全文获取类型
收费全文 | 3861篇 |
免费 | 55篇 |
国内免费 | 27篇 |
专业分类
化学 | 2614篇 |
晶体学 | 59篇 |
力学 | 116篇 |
数学 | 738篇 |
物理学 | 416篇 |
出版年
2020年 | 28篇 |
2016年 | 42篇 |
2015年 | 36篇 |
2014年 | 43篇 |
2013年 | 202篇 |
2012年 | 128篇 |
2011年 | 139篇 |
2010年 | 82篇 |
2009年 | 74篇 |
2008年 | 146篇 |
2007年 | 150篇 |
2006年 | 176篇 |
2005年 | 164篇 |
2004年 | 132篇 |
2003年 | 144篇 |
2002年 | 110篇 |
2001年 | 52篇 |
2000年 | 55篇 |
1999年 | 41篇 |
1998年 | 30篇 |
1997年 | 56篇 |
1996年 | 67篇 |
1995年 | 61篇 |
1994年 | 63篇 |
1993年 | 68篇 |
1992年 | 46篇 |
1991年 | 67篇 |
1990年 | 52篇 |
1989年 | 51篇 |
1988年 | 46篇 |
1987年 | 39篇 |
1986年 | 44篇 |
1985年 | 73篇 |
1984年 | 78篇 |
1983年 | 50篇 |
1982年 | 80篇 |
1981年 | 74篇 |
1980年 | 65篇 |
1979年 | 78篇 |
1978年 | 70篇 |
1977年 | 73篇 |
1976年 | 60篇 |
1975年 | 56篇 |
1974年 | 67篇 |
1973年 | 81篇 |
1972年 | 41篇 |
1971年 | 41篇 |
1970年 | 36篇 |
1969年 | 28篇 |
1968年 | 32篇 |
排序方式: 共有3943条查询结果,搜索用时 31 毫秒
101.
Thompson TS Noot DK Calvert J Pernal SF 《Rapid communications in mass spectrometry : RCM》2005,19(3):309-316
A simple and rapid analytical method was developed for the determination of lincomycin and tylosin residues in honey as part of field studies examining the efficacy and target animal safety of these antibiotics to control American foulbrood disease in honey bees. Residues of the antibiotics were determined using liquid chromatography/electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS). Honey samples were diluted and injected directly into the LC/MS/MS system without additional cleanup by solid-phase extraction or liquid-liquid partitioning. A six-port valve system was utilized to selectively route eluant from the LC column into the mass spectrometer only during a relatively short portion of the chromatographic run corresponding to the elution of the analytes of interest. Minimal contamination of the MS source chamber was observed despite the analysis of large numbers of samples. Using internal standard quantitation, excellent accuracy and precision were obtained with no apparent matrix-to-matrix variation. Based on the analysis of fortified replicates, the mean percent deviation from the theoretical concentration and the percent relative standard deviation were both less than 10% for tylosin over an analytical range of 10-1000 microg/kg. Slightly higher mean percent deviations and relative standard deviations were observed for the analysis of lincomycin in fortified replicate samples. The method detection limits were determined to be 5 and 2 microg/kg for lincomycin and tylosin, respectively. 相似文献
102.
103.
The concept of an EP matrix is extended to a morphism of a category C with involution. It is shown that an EP morphism has a group inverse iff it has a Moore-Penrose inverse, and in this case the inverses are identical. On the other hand, if a morphism has a Moore-Penrose inverse that is a group inverse, then C is a full subcategory of a category in which φ is EP. Also, if C is an additive category with involution 1 and with 1-biproduct factorization, then a morphism of φ of C is EP iff there is a 1-biproduct J ⊕ K and an invertible morphism θ : J → J such that φ is congruent to a morphism of the form In particular, a square matrix over a principal-ideal domain with involution is EP iff it is congruent to a matrix of the form dg(θ, 0) with θ invertible. 相似文献
104.
105.
The prominence of multiply charged molecular and fragment ions upon electron-impact in the mass spectrometer is proposed as an experimental, empirical indication of aromatic character. The effects of electron withdrawing and donating substituents on the production of multiply charged ions are considered and appearance potentials are noted for several species. 相似文献
106.
Edward E. Flagg Donald L. Schmidt 《Journal of polymer science. Part A, Polymer chemistry》1970,8(1):1-14
Poly[tris(diorganophosphinato)alanes], [Al(OPRR′O)3]n, were synthesized in which the organic moieties (R,R′) contained from one to eighteen carbon atoms. Polymeric properties depended upon the organic moieties; polymers were fusible, tractable, and flexible when the organic moieties contained six or more carbon atoms. Soluble polymers were prepared by using mixtures of symmetrical and unsymmetrical phosphinates. One polymer, poly{bis[n-butyl(benzyl)phosphinato]di-n-octylphosphinatoalane}, exhibited a degree of polymerization greater than 1000 and an exceptionally high intrinsic viscosity of 37 dl/g. The properties of the different polymers are discussed, and feasible structures are proposed. 相似文献
107.
108.
Funyu S Isobe T Takagi S Tryk DA Inoue H 《Journal of the American Chemical Society》2003,125(19):5734-5740
Visible light irradiation of a reaction mixture of carbonyl-coordinated tetra(2,4,6-trimethyl)phenylporphyrinatoruthenium(II) (Ru(II)TMP(CO)) as a photosensitizer, hexachloroplatinate(IV) as an electron acceptor, and an alkene in alkaline aqueous acetonitrile induces selective epoxidation of the alkene with high quantum yield (Phi = 0.6, selectivity = 94.4% for cyclohexene and Phi = 0.4, selectivity = 99.7% for norbornene) under degassed conditions. The oxygen atom of the epoxide was confirmed to come from a water molecule by an experiment with H(2)(18)O. cis-Stilbene was converted into its epoxide, cis-stilbeneoxide, without forming trans-stilbeneoxide. trans-Stilbene, however, did not exhibit any reactivity. Under neutral conditions, an efficient buildup of the cation radical of Ru(II)TMP(CO) was observed at the early stage of the photoreaction, while an addition of hydroxide ion caused a rapid reaction with the cation radical to promote the reaction with reversion to the starting Ru(II)TMP(CO). A possible involvement of a higher oxidized state of Ru such as Ru(IV), Ru(V), Ru(VI) through a dismutation of the Ru(III) species was excluded by an experiment with Ru(VI)TMP(O)(2). Decarbonylation of the Ru complex was also proven to be invalid. A reaction mechanism involving an electron transfer from the excited triplet state of Ru(II)TMP(CO) to hexachloroplatinate(IV) and subsequent formation of OH(-)-coordinated Ru(III) species, leading to an oxo-ruthenium complex as the key intermediate of the photochemical epoxidation, was postulated. 相似文献
109.
Our recently proposed scheme for including aqueous solvation free energies in parameterized NDDO SCF models is extended to the Parameterized Model 3 semiempirical Hamiltonian. The solvation model takes accurate account of the hydrophobic effect for hydrocarbons, as well as electric polarization of the solvent, the free energy of cavitation, and dispersion interactions. Eight heteroatoms are included (along with H and C), and the new model is parameterized accurately for the water molecule itself, which allows meaningful treatments of specifically hydrogen bonded water molecules. The unphysical partial charges on nitrogen atoms predicted by the Parameterized Model 3 Hamiltonian limit the accuracy of the predicted solvation energies for some compounds containing nitrogen, but the model may be very useful for other systems, especially those for which PM3 is preferred over AM1 for the solute properties of the particular system under study. © 1992 by John Wiley & Sons, Inc. 相似文献