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21.
John R. Peterson Tamara J. Winter Hoang D. Do Robin D. Rogers 《Journal of chemical crystallography》1989,19(1):135-145
Structural and conformational information obtained from the crystal structure and solution1H nmr investigations of the title compound are compared. The 4-aryltetralone, C24H24O10, crystallizes as a chloroform solvate in the monoclinic space group, P21/n, witha=12.519(4),b=17.938(6),c=12.534(9)Å,=111.90(5)°, and Dcalc=1.51 g cm–3 forZ=4. The data for this compound were collected at –150°C. Least-squares refinement of 2796 observed [F
o5(F
o)] reflections led to the final agreement index ofR=0.062. A threefold static disorder was observed for one of the carboxyl groups. The second carboxyl group participates in an intramolecular hydrogen bond and is thus ordered. The1H nmr spectrum revealed the title compound to exist as a keto-enol tautomeric mixture in solution. Vicinal hydrogen coupling constant analysis proved reliable in ascertaining B-ring stereochemistry of 2,3-disubstituted-4-aryltetralones. 相似文献
22.
Xu Wen-Yang Guo Chang-Jie Do Tao 《Journal of inclusion phenomena and macrocyclic chemistry》1986,4(4):325-331
A member of the novel family of crystalline microporous aluminophosphates, AlPO4-12, was synthesized by hydrothermal crystallization using different aluminum-containing compounds. Three new crystalline phases were obtained by varying the composition of the reaction mixture. The effect of the synthesis conditions on the hudrothermal process and the kinetics of crystallization are discussed. The apparent activation energies obtained for AlPO4-12 are 20.9 and 14.6 kcal/mol for nucleation and crystallization, respectively. The adsorption isotherms of one AlPO4-12 product were measured. 相似文献
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Fa Jie Yang Da Ling Yang Shou Hai Zhang Xi Gao Jian 《中国化学快报》2007,18(8):966-968
A new interfacial polymerization (IP) procedure is developed in order to synthesize polypiperazine-amide thin-film membrane on the inner surface of poly(phthalazinone ether sulfone ketone) (PPESK) hollow fiber ultrafiltration (UF) membrane.A hollow fiber composite membrane with good performance was prepared and studied by FT-IR and scanning electron microscopy. 相似文献
25.
C. H. Do E. M. Pearce B. J. Bulkin H. K. Reimschuessel 《Journal of polymer science. Part A, Polymer chemistry》1987,25(8):2301-2321
The progress of photo- and photooxidative degradation of nylon films were studied by FT–IR spectroscopy. The gases evolved from the photolysis of various nylons and their model amides were also analyzed. The formation of double bonds, changes of crystallinity, and the effect of amino and carboxyl end groups has been studied and discussed. The band shapes of the IR spectra pertaining to the carbonyl groups formed by thermal oxidation or photooxidation were found to be very similar, suggesting that the two oxidation mechanisms might be similar. The broadness of these bands indicates that the carbonyl groups may belong to more than one species. The photodegradation of nylons containing purposely inserted carbonyl groups formed ? CH?CH2 groups. Carbonyl groups formed during oxidation, and present either as keto groups or part of N-acylamide units make nylons susceptible to degradation reactions entailing mainly a Norrish type II mechanism. 相似文献
26.
A New Asterosaponin from the Starfish Culcita novaeguineae 总被引:1,自引:0,他引:1
HaiFengTANG YangHuaYI LingLI PengSUN DaZhengZHOU BaoShuLIU 《中国化学快报》2005,16(5):619-622
A new asterosaponin named novaeguinoside A, along with a known saponin, asteronyl pentaglycoside sulfate, was isolated from the starfish Culcita novaeguineae. The new compound was identitied to be sodium 6α-O-{β-D-fucopyranosyl-(1→2)-β-D-fucopyranosyl-(1→4)-[β-D-quinovopyranosyl-(1→2)]-β-D-xylopyranosyl-(1→3)-[β-D-quinovopyranosyl}-5α-pregn-9(11)-en-20-one-3β-yl-sulfate by extensive spectral analysis and chemical evidence. 相似文献
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Kwak WJ Han CK Chang HW Kim HP Kang SS Son KH 《Chemical & pharmaceutical bulletin》2003,51(3):333-335
A new triterpenoid saponin, loniceroside C was isolated from the aerial parts of Lonicera japonica. Its structure was established to be 3-O-beta-D-glucopyranosyl hederagenin 28-O-alpha-L-rhamnopyranosyl (1-->2)-[beta-D-xylopyranosyl(1-->6)]-beta-D-glucopyranosyl ester by spectroscopic techniques and chemical transformations. Loniceroside C showed in vivo antiinflammatory activity against mouse ear edema provoked by croton oil. 相似文献
30.
典型钙/镁基吸附剂对二氧化硒吸附特性研究 《燃料化学学报》2003,48(11):1335-1344
针对钙/镁基矿物吸附剂的主要组分CaO、CaCO3、MgO在500-800 ℃下对Se的吸附特性进行研究,并选取天然矿物方解石、白云石研究其对Se的吸附效果,且对矿物煅烧所得CaO进行吸附实验。结果表明,三种组分中CaO的吸附效果最佳,800 ℃时单位质量CaO对Se的吸附量可达368 mg/g。CaCO3对Se的吸附在700 ℃时效果最佳且其吸附产物的热稳定性较好。镁基吸附剂仅在中温段对Se具有一定吸附效果。方解石对Se的吸附效果随温度变化趋势与CaCO3相似,因其较好的孔隙结构,吸附效果略优于CaCO3。煅烧方解石得到的F-sor对Se的吸附效果优于CaO和CaCO3煅烧得到的C-sor,这与其良好的比表面积、孔隙结构与抗烧结能力有关,且F-sor吸附产物的热稳定性相对较好。F-sor对Se的吸附量最高可达403 mg/g。 相似文献