Germaborenes: Borylene Transfer Agents for the Synthesis of Iminoboranes

Halide and phenyl substituted germaborenes were shown to react with azides at room temperature and transfer a borylene moiety to give iminoboranes. This iminoborane synthesis based on a borylene transfer route was investigated computationally in the case of the phenyl substituted germaborene.     

Isogeometric Collocation: Cost Comparison with Galerkin Methods and Extension to Adaptive Hierarchical NURBS Discretizations

Collocation is based on the discretization of the strong form of the underlying partial differential equations, which requires basis functions of sufficient order and smoothness. Consequently, the use of isogeometric analysis (IGA) for collocation suggests itself, since splines can be readily adjusted to any order in polynomial degree and continuity required by the differential operators. In addition, they can be generated for domains of arbitrary geometric and topological complexity, directly linked to and fully supported by CAD technology. The major advantage of isogeometric collocation over Galerkin type IGA is the minimization of the computational effort for numerical quadrature. (© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Jordan generalized derivations on triangular algebras

Let 𝒜 be a unital algebra and let ? be a unitary 𝒜-bimodule. We consider Jordan generalized derivations mapping from 𝒜 into ?. Our results on unitary algebras are applied to triangular algebras. In particular, we prove that any Jordan generalized derivation of a triangular algebra is a generalized derivation.     

An Exact Navier-Stokes Solution for Three-Dimensional,Spanwise-Homogeneous Boundary Layers

The plane stagnation flow onto (Hiemenz boundary layer, HBL) and the asymptotic suction boundary layer flow over a flat wall (ASBL) are two boundary layer flows for which the incompressible Navier-Stokes equations are amenable to exact similarity solutions. The Hiemenz solution has been extended to swept Hiemenz flows by superposition of a third, spanwise-homogeneous sweep velocity. This solution becomes singular as the chordwise, tangential base flow component vanishes. In this limit, the homogeneous ASBL solution is valid, which however cannot describe the swept Hiemenz flow, because it does not contain any chordwise velocity. This work presents a generalized three-dimensional similarity solution which describes three-dimensional spanwise homogeneously impinging boundary layers at arbitrary wall-normal suction velocities, using a rescaled similarity coordinate. The HBL and the ASBL are shown to be two limits of this solution. Further extensions consist of oblique impingement or different boundary suction directions, such as slip or stretching walls. (© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Higher Order Mortar Finite Element Methods in 3D with Dual Lagrange Multiplier Bases

Mortar methods with dual Lagrange multiplier bases provide a flexible, efficient and optimal way to couple different discretization schemes or nonmatching triangulations. Here, we generalize the concept of dual Lagrange multiplier bases by relaxing the condition that the trace space of the approximation space at the slave side with zero boundary condition on the interface and the Lagrange multiplier space have the same dimension. We provide a new theoretical framework within this relaxed setting, which opens a new and simpler way to construct dual Lagrange multiplier bases for higher order finite element spaces. As examples, we consider quadratic and cubic tetrahedral elements and quadratic serendipity hexahedral elements. Numerical results illustrate the performance of our approach. This work was supported in part by the Deutsche Forschungsgemeinschaft, SFB 404, C12, the Netherlands Organization for Scientific Research and by the European Community's Human Potential Programme under contract HPRN-CT-2002-00286.     

Interior penalty method for the indefinite time-harmonic Maxwell equations

Summary In this paper, we introduce and analyze the interior penalty discontinuous Galerkin method for the numerical discretization of the indefinite time-harmonic Maxwell equations in the high-frequency regime. Based on suitable duality arguments, we derive a-priori error bounds in the energy norm and the L²-norm. In particular, the error in the energy norm is shown to converge with the optimal order (h^min{s,}) with respect to the mesh size h, the polynomial degree , and the regularity exponent s of the analytical solution. Under additional regularity assumptions, the L²-error is shown to converge with the optimal order (h⁺¹). The theoretical results are confirmed in a series of numerical experiments.Supported by the EPSRC (Grant GR/R76615).Supported by the Swiss National Science Foundation under project 21-068126.02.Supported in part by the Natural Sciences and Engineering Council of Canada.     

Asymptotic Results for the Sum of Dependent Non-identically Distributed Random Variables

In this paper we extend some results about the probability that the sum of n dependent subexponential random variables exceeds a given threshold u. In particular, the case of non-identically distributed and not necessarily positive random variables is investigated. Furthermore we establish criteria how far the tail of the marginal distribution of an individual summand may deviate from the others so that it still influences the asymptotic behavior of the sum. Finally we explicitly construct a dependence structure for which, even for regularly varying marginal distributions, no asymptotic limit of the tail of the sum exists. Some explicit calculations for diagonal copulas and t-copulas are given. Dominik Kortschak was supported by the Austrian Science Fund Project P18392.