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排序方式: 共有162条查询结果,搜索用时 15 毫秒
41.
O. Dogan 《Journal of Quantitative Spectroscopy & Radiative Transfer》2005,95(2):263-269
The Ag diffusion in superconducting YBa2Cu3O7 (YBaCuO) ceramic has been studied over the duration of the diffusion range 5-24 h in the temperature range 700-850 °C by the energy-dispersive X-ray fluorescence (EDXRF) technique. For the excitation of silver atoms, an annular Am-241 radioisotope source (50 mCi) emitting 59.543 keV photons was used. The temperature dependences of silver diffusion coefficients in grains (D1) and over the grain boundaries in the range 700-850 °C (D2) are described by the relations D1=1.4×10−2 exp[−(1.18±0.10)/kT] and D2=3.1×10−4 exp[−(0.87±0.10)/kT]. 相似文献
42.
Alraqa Shaya Y. Kaya Esra Nur Taşci Neşe Erbahar Dogan Durmuş Mahmut 《Journal of fluorescence》2022,32(5):1801-1813
Journal of Fluorescence - In this current study, the novel bis[4,5-(pyrene-2-yl)-3,6-(hexyloxy)] phthalonitrile (SPN) fluorophore has been successfully synthesized. Structural characterization of... 相似文献
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[reaction: see text] A series of water-soluble green perylenediimide (PDI) dyes have been synthesized. On red light excitation, these dyes were shown to be efficient generators of singlet oxygen, and in cell culture media, they were shown to display significant light-induced cytotoxic effects on the human erythroleukemia cell line (K-562). It appears that highly versatile PDI dyes are likely to find new applications in photodynamic therapy. 相似文献
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Asli Yildirim Prof. Dr. Fethiye Aylin Sungur Konuklar Dr. Saron Catak Prof. Dr. Veronique Van Speybroeck Prof. Dr. Michel Waroquier Prof. Dr. Ilknur Dogan Prof. Dr. Viktorya Aviyente 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(40):12725-12732
The mechanism of ring–chain–ring tautomerization and the prominent effect of the solvent environment have been computationally investigated in an effort to explain the enantiomeric interconversion observed in 2‐oxazolidinone derivatives, heterocyclic analogues of biphenyl atropisomers, which were isolated as single stable enantiomers and have the potential to be used as axially chiral catalysts. This study has shed light on the identity of the intermediate species involved in the ring–chain–ring tautomerization process as well as the catalytic effect of polar protic solvents. These mechanistic details will prove very useful in predicting and understanding ring–chain tautomeric equilibria in similar heterocyclic systems and will further enable experimentalists to devise appropriate experimental conditions in which axially chiral catalysts remain stable as single enantiomers. 相似文献
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Seylan Ayan Özdemir Dogan Polina M. Ivantcova Nikita G. Datsuk Dmitry A. Shulga Vladimir I. Chupakhin Dmitry V. Zabolotnev Konstantin V. Kudryavtsev 《Tetrahedron: Asymmetry》2013,24(13-14):838-843
The (2R,4R,5S)- and (2S,4S,5R)-enantiomers of 4-(tert-butyl) 2-methyl 5-(4-bromophenyl)-pyrrolidine-2,4-dicarboxylate 3 were synthesized efficiently with an ee of >90% on a gram scale using a FAM-catalytic methodology. Subsequent modification afforded enantiopure N-((4-chlorophenyl)thio)acetyl pyrrolidine derivatives 4, which are potential thrombin inhibitors according to comprehensive molecular docking studies. 相似文献
48.
Sevinc Kurbanoglu Burcu Dogan‐Topal Bengi Uslu Alp Can Sibel A. Ozkan 《Electroanalysis》2013,25(6):1473-1482
The effect of surface modifications on the electrochemical behavior of the anticancer drug idarubicin was studied at multiwalled carbon nanotubes modified glassy carbon and edge plane pyrolytic graphite electrodes. The surface morphology of the modified electrodes was characterized by scanning electron microscopy. The modified electrodes were constructed for the determination of idarubicin using adsorptive stripping differential pulse voltammetry. The experimental parameters such as supporting electrolyte, pH, accumulation time and potential, amount of carbon nanotubes for the sensitive assay of idarubicin were studied as details. Under the optimized conditions, idarubicin gave a linear response in the range 9.36×10?8–1.87×10?6 M for modified glassy carbon and 9.36×10?8–9.36×10?7 M for modified edge plane pyrolytic graphite electrodes. The detection limits were found as 1.87×10?8 M and 3.75×10?8 M based on modified glassy carbon and edge plane pyrolytic graphite electrodes, respectively. Interfering species such as ascorbic acid, dopamine, and aspirin showed no interference with the selective determination of idarubicin. The analyzing method was fully validated and successfully applied for the determination of idarubicin in its pharmaceutical dosage form. The possible oxidation mechanism of idarubicin was also discussed. The results revealed that the modified electrodes showed an obvious electrocatalytic activity toward the oxidation of idarubicin by a remarkable enhancement in the current response compared with bare electrodes. 相似文献
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In this work, viscosities of ternary Au–Ag–Cu and Al–Cu–Si liquid alloys have been calculated as a function of gold, aluminium and copper compositions for the sections Au–Ag–Cu (xAg/xCu = 0.543 at 1373 K), Alx(Cu50–Si50)(1–x) and Cux(Al50–Si50)(1–x) at 1375 K using Chou’s general solution model, Muggianu, Kohler, Toop, Hillert, Budai et al., Kozlov et al., Schick et al. and Kaptay et al. models. The present study finds that a comparison of the predicted values of viscosities associated with the geometric and physical models indicate good mutual agreement. The Muggianu model indicates the best agreement with the results obtained for Au–Ag–Cu and Alx–Cu50–Si50 alloy systems and the Kaptay et al. model, which is a physical model, indicates the best agreement with the results obtained for Al50–Cux–Si50. 相似文献