Distribution coefficients of phenol between water and hydrocarbons at 283–328 K

Distribution of phenol between aqueous and organic phases at maximal dilution in the range 283–328 K was studied chromatographically. Ten systems containing saturated and aromatic hydrocarbons were examined.Translated from Zhurnal Prikladnoi Khimii, Vol. 77, No. 11, 2004, pp. 1768–1771.Original Russian Text Copyright © 2004 by Dobryakova, Dobryakov.     

Gas-chromatographic determination of volatile sulfur-containing impurities in industrial emissions and aqueous solutions

Procedures are developed for determining volatile sulfur-containing impurities, hydrogen sulfide, simple mercaptans, sulfides, and disulfides in air and aqueous solutions. The procedures are based on the principle’s headspace gas chromatography and equilibrium preconcentration. The procedures differ from the officially approved ones in that the operations of sampling and sample preparation to gas-chromatographic analysis considerably reduce the loss of hydrogen sulfide and mercaptans unstable in humid air. The procedures provide the determination of sulfur-containing substances at the level of their maximum permissible concentrations (MPC) in industrial emissions and natural waters and the analytical range of four orders of magnitude; they can be implemented on gas chromatographs with flame ionization and flame photometric detectors, a quartz capillary column, and a thermostated gas-sampling valve.     

Comments on small superconducting clusters

The feasibility of an experimental study of small superconducting clusters (SC) is analyzed. Critical sizes for SC are calculated. Oscillations of the energy gap and the diamagnetic susceptibility of SC are considered.