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81.
Sukul PK Asthana D Mukhopadhyay P Summa D Muccioli L Zannoni C Beljonne D Rowan AE Malik S 《Chemical communications (Cambridge, England)》2011,47(43):11858-11860
We report unique and spontaneous formation of hydrogels of perylene derivatives with melamine. The luminescent gel network is formed by H-type aggregation of the perylene core, supramolecularly cross-linked by melamine units. As a result of controlled aggregation in the extended nanofibers, strong exciton fluorescence emission is observed. 相似文献
82.
Meccanica - This paper is the second in a series of two that deal with a generalized theory of nonlocal elasticity of n-Helmholtz type. This terminology is motivated by the fact that the... 相似文献
83.
We generalize the classical definition of hypergroups of type U on the right to semihypergroups, and we prove some properties of their subsemihypergroups and subhypergroups. In particular, we obtain that a finite proper semihypergroup of type U on the right can exist only if its order is at least 6. We prove that one such semihypergroup of order 6 actually exists. Moreover, we show that there exists a hypergroup of type U on the right of cardinality 9 containing a proper non-trivial subsemihypergroup. In this way, we solve a problem left open in [D. Freni, Sur les hypergroupes de type U et sous-hypergroupes engendrés par un sous-ensemble, Riv. Mat. Univ. Parma 13 (1987) 29-41]. 相似文献
84.
Pier Domenico Lamberti Massimo Lanza de Cristoforis 《Mathematical Physics, Analysis and Geometry》2006,9(1):65-94
We consider the Dirichlet eigenvalue problem for the Laplace operator on a variable nonsmooth domain. We extend a result of Lupo and Micheletti concerning the structure of the set of domain perturbations which leave the multiplicity of an eigenvalue unchanged, and we study the set of perturbations which leave a certain eigenvalue unchanged. 相似文献
85.
Domenico Alfieri Giuseppe Coppola Pietro Ferraro Giovanni Pierattini 《Optics Communications》2006,260(1):113-116
A method for allowing direct perfect superimposition and comparison of Fresnel-transform reconstructions of digital holograms recorded of the same object at different distances and wavelengths is proposed and demonstrated. The method takes into account the dependence of the reconstruction pixel on the distance and the wavelength by the Fresnel-transform algorithm. The method avoids the need for image scaling at the end of the reconstruction process that usually is performed in multi-wavelength digital holography. Demonstration is given by superposing the numerical reconstructions of holograms recorded at different distances and wavelengths. The method can be potentially very useful for real-time monitoring in biological processes or for recognition and ranging by multiple wavelengths of a target with fast movements or finally for very fast investigation and study of very fast processes. 相似文献
86.
Giuseppe Mensitieri Domenico Larobina Gaetano Guerra Vincenzo Venditto Maurizio Fermeglia Sabrina Pricl 《Journal of Polymer Science.Polymer Physics》2008,46(1):8-15
The transport of chloroform in films of atactic polystyrene and of semicrystalline syndiotactic polystyrene in its nanoporous form (δ‐form) has been investigated by gravimetric analysis. Experimental tests have been performed at 35, 49, and 56 °C and at several vapor pressures ranging from 0.5 to 100 Torr. Nonequilibrium lattice fluid prediction of the amorphous sorption behavior was used to enucleate the sorption contribution of the crystalline nanoporous phase from semicrystalline samples. Sorption behavior of the crystalline phase has been interpreted on the basis of Langmuir equation. Moreover, the chloroform sorption at low activities in the crystalline nanoporous phase has been predicted by using Grand Canonical Monte Carlo molecular simulations. Isosteric heats of sorption were also experimentally evaluated for the crystalline phase, and compared with the corresponding prediction of molecular simulation. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 8–15, 2008 相似文献
87.
88.
Lorenzo Mangoni Domenico Merola Pietro Monaco Michelangelo Parrilli Lucio Previtera 《Tetrahedron letters》1984,25(24):2597-2600
On the basis of spectroscopic data structure 1 is proposed for a tetraterpene alcohol isolated from Elodea canadensis. A new biogenetic route is suggested for its formation. 相似文献
89.
Giuseppe Distefano Maurizio Guerra Francesco Paolo Colonna Derek Jones Giovanni Consiglio Domenico Spinelli 《Chemical physics》1982,72(3):267-279
The shake-up satellites present in the O1s and N1s energy regions of the XPS spectra of the planar 4-N-piperidyl-nitrobenzene (1) and 2-N-piperidyl-5-nitrothiophen (3), and of the sterically hindered 2-N-piperidyl-nitrobenzene (2), 2-N-piperidyl-3-nitrothiophen (4) and 3-N-piperidyl-2-nitrothiophen (5) and, for comparison, of 2-bromo-3-nitrothiophen (6) have been analyzed with the help of CNDO/S CI calculations. The spectra of the planar derivatives closely resemble these of the related compounds previously analysed, the main satellites deriving from the transition between the highest occupied molecular orbital (HOMO, localized at the donor-ring moiety) towards the lowest unoccupied one (LUMO, localized at the nitro group). Calculations indicate that in the ortho derivatives new relaxation processes are allowed upon N1s/NO2 ionization. In 2, where the angle of rotation θ is closer to 90° than 60°, the NR 2 lone-pair orbital relaxes through space towards the core-ionized N/NO2 atom. In 4 and 5, where 45° ? θ ? 60°, both through-ring and through-space relaxations are present. The assignment of the main N1s/NO2 line in 1 is discussed. 相似文献
90.