全文获取类型
收费全文 | 29942篇 |
免费 | 4660篇 |
国内免费 | 3129篇 |
专业分类
化学 | 21893篇 |
晶体学 | 360篇 |
力学 | 1601篇 |
综合类 | 157篇 |
数学 | 3152篇 |
物理学 | 10568篇 |
出版年
2024年 | 101篇 |
2023年 | 580篇 |
2022年 | 1049篇 |
2021年 | 1115篇 |
2020年 | 1282篇 |
2019年 | 1188篇 |
2018年 | 1073篇 |
2017年 | 905篇 |
2016年 | 1443篇 |
2015年 | 1431篇 |
2014年 | 1594篇 |
2013年 | 2299篇 |
2012年 | 2617篇 |
2011年 | 2589篇 |
2010年 | 1751篇 |
2009年 | 1736篇 |
2008年 | 1991篇 |
2007年 | 1767篇 |
2006年 | 1583篇 |
2005年 | 1450篇 |
2004年 | 1103篇 |
2003年 | 940篇 |
2002年 | 967篇 |
2001年 | 704篇 |
2000年 | 570篇 |
1999年 | 586篇 |
1998年 | 438篇 |
1997年 | 374篇 |
1996年 | 392篇 |
1995年 | 326篇 |
1994年 | 280篇 |
1993年 | 229篇 |
1992年 | 207篇 |
1991年 | 186篇 |
1990年 | 157篇 |
1989年 | 124篇 |
1988年 | 101篇 |
1987年 | 79篇 |
1986年 | 74篇 |
1985年 | 73篇 |
1984年 | 57篇 |
1983年 | 34篇 |
1982年 | 29篇 |
1981年 | 34篇 |
1980年 | 19篇 |
1979年 | 10篇 |
1976年 | 10篇 |
1975年 | 13篇 |
1973年 | 7篇 |
1971年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
The solubility and diffusion coefficient of carbon dioxide in intermediate‐moisture starch–water mixtures were determined both experimentally and theoretically at elevated pressures up to 16 MPa at 50 °C. A high‐pressure decay sorption system was assembled to measure the equilibrium CO2 mass uptake by the starch–water system. The experimentally measured solubilities accounted for the estimated swollen volume by Sanchez–Lacombe equation of state (S‐L EOS) were found to increase almost linearly with pressure, yielding 4.0 g CO2/g starch–water system at 16 MPa. Moreover, CO2 solubilities above 5 MPa displayed a solubility increase, which was not contributed by the water fraction in the starch–water mixture. The solubilities, however, showed no dependence on the degree of gelatinization (DG) of starch. The diffusion coefficient of CO2 was found to increase with concentration of dissolved CO2, which is pressure‐dependent, and decrease with increasing DG in the range of 50–100%. A free‐volume‐based diffusion model proposed by Areerat was employed to predict the CO2 diffusivity in terms of pressure, temperature, and the concentration of dissolved CO2. S‐L EOS was once more used to determine the specific free volume of the mixture system. The predicted diffusion coefficients showed to correlate well with the measured values for all starch–water mixtures. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 607–621, 2006 相似文献
92.
Xiaoqing Liu Chuncheng Li Dong Zhang Yaonan Xiao 《Journal of Polymer Science.Polymer Physics》2006,44(6):900-913
This article investigated the melting behaviors, crystallization kinetics, and spherulitic morphologies of poly(butylene succinate) (PBS) and its copolyester (PBSR) modified with rosin maleopimaric acid anhydride, using wide‐angle X‐ray diffraction, differential scanning calorimeter (DSC), and polarized optical microscope. Subsequent DSC scans of isothermally crystallized PBS and PBSR exhibited two melting endotherms, respectively, which was due to the melt‐recrystallization process occurring during the DSC scans. The equilibrium melting point of PBSR (125.9 °C) was lower than that of PBS (139 °C). The commonly used Avrami equation was used to describe the isothermal crystallization kinetics. For nonisothermal crystallization studies, the model combining Avrami equation and Ozawa equation was employed. The result showed a consistent trend in the crystallization process. The crystallization rate was decreased, the perfection of crystals was decreased, the recrystallization was reduced, and the spherulitic morphologies were changed when the huge hydrogenated phenanthrene ring was added into the chain of PBS. The activation energy (ΔE) for the isothermal crystallization process determined by Arrhenius method was 255.9 kJ/mol for PBS and 345.7 kJ/mol for PBSR. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 900–913, 2006 相似文献
93.
J.-S. Kang G. Kim S.S. Lee S. Choi S. Cho S.W. Han H.J. Shin B.I. Min 《Journal of magnetism and magnetic materials》2006
The spatial concentration distribution and local electronic structure of ferromagnetic Ge1−xTx (T=Cr, Mn, Fe) DMS single crystals have been investigated by using scanning photoelectron microscopy (SPEM), X-ray absorption spectroscopy (XAS), and photoemission spectroscopy (PES). It is found that doped T ions in Ge1−xTx crystals are chemically phase-separated, suggesting that the observed ferromagnetism arises from the phase-separated T-rich phases in Ge1−xTx. 相似文献
94.
A. Subramanian T.-Y. Choi L.X. Dong J. Tharian U. Sennhauser D. Poulikakos B.J. Nelson 《Applied Physics A: Materials Science & Processing》2007,89(1):133-139
We report on a novel method for local control of shell engineering in multiwalled carbon nanotubes (MWNTs) using Joule-heating
induced electric breakdown. By modulating the heat dissipation along a nanotube, we can confine its thinning and shell breakdown
to occur within localized regions of peak temperatures, which are distributed over one-half of the NT length. The modulation
is achieved by using suitably designed nanomachined heat sinks with different degrees of thermal coupling at different parts
of a current-carrying nanotube. The location of electric breakdown occurs precisely at the regions of high temperatures predicted
by the classical finite-element model of Joule heating in the MWNT. The experiments herein provide new insight into the electric
breakdown mechanism and prove unambiguously that shell removal occurs due to thermal stress, underpinning the diffusive nature
of MWNTs. The method demonstrated here has the potential to be a powerful tool in realizing MWNT bearings with complex architectures
for use in integrated nanoelectromechanical systems (NEMS). In addition, the breakdown current and power in the nanotubes
are significantly higher than those observed in nanotubes without heat removal via additional heat sinks. This indicates future
avenues for enhancing the performance of MWNTs in electrical interconnect and nanoelectronic applications.
PACS 73.63.Fg; 65.80.+n 相似文献
95.
In this paper we prove the semialgebraic version of Palais' covering homotopy theorem, and use this to prove Bredon's covering mapping cylinder conjecture positively in the semialgebraic category. Bredon's conjecture was originally stated in the topological category, and a topological version of our semialgebraic proof of the conjecture answers the original topological conjecture for topological G-spaces over “simplicial” mapping cylinders. 相似文献
96.
EucalyPtusgl0bulusLabill.(Myrtaceae)isakindofmedicinalplantwidelydistributedintheYunnanpr0vinceofChina.ItSleaves,rootSandffoitShavebeenusedastraditionalremediesforthetreatmentofinfluenza,dysentery,enteritis,rheumatalgiaandbleeding.BesidesvolatileterpenoidconstituentSintheessential0iloftheleavesandfruits,theoccurrenceofanumber0fphloroglucinol-sesquiterpene-or-m0n0terpene-c0upledcomPoundsnamedmacrocarpals'andeugl0bals'intheleavesandbudshasbeenrepofted.Inordertostudythechendcalandbioactivecon… 相似文献
97.
98.
本文报导共价链相连的X-P-Y“三合板”型化合物在二甲基甲酰胺(DMF)和苯溶液中的发光特性.结果发现:引入取代基X=Cl—,CH3O—和Y=苯、硝基苯对中心卟啉的吸收和荧光光谱均无明显影响,仅其峰值频率将因溶剂不同而有所偏移.此外,由Cl—取代的卟啉—苯的荧光强度总比CH3O—取代时高;若将Y取代基由苯改换为硝基苯时,将使CH3O—P—Y化合物的荧光增强,但在Cl—P—Y化合物中则出现相反的趋势.不论在何种化合物中,在Y取代基中的苯环上引入NO2—基后,均可使其消光系数减小,而且当硝基在邻位取代时,这一效应更为显著.所有这些变化规律均不因溶剂不同而异.如果我们认为X—P—Y化合物的发光强度变化和其中心的卟啉大环上的π电子云密度偏移有规律性的关联,那么上述的一些取代基效应是可以理解的.进而,我们认为:本文所报导的事实将有助于充实巧妙设计高效利用太阳能的分子体系的科学依据. 相似文献
99.
100.
K. -H. Speidel M. Knopp W. Karle U. Kilgus M. -L. Dong H. -J. Simonis F. Hagelberg J. Gerber 《Zeitschrift für Physik A Hadrons and Nuclei》1988,331(1):29-36
Transient field precessions have been measured with the first excited 2 1 + -state as probe for ions of28Si traversing Fe at vion?1v0 and 13v0(v0=c/137) and62Ni being stopped in Fe. The degree of polarization deduced for the Si ions, p1s=0.19(6), is consistent with low-velocity data. There is clear evidence that the field strength is attenuated by heavy ion beams. For the62Ni(2 1 + ) state at 1.173 MeV a g-factor value of g=0.34(7) was obtained in good agreement with a previous result. 相似文献