Spektrochemische bestimmung der hauptbestandteile von Cu-Al-binärlegierungen mit der glimmentladungslampe als lichtquelle

The suitability of the glow discharge lamp for the analysis of both main components of a binary system Cu-Al has been investigated. The standard samples contained Cu and Al between 0.5 and 99.5%. Different calibration methods for these systems are discussed. Only the “method of binary ratios” yields a straight line for calibration within the entire concentration range. It is obtained if the logarithm of the intensity ratio is plotted against the logarithm of the concentration ratio of Cu and Al. Accurate and precise results are obtained if the discharge voltage and the gas pressure are kept constant for all samples. The correlation coefficient was found to be 0.99986 and the relative standard deviation for the determination of the concentration was about 0.06 · (1-w), where w is the concentration expressed as a fraction.     

Trace determination of oxygen in gold-copper alloys and in high purity gold using3He and4He activation analysis

Trace amounts of oxygen in gold-copper alloys and high purity gold have been determined by³He and⁴He activation analysis. Interferences from the matrix have been identified and the factors which can have an effect upon the precision and the accuracy of the method have been investigated. Thus a destructive technique has been choosen. The¹⁸F produced was chemically separated by steam distillation and precipitated as PbClF. The values of the oxygen concentration were found to range between 0.2 and 2 μg·g⁻¹ depending on the copper concentration and the thermal treatment applied to the samples. A possible mechanism of internal oxidation is presented.     

Experimental characterization of transition to chaos in the presence of noise

Transition to chaos in the presence of noise is an important problem in nonlinear and statistical physics. Recently, a scaling law has been theoretically predicted which relates the Lyapunov exponent to the noise variation near the transition. Here we present experimental observation of noise-induced chaos in an electronic circuit and obtain the fundamental scaling law characterizing the transition. The experimentally obtained scaling exponent agrees very well with that predicted by theory.     

Analogues méso-hétérocycliques du dihydro-9,10 anthracène. XII — Sur quelques indoles dérivés de la dibenzo-p-dioxine

2-Aminodibenzo-p-dioxine undergoes facile condensation with different ω-bromoketones to give 2-aroylmethylaminodibenzo-p-dioxines, which undergo Möhlau-Bischler cyclisation under certain conditions. Some indolo[5,6-b] [1,4]benzodioxine were prepared by this method and their biochemical effect on the zoxazolamine hydroxylase in rats was studied.     

Development of a Sensitive LC Assay with Fluorescence Detection for the Determination of Zearalenone in Rat Serum

A simple and sensitive liquid chromatographic assay with fluorescence detection assay was developed for the determination of zearalenone levels in rat serum. The assay utilized a single liquid–liquid extraction with t-butyl methyl ether and isocratic elution using a mobile phase consisting of acetonitrile and 0.1% triethylamine in distilled water (pH = 6) (50:50, v/v). Linearity was observed over a concentration range from 10 to 1,000 ng mL^?1 (r = 0.9995), with the limit of quantification at 10 ng mL^?1 with 100 μL of rat serum. The validated assay was applied to a pharmacokinetic study in rats.     

Organic Positive Materials for Magnesium Batteries: A Review

Magnesium batteries, like lithium-ion batteries, with higher abundance and similar efficiency, have drawn great interest for large-scale applications such as electric vehicles, grid energy storage and many more. On the other hand, the use of organic electrode materials allows high energy-performance, metal-free, environmentally friendly, versatile, lightweight, and economically efficient magnesium storage devices. In particular, the structural diversity and the simple activity of organic molecules make redox properties, and hence battery efficiency, easy to monitor. While organic magnesium batteries still in their infancy, this field becomes more and more promising because significant results were reported. To summarize the achievements in studies on organic cathodes for magnesium systems, their synthesis is discussed, combined with electrode design to provide the basis for controlling the electrochemical properties. Moreover, the techniques to synthesize organic materials with high-yield are mentioned. Finally, potential problems and prospects are explored to further improve organic cathodes.     

Speciation analysis of chromium by separation on a 5-palmitoyl oxine-functionalized XAD-2 resin and spectrophotometric determination with diphenylcarbazide

The method developed in this work for the separation and preconcentration of Cr(III) is based on its retention by an Amberlite XAD-2 copolymer resin functionalized with 5-palmitoyl-8-hydroxyquinoline (oxine), abbreviated XAD-POx, with the ligand covalently bound to the copolymer. Cr(III) sorption was quantitative within the pH range 4.5–7.0 and Cr(VI) was not retained. The Cr(III) held by the resin column was eluted with a hot solution of H₂O₂ in pH9.0 aqueous NH₃–NH₄Cl buffer, and Cr oxidized to CrO₄^2– was rejected by the chelating cation-exchanger column. Any Cr(VI) originally present with Cr(III) could be reduced with an acidic solution of H₂O₂, and retained by the column yielding total Cr results, Cr(VI) being determined from the difference. The resin showed a maximal preconcentration factor of 60 for Cr(III), the LOD and LOQ being 9.3 and 30.1 nmol L^–1, respectively. The developed preconcentration-speciation analysis was finished with a diphenylcarbazide (DPC) spectrophotometric procedure suitable for conventional laboratories. The resin showed excellent salt tolerance, enabling Cr analysis in seawater, and was stable over extended use. All the interferents of this procedure that normally occur in an electroplating effluent, a blended coal CRM, and a standard steel sample could be removed by the recommended procedure, by use of partial and total selectivity at the adsorption and desorption stages, respectively, enabling preconcentration and colorimetric determination of chromium in various complex matrices.     

Comparative Study of Biosorption of Heavy Metals Using Living Green Algae Scenedesmus quadricauda and Neochloris pseudoalveolaris: Equilibrium and Kinetics

The biosorption of several heavy metals such as cobalt(II), chromium(III), lead(II), cadmium(II), nickel(II), and manganese(II) from aqueous systems on living microalgae cultures, Scenedesmus quadricauda and Neochloris pseudoalveolaris were studied under laboratories conditions. The kinetic and statistical parameters were calculated by using the data obtained from batch cultivation and well fitted a pseudo-first-order rate equation. The initial metal concentrations in solution were about 5–40 mg · L^?1. According to the pseudo-second-order model, the biosorption capacities of Scenedesmus quadricauda for Co(II), Cr(III), Pb(II), Cd(II), Ni(II), and Mn(II) ions were found in the ranges of 2.14–52.48, 1.98–81.98, 8.05–4.26, 7.81–24.96, 2.17–55.71, and 3.54–75.20 mg g^?1, respectively. Kinetic studies revealed that the metal uptake capacity of each living green algae was rather fast. It was also observed that the biosorption kinetic rate decreased with increasing concentration for both microalgae. The application of diffusion-controlled models to the experimental results indicated that the contribution of intraparticle diffusion to the overall sorption kinetics was not very important. Results showed that Co(II), Cr(III), Pb(II), Cd(II), Ni(II), and Mn(II) ions could effectively be absorbed by using living microalga cultures from aqueous solutions.