Double-resonance <Emphasis Type="Italic">g</Emphasis>-factor measurements by quantum jump spectroscopy

With the advent of high-precision frequency combs that can bridge large frequency intervals, new possibilities have opened up for the laser spectroscopy of atomic transitions. Here, it is shown that laser spectroscopic techniques can also be used to determine the ground-state g factor of a bound electron. The proposal is based on a double-resonance experiment, where the spin state of a ground-state electron is constantly being read out by laser excitation to the atomic L shell, while the spin flip transitions are being induced simultaneously by a resonant microwave field, leading to the detection of the quantum jumps between the ground-state Zeeman sublevels. The magnetic moments of electrons in light hydrogen-like ions could thus be measured with advanced laser technology. Corresponding theoretical predictions are also presented. The text was submitted by the authors in English.     

Extreme-field physics in Penning traps

We present two Penning trap experiments concerned with different aspects of the physics of extreme electromagnetic fields, the ARTEMIS experiment designed for bound-electron magnetic moment measurements in the presence of the extremely strong fields close to the nucleus of highly charged ions, and the HILITE experiment, in which well-defined ion targets are to be subjected to high-intensity laser fields.     

Dynamic Covalent Identification of an Efficient Heparin Ligand

Despite heparin being the most widely used macromolecular drug, the design of small‐molecule ligands to modulate its effects has been hampered by the structural properties of this polyanionic polysaccharide. Now a dynamic covalent selection approach is used to identify a new ligand for heparin, assembled from extremely simple building blocks. The amplified molecule strongly binds to heparin (K_D in the low μm range, ITC) by a combination of electrostatic, hydrogen bonding, and CH–π interactions as shown by NMR and molecular modeling. Moreover, this ligand reverts the inhibitory effect of heparin within an enzymatic cascade reaction related to blood coagulation. This study demonstrates the power of dynamic covalent chemistry for the discovery of new modulators of biologically relevant glycosaminoglycans.     

Bohr’s strip for vector valued Dirichlet series

Bohr showed that the width of the strip (in the complex plane) on which a given Dirichlet series , converges uniformly but not absolutely, is at most 1/2, and Bohnenblust-Hille that this bound in general is optimal. We prove that for a given infinite dimensional Banach space Y the width of Bohr’s strip for a Dirichlet series with coefficients a _n in Y is bounded by 1 - 1/Cot (Y), where Cot (Y) denotes the optimal cotype of Y. This estimate even turns out to be optimal, and hence leads to a new characterization of cotype in terms of vector valued Dirichlet series. The first, second and third authors were supported by MEC and FEDER Project MTM2005-08210.     

POLYNOMIAL NUMERICAL INDEX FOR SOME COMPLEX VECTOR-VALUED FUNCTION SPACES

We study the relation between the polynomial numerical indicesof a complex vector-valued function space and the ones of itsrange space. It is proved that the spaces C(K, X) and L(µ,X) have the same polynomial numerical index as the complex Banachspace X for every compact Hausdorff space K and every -finitemeasure µ, which does not hold any more in the real case.We give an example of a complex Banach space X such that, forevery k 2, the polynomial numerical index of order k of X isthe greatest possible, namely 1, while the one of X** is theleast possible, namely k^k/(1–k). We also give new examplesof Banach spaces with the polynomial Daugavet property, namelyL(µ, X) when µ is atomless, and C_w(K, X), C_w*(K,X*) when K is perfect.     

The laser-induced discoloration of stonework; a comparative study on its origins and remedies

For understanding the phenomena associated with the discoloration observed in some cases of infrared laser cleaned stonework surfaces, a comparative study of three different types and morphologies of pollution encrustation and stone substrates was undertaken. Fragments originating from monuments with historic and/or artistic value, bearing homogeneous thin soiling on Pentelic marble (Athens, Greece), thick encrustation on Hontoria limestone (Burgos, Spain) and compact thin crust on gypsum decorations (Athens, Greece), have been studied on the basis of their composition and origin, together with the conditions that may induce yellowing effects upon their laser cleaning with IR wavelengths. While irradiation in the UV (i.e. at 355 nm) could not effectively remove the encrustations studied, irradiation at 1,064 nm was found efficient to remove all the studied pollution accumulations. Discoloration towards yellow was evident in all cases and at different levels, including the samples with intentional patination layer. To the limit of Raman detection no chemical alterations were detected on the irradiated areas while the presence of yellow polar compounds in all the pollution crusts studied supports the argument that the discoloration of the stone surfaces upon their IR irradiation may be due to the uncovering of existing yellow layers as result of the migration of these compounds inwards to the original stone surface. To correct and/or prevent such undesired coloration the use of IR and UV radiation both in sequential and synchronous mode was considered, with positive results.     

Understanding the reactivity of captodative ethylenes in polar cycloaddition reactions. A theoretical study

The electrophilic/nucleophilic character of a series of captodative (CD) ethylenes involved in polar cycloaddition reactions has been studied using DFT methods at the B3LYP/6-31G(d) level of theory. The transition state structures for the electrophilic/nucleophilic interactions of two CD ethylenes toward a nucleophilically activated ethylene, 2-methylene-1,3-dioxolane, and an electrophilically activated ethylene, 1,1-dicyanoethyelene, have been studied, and their electronic structures have been characterized using both NBO and ELF methods. Analysis of the reactivity indexes of the CD ethylenes explains the reactivity of these species. While the electrophilicity of the molecules accounts for the reactivity toward nucleophiles, it is shown that a simple index chosen for the nucleophilicity, Nu, based on the HOMO energy is useful explaining the reactivity of these CD ethylenes toward electrophiles.     

Photo-induced electron emission from 17beta-estradiol and progesterone and possible biological consequences

It was established for the first time, that the sexual hormones 17beta-estradiol (17betaE2) and progesterone (PRG) are able to emit electrons from their excited single state in water-ethanol mixtures. The yield of the "solvated electrons" (e(s)(-)) depends on the substrate concentration, the ratio of water-alcohol-mixtures and the temperature. The e(s)(-) yield obtained from 17betaE2 is by two orders of magnitude higher than this of PRG. The possible relationship of the resulting hormone transients from 17betaE2 leading via specific metabolites to breast cancer is discussed.