of well-deformed nuclei are also satisfactory. Moreover, a formula for the spherical proton emission half-life based on the Gamow quantum tunneling theory is presented. 相似文献
102.
Rotational and Vibrational State Distributions of CsH and Relative Reactivity in Reactions of Cs(6^2D,7^2D) with H2 下载免费PDF全文
By using a pump-probe technique, the nascent rotational and vibrational state distributions of CsH are obtained in the Cs(6^2 D,7^2 D) plus H2 reaction. The nascent CsH molecules are found to populate the lowest two vibrational (v″ = 0 and 1) levels of the ground electronic state. By comparing the spectral intensities of the CsH action spectra with those of pertinent Cs atomic fluorescence excitation spectra, the relative reactivity with 1-12 is in an order of6^2D3/2 〉 6^2D5/2 〉 7^2D3/2 〉 7^2D5/2. The rotational temperatures are found to be slightly below the cell temperature. The relative fractions (〈fV〉, 〈fR〉, 〈fT〉) of average energy disposal are derived as (0.2,0.12,0.68), (0.2,0.12,0.68), (0.07,0.04,0.89) and (0.07,0.04,0.89) for the 6^2D3/2, 6^2D5/2, 7^2D3/2 and 7^2D5/2, respectively. The major available energy is released as translation. These results support that the reaction mechanism of Cs(6^2 D,7^2 D) plus 112 is primarily a eollinear abstraction and not an insertion. 相似文献
103.
Polymer-supported 4-aminoformoyldiphenylammonium triflate (PS-AFDPAT) was used as an effective catalyst for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones (DHPMs) via the Biginelli reaction. This immobilized catalyst could be easily recovered by simple filtration and recycled for 10 runs without significant decrease of the catalytic activity. 相似文献
104.
纳米复合材料中的微观界面结构和界面作用对材料的宏观介电性能, 如介电常数、介电损耗、击穿强度等有十分重要的影响. 本文发展了一种基于扫描静电显微探针技术的测量方法, 可以直接表征二氧化钛/环氧树脂纳米复合材料的微观界面结构及相应的动态介电响应行为. 实验中利用扫描探针的纳米尺度分辨能力, 探测到不同温度下环氧树脂纳米复合材料的局域动态介电响应变化过程, 从而获得纳米颗粒与高分子界面相互作用及极化相关的温度特性. 进一步通过对二氧化钛纳米颗粒进行表面修饰, 得到了两种不同特性的二氧化钛/环氧树脂界面, 验证了不同界面作用引起的复合材料界面区域与非界面区域高分子链介电损耗图像的反差. 相似文献
105.
A new aromatic dicarboxylic acid, 9,9-bis[4-(4-carboxyphenoxy)-3-methylphenyl]xanthene (BCAMPX) was prepared from the nucleophilic substitution reaction of 9,9-bis(4-hydroxy-3-methylphenyl)xanthene with p-fluorobenzonitrile, followed by alkaline hydrolysis. Then BCAMPX was polycondensated with various aromatic diamines to afford the polyamides with the number-average molecular weight in the range of 45,300–51,500 and the polydispersity index ranged from 1.67 to 1.85. These polyamides showed glass transition temperatures between 260–286°C and 10% weight loss temperatures ranging from 490 to 504°C and 480 to 490°C in nitrogen and air respectively, and char yields above 52% at 800°C in nitrogen. Nearly all polyamides were readily soluble polar aprotic solvents such as N-methyl-2-pyrrolidone, N,N-dimethylacetamide (DMAc), tetrahydrofuran and pyridine, and afforded transparent, strong and flexible films upon casting from DMAc solvent. All polyamides were amorphous and exhibited tensile strengths of 80–91 MPa, elongations at break of 9–13%, and initial moduli of 1.95–2.82 GPa, as well as low moisture absorption in the range of 2.65–3.65%, and high transparency with an ultraviolet–visible absorption cut-off wavelength in the 360–378 nm range. 相似文献
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设计了一种基于双芯负曲率光纤的新型低损耗大带宽太赫兹偏振分束器,该器件以环烯烃共聚物为基底,沿圆周等间距分布着12个含内嵌管的圆形管,通过上下对称的两组外切小包层管将纤芯分成双芯.采用时域有限差分法对其导模特性进行分析,详细研究了各个参数对其偏振分束特性的影响,分析了该偏振分束器的消光比、带宽、传输损耗等性能.仿真结果表明:当入射光频率为1 THz,分束器长度为6.224 cm时, x偏振光的消光比达到120.8 d B,带宽为0.024 THz, y偏振光的消光比达到63.74 d B,带宽为0.02 THz,传输总损耗低至0.037 d B/cm.公差分析表明结构参数在±1%的偏差下,偏振分束器仍然可以保持较好的性能. 相似文献