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121.
1. INTRODUCTION Streptococcus pneumoniae remains an important cause of infections in this end of the 20th century and is responsible for invasive diseases - pneumonia, meningitis, bacteremia, septicemia - as well as for noninvasive diseases such as pharyngitis, conjunctivitis, otitis media.1,2 相似文献
122.
Sarah Djabarouti Pierre Duffau Fabien Xuereb Estibaliz Lazaro Carine Greib Jean-Baptiste Gordien Olivier Caubet Marie-Claude Saux Jean-François Viallard Jean-Luc Pellegrin Dominique Breilh 《Chromatographia》2009,70(5-6):939-945
Liquid chromatography coupled with mass spectrometry for the determination of total and unbound mycophenolic acid and its major metabolite in human plasma has been developed. Sample preparations were based on a fully automated solid-phase extraction process and ultrafiltration. Mass spectrometric data were acquired in a single-ion monitoring method. The analytes and nevirapine (internal standard) were well separated in an isocratic mode over 8 min. Validation study exhibited excellent linearity, with intra- and inter-day precision and accuracy of less than 12%. The assay was successfully applied to the pharmacokinetic study of mycophenolic acid in patients with autoimmune diseases. 相似文献
123.
The Cr 2p and O 1s binding energy (BE) levels have been calculated by first principles methods for different models of hydroxylated (0001)-Cr2O3 surfaces. Several surface terminations have been considered. The calculations allow us to reproduce the O 1s shifts between O in oxide and OH groups. It is found that two main effects account for the OH binding energy shifts. On the one hand, the increased covalency of the O–H bond with respect to the Cr–O bond, lowers the electronic O (1s and 2p) energy, and in consequence the BE of the core levels (O 1s) are higher. On the other hand, the lower the OH coordination number, the higher the valence and core levels energy, and the lower the BE. Consequently, mono-coordinated hydroxyls have a binding energy near that of O2? in the oxide (ΔBEOH–O = ? 0.2–0.0 eV). Two-fold coordinated hydroxyls have a slightly higher BE (ΔBEOH–O = + 0.3 eV). Three-fold coordinated OH groups have a higher binding energy (ΔBEOH–O = + 0.6?0.7 eV), corresponding to that experimentally measured for OH groups. Finally, water adsorbed above OH groups exhibits a still higher BE (ΔBEHOH–O = + 0.9–1.0 eV). The ΔBE are slightly under-estimated under the initial state approximation, and overestimated under the final state (Z + 1) approximation. 相似文献
124.
Dominique Petit Jean-Pierre Korb Pierre Levitz Jean LeBideau David Brevet 《Comptes Rendus Chimie》2010,13(4):409-411
We present the first results of the nuclear magnetic relaxation dispersion (NMRD) of the confined proton-bearing cation (BMI) and fluorine-bearing anion (TFSI) pair of ionic liquids (Li+-ionogels) confined within a silica-like mesoporous matrices designed for lithium batteries. These results are in favour of a very-correlated dynamical motion of the anion–cation pair within the solid and disordered silica matrix. 相似文献
125.
126.
We study the relationship between two classical approaches for quantitative ergodic properties: the first one based on Lyapunov type controls and popularized by Meyn and Tweedie, the second one based on functional inequalities (of Poincaré type). We show that they can be linked through new inequalities (Lyapunov-Poincaré inequalities). Explicit examples for diffusion processes are studied, improving some results in the literature. The example of the kinetic Fokker-Planck equation recently studied by Hérau and Nier, Helffer and Nier, and Villani is in particular discussed in the final section. 相似文献
127.
Dominique Foata 《Journal of Combinatorial Theory, Series A》2008,115(5):726-736
Using classical transformations on the symmetric group and two transformations constructed in Fix-Mahonian Calculus I, we show that several multivariable statistics are equidistributed either with the triplet (fix, des, maj), or the pair (fix, maj), where “fix,” “des” and “maj” denote the number of fixed points, the number of descents and the major index, respectively. 相似文献
128.
129.
Dominique Langevin Dr. 《Chemphyschem》2008,9(4):510-522
This paper reviews the properties of aqueous foams. The current state of knowledge is summarized briefly and the interdisciplinary aspects of this field of investigation are emphasized. Many phenomena are controlled by physical laws, but they are highly dependent upon the chemicals used as foam stabilizers: surfactants, polymers, particles. Most of the existing work is related to surfactants and polymer foams, and little is known yet for particle foams although research in this field is becoming popular. This article presents the general concepts used to describe the monolayers and the films and also some of the recent advances being made in this area. 相似文献
130.
Dominique Duchêne Gilles Ponchel 《Journal of inclusion phenomena and macrocyclic chemistry》2002,44(1-4):15-16
The use of nanoparticles is of great interest for oral or parenteral administration. In fact, nanoparticles not only can protect the active ingredient, but they confer on it a large contact surface with biological membranes and a possible improvement in bioavailability. Biodegradability of nanoparticles, which can be considered as a pre-requisite in the case of parenteral administration 相似文献