全文获取类型
收费全文 | 543篇 |
免费 | 20篇 |
国内免费 | 8篇 |
专业分类
化学 | 337篇 |
晶体学 | 2篇 |
力学 | 4篇 |
数学 | 136篇 |
物理学 | 92篇 |
出版年
2023年 | 2篇 |
2022年 | 7篇 |
2021年 | 10篇 |
2020年 | 11篇 |
2019年 | 12篇 |
2018年 | 3篇 |
2017年 | 3篇 |
2016年 | 12篇 |
2015年 | 15篇 |
2014年 | 13篇 |
2013年 | 26篇 |
2012年 | 39篇 |
2011年 | 30篇 |
2010年 | 22篇 |
2009年 | 14篇 |
2008年 | 28篇 |
2007年 | 35篇 |
2006年 | 29篇 |
2005年 | 21篇 |
2004年 | 30篇 |
2003年 | 18篇 |
2002年 | 14篇 |
2001年 | 11篇 |
2000年 | 8篇 |
1999年 | 2篇 |
1998年 | 6篇 |
1997年 | 9篇 |
1996年 | 5篇 |
1995年 | 5篇 |
1994年 | 14篇 |
1993年 | 9篇 |
1992年 | 17篇 |
1991年 | 12篇 |
1990年 | 6篇 |
1989年 | 16篇 |
1988年 | 7篇 |
1987年 | 2篇 |
1985年 | 7篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1981年 | 6篇 |
1980年 | 3篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1967年 | 2篇 |
排序方式: 共有571条查询结果,搜索用时 15 毫秒
81.
82.
A concise (12 step) total synthesis of sorbicillactone A and 9-epi-sorbicillactone A is reported. Unlike typical routes to the sorbicillinoids, this strategy does not start from sorbicillin and allows for the production of the bicyclic core on a multigram scale. The intramolecular conjugate addition of a tethered malonate serves as an effective means of introducing the lactone ring and provides a synthetic handle for installing the amide nitrogen. 相似文献
83.
In an attempt to perform a simple anion-exchange reaction on a pincer-carbene-ligated nickel complex using AgNO(3), we instead obtained an unexpected three-dimensional (3D) Ag(7) cluster containing a [Ag(6)] core in a twisted-bowtie geometry. The reverse-transmetalation reaction by which the carbene is transferred from nickel to silver is virtually unprecedented. The CNC pincer-carbene ligands exhibit unusual bridging modes of ligand bonding for all three donor atoms. Another unique feature is that the final structure exhibits a 3D structure brought about by the connection of two-dimensional layers of the [Ag(6)] core via a seventh Ag ion. 相似文献
84.
Selby TM Clarkson JR Mitchell D Fitzpatrick JA Lee HD Pratt DW Zwier TS 《The journal of physical chemistry. A》2005,109(20):4484-4496
The infrared and ultraviolet spectroscopy of o-, m-, and p-ethynylstyrene isomers (oES, mES, and pES) were studied by a combination of methods, including resonance-enhanced two-photon ionization (R2PI), UV-UV hole-burning spectroscopy (UVHB), resonant ion-dip infrared spectroscopy (RIDIRS), and rotationally resolved fluorescence excitation spectroscopy. In addition, the newly developed method of stimulated emission pumping-population transfer spectroscopy (SEP-PTS) was used to determine the energy threshold to conformational isomerization in m-ethynylstyrene. The S(1) <-- S(0) origin transitions of oES and pES occur at 32 369 and 33 407 cm(-1), respectively. In mES, the cis and trans conformations are calculated to be close in energy. In the R2PI spectrum of mES, the two most prominent peaks (32672 and 32926 cm(-1)) were confirmed by UVHB spectroscopy to be S(1) <-- S(0) origins of these two conformers. The red-shifted conformer was identified as the cis structure by least-squares fitting of the rotationally resolved fluorescence excitation spectrum of the origin band. There are also two possible conformations in oES, but transitions due to only one were observed experimentally, as confirmed by UVHB spectroscopy. Density functional theory calculations (B3LYP/6-31+G) predict that the cis-ortho conformer, in which the substituents point toward each other, is about 8 kJ/mol higher in energy than the trans-ortho isomer, and should only be about 5% of the room temperature population of oES. Ground-state infrared spectra in the C-H stretch region (3000-3300 cm(-1)) of each isomer were obtained with RIDIRS. In all three structural isomers, the acetylenic C-H stretch fundamental was split by Fermi resonance. Infrared spectra were also recorded in the excited electronic state, using a UV-IR-UV version of RIDIR spectroscopy. In all three isomers the acetylenic C-H stretch fundamental was unshifted from the ground state, but no Fermi resonance was seen. The first observed and last unobserved transitions in the SEP-PT spectrum were used to place lower and upper bounds on the barrier to cis --> trans isomerization in m-ethynylstyrene of 990-1070 cm(-1). Arguments are given for the lack of a kinetic shift in the measurement. The analogous trans --> cis barrier is in the same range (989-1065 cm(-1)), indicating that the relative energies of the zero-point levels of the two isomers are (E(ZPL)(cis) - E(ZPL)(trans))= -75 to +81 cm(-1). Both the barrier heights and relative energies of the minima are close to those determined by DFT (Becke3LYP/6-31+G) calculations. 相似文献
85.
Based upon the recommendations of professional organizations in science and mathematics education, children at K-6 levels need to be exposed to activities involving scientific methodology, the discovery of new knowledge and the integration of science and mathematics curricula. This study describes several distinct kinds of problem solving investigations identified from real life situations which can be adapted in intellectually honest ways for selected levels of the elementary school curriculum. The activities lend themselves to interactions with businesses and industries in the children's community and involve the children in a variety of non-traditional instructional activities such as oral presentations, small group collaborative efforts, and written reports. Finally, the investigations promote the integration of science and mathematics curricula and suggest the role curricula can play in the lives of children. 相似文献
86.
Diane McGrath 《School science and mathematics》1989,89(4):346-350
Super Vocab Machine Elements, Compounds, and Mixtures: A Matter of Mystery That's Life: Human Body Exploration 相似文献
87.
In this paper we give an approximate probability distribution for the maximum order complexity of a random binary sequence. This enables the development of statistical tests based on maximum order complexity for the testing of a binary sequence generator. These tests are analogous to those based on linear complexity. 相似文献
88.
89.
90.
The total synthesis of (±)-desepoxy-4,5-didehydromethylenomycin A employing a retrolactonization strategy has been achieved. 相似文献