全文获取类型
收费全文 | 480篇 |
免费 | 10篇 |
国内免费 | 1篇 |
专业分类
化学 | 290篇 |
晶体学 | 14篇 |
力学 | 3篇 |
数学 | 21篇 |
物理学 | 163篇 |
出版年
2024年 | 8篇 |
2023年 | 6篇 |
2022年 | 19篇 |
2021年 | 13篇 |
2020年 | 15篇 |
2019年 | 25篇 |
2018年 | 13篇 |
2017年 | 3篇 |
2016年 | 14篇 |
2015年 | 10篇 |
2014年 | 15篇 |
2013年 | 32篇 |
2012年 | 27篇 |
2011年 | 29篇 |
2010年 | 14篇 |
2009年 | 14篇 |
2008年 | 13篇 |
2007年 | 18篇 |
2006年 | 17篇 |
2005年 | 15篇 |
2004年 | 9篇 |
2003年 | 8篇 |
2002年 | 7篇 |
1999年 | 9篇 |
1998年 | 7篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1993年 | 5篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1988年 | 7篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1985年 | 8篇 |
1984年 | 12篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1981年 | 10篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1977年 | 6篇 |
1974年 | 3篇 |
1973年 | 4篇 |
1972年 | 2篇 |
1971年 | 5篇 |
1955年 | 2篇 |
1954年 | 2篇 |
排序方式: 共有491条查询结果,搜索用时 15 毫秒
101.
Divya Tripathi 《Tetrahedron》2009,65(11):2226-594
A short and enantioselective approach to medium ring ethers and its application to the syntheses of (−)-cis-lauthisan and (+)-isolaurepan are described. The synthetic strategy features Jacobson's Hydrolytic Kinetic Resolution (HKR), oxidative resolution of secondary alcohol, and highly diastereoselective Et3SiH/TMSOTf-promoted reductive cyclization of a hydroxy ketone to give exclusively the different medium-sized cis-disubstituted cyclic ethers. 相似文献
102.
Dowex-50W ion exchange resin-promoted solvent-free heating of an intimate mixture of an aldehyde, an active methylene compound and N,N′-dimethylurea furnished the title compounds in moderate to good yields. 相似文献
103.
Ganeshpurkar Ankit Singh Ravi Shivhare Shalini Divya Kumar Devendra Gutti Gopichand Singh Ravibhushan Kumar Ashok Singh Sushil Kumar 《Molecular diversity》2022,26(3):1455-1479
Molecular Diversity - Structure-based drug design (SBDD) is an important in silico technique, used for the identification of enzyme inhibitors. Acetylcholinesterase (AChE), obtained from... 相似文献
104.
Divya P. V. Kaliprasad C. S. Narayana Y. Prakash V. 《Journal of Radioanalytical and Nuclear Chemistry》2019,322(1):121-127
Journal of Radioanalytical and Nuclear Chemistry - Some of the coastal parts of Kerala are well reported high background radiation areas (HBRA). Hence, the radiological protection of the population... 相似文献
105.
Kanhed Ashish M. Patel Dushyant V. Teli Divya M. Patel Nirav R. Chhabria Mahesh T. Yadav Mange Ram 《Molecular diversity》2021,25(1):383-401
Molecular Diversity - The Corona virus Disease (COVID-19) is caused because of novel coronavirus (SARS-CoV-2) pathogen detected in China for the first time, and from there it spread across the... 相似文献
106.
Monika Bhardwaj Poonam Yadav Divya Vashishth Kavita Sharma Ajay Kumar Jyoti Chahal Sunita Dalal Sudhir Kumar Kataria 《Molecules (Basel, Switzerland)》2021,26(11)
Obesity is a serious health complication in almost every corner of the world. Excessive weight gain results in the onset of several other health issues such as type II diabetes, cancer, respiratory diseases, musculoskeletal disorders (especially osteoarthritis), and cardiovascular diseases. As allopathic medications and derived pharmaceuticals are partially successful in overcoming this health complication, there is an incessant need to develop new alternative anti-obesity strategies with long term efficacy and less side effects. Plants harbor secondary metabolites such as phenolics, flavonoids, terpenoids and other specific compounds that have been shown to have effective anti-obesity properties. Nanoencapsulation of these secondary metabolites enhances the anti-obesity efficacy of these natural compounds due to their speculated property of target specificity and enhanced efficiency. These nanoencapsulated and naive secondary metabolites show anti-obesity properties mainly by inhibiting the lipid and carbohydrate metabolizing enzymes, suppression of adipogenesis and appetite, and enhancing energy metabolism. This review focuses on the plants and their secondary metabolites, along with their nanoencapsulation, that have anti-obesity effects, with their possible acting mechanisms, for better human health. 相似文献
107.
An environment friendly method for the synthesis of 2-oxo/thioxooctahydroquinazolin-5-one derivatives has been devised using Ceric ammonium nitrate (CAN) as catalyst and polyethylene glycol (PEG) as solvent. The cytotoxic effect of these compounds was studied on U87 human glioma cells, compounds 4c, 4d and 4e are found to exhibit excellent activity at a concentration as low as 0.06 μg/ml. 相似文献
108.
The structure of nuclear transition matrix elements (NTMEs) required for the study of neutrinoless double-β decay within light Majorana neutrino mass mechanism is disassembled in the PHFB model. The NTMEs are calculated using a set
of HFB intrinsic wave functions, the reliability of which has been previously established by obtaining an overall agreement
between the theoretically calculated spectroscopic properties and the available experimental data. Presently, we study the
role of short-range correlations, radial evolution of NTMEs and deformation effects due to quadrupolar correlations. In addition,
limits on effective light neutrino mass 〈m
ν
〉 are extracted from the observed limits on half-lives T
12/0ν
of neutrinoless double-β decay. 相似文献
109.
We investigate the critical role played by the mean micellar length during the route to rheochaos for wormlike micellar gels of surfactant cetyltrimethylammonium tosylate in the presence of salt sodium chloride that show coupling of flow to concentration fluctuations. To this end, we have carried out stress/shear rate relaxation experiments at a fixed shear rate/stress but at different temperatures to take the sample through the route to rheochaos. We see the type-II intermittency route to rheochaos in stress relaxation measurements and the type-III intermittency route to rheochaos in shear rate relaxation measurements. We have also carried out linear rheology measurements at different temperatures to estimate the mean micellar length (-)L, the reptation time tau(rep), and the breaking time tau(break). It is shown that (-)L changes by approximately 58%, as the sample goes through the route to rheochaos. 相似文献
110.
Krishnamurthy D Kasper GD Namuswe F Kerber WD Narducci Sarjeant AA Moënne-Loccoz P Goldberg DP 《Journal of the American Chemical Society》2006,128(44):14222-14223
The synthesis of a mononuclear, five-coordinate ferrous complex [([15]aneN4)FeII(SPh)](BF4) (1) is reported. This complex is a new model of the reduced active site of the enzyme superoxide reductase (SOR), which is comprised of a [(NHis)4(Scys)FeII] center. Complex 1 reacts with alkylhydroperoxides (tBuOOH, cumenylOOH) at low temperature to give a metastable, dark red intermediate (2a: R = tBu; 2b: R = cumenyl) that has been characterized by UV-vis, EPR, and resonance Raman spectroscopy. The UV-vis spectrum (-80 degrees C) reveals a 526 nm absorbance (epsilon = 2150 M-1 cm-1) for 2a and a 527 nm absorbance (epsilon = 1650 M-1 cm-1) for 2b, indicative of alkylperoxo-to-iron(III) LMCT transitions, and the EPR data (77 K) show that both intermediates are low-spin iron(III) complexes (g = 2.20 and 1.97). Definitive identification of the Fe(III)-OOR species comes from RR spectra, which give nu(Fe-O) = 612 (2a) and 615 (2b) cm-1, and nu(O-O) = 803 (2a) and 795 (2b) cm-1. The assignments for 2a were confirmed by 18O substitution (tBu18O18OH), resulting in a 28 cm-1 downshift for nu(Fe-18O), and a 46 cm-1 downshift for nu(18O-18O). These data show that 2a and 2b are low-spin FeIII-OOR species with weak Fe-O bonds and suggest that a low-spin intermediate may occur in SOR, as opposed to previous proposals invoking high-spin intermediates. 相似文献